公开(公告)号：US20080128615A1

公开(公告)日：2008-06-05

申请号：US11987085

申请日：2007-11-27

申请人： Masuyoshi Yamada ,  Masako Ishimaru

发明人： Masuyoshi Yamada ,  Masako Ishimaru

IPC分类号： H01J49/04

CPC分类号： H01J49/0422

摘要： An analyzer carrying out analysis with a high degree of qualitative accuracy by separating impurities which hinder the analysis while analyzing in real time. An introducing tube is branched with one branched tube directly leading to an ion source for real time analysis. The other branched tube leads to the ion source so as to introduce the sample gas into the ion source at a later time. When a result of the real time analysis shows that a spectrum pattern on a MS spectrum is changed and an increase in the concentration of an impurity is observed, the introducing path for the sample gas is changed so that the sample gas is introduced into the ion source after the impurity is separated at the separation part.

摘要翻译： 分析仪通过分析实时分析分析杂质，以高度的定性精度进行分析。 引入管被分支，一个分支管直接通向离子源进行实时分析。 另一个分支管通向离子源，以便稍后将样品气体引入离子源。 当实时分析的结果表明MS谱上的光谱图变化并且观察到杂质浓度增加时，改变样品气体的引入路径，使样品气体被引入离子 杂质在分离部分分离出来。

公开(公告)号：US08368013B2

公开(公告)日：2013-02-05

申请号：US13084930

申请日：2011-04-12

申请人： Masako Ishimaru ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Masuyuki Sugiyama ,  Hidetoshi Morokuma

发明人： Masako Ishimaru ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Masuyuki Sugiyama ,  Hidetoshi Morokuma

IPC分类号： B01D59/44 ,  H01J49/00

CPC分类号： H01J49/145

摘要： An analyzer performs dielectric barrier discharge and ionization of a sample by a reaction between the sample and excited molecules or ions generated by the dielectric barrier discharge at a pressure lower than an atmospheric pressure.

摘要翻译： 分析仪通过在低于大气压的压力下通过介电阻挡放电产生的样品和激发的分子或离子之间的反应来进行介电阻挡放电和样品的离子化。

公开(公告)号：US08253097B2

公开(公告)日：2012-08-28

申请号：US12039762

申请日：2008-02-29

申请人： Masako Ishimaru ,  Masuyoshi Yamada

发明人： Masako Ishimaru ,  Masuyoshi Yamada

IPC分类号： H01J49/00

CPC分类号： H01J49/168 ,  G01N30/461 ,  G01N30/7213 ,  H01J49/147

摘要： In a mass spectrometer having ion sources capable of switching between atmospheric pressure chemical ionization and electron impact ionization, a first gas chromatography device capable of separating a sample to meet a condition suitable for atmospheric pressure chemical ionization measurement is connected to upstream of an atmospheric pressure chemical ionization ion source. Part of the sample separated by the first gas chromatography device is introduced to a second gas chromatography device by distributing a flow channel. In the second gas chromatography device, a target substance and background ingredients contained in the sample are further separated and are introduced to an electron impact ionization ion source. By separating the target substance from the background ingredients, an electron impact ionization spectrum of the target substance is obtained without an effect of the background ingredients.

摘要翻译： 在具有能够在大气压化学电离和电子轰击电离之间切换的离子源的质谱仪中，能够分离样品以满足适于大气压化学电离测量的条件的第一气相色谱装置连接到大气压化学品 电离离子源。 通过分配流动通道将由第一气相色谱装置分离的样品的一部分引入第二气相色谱装置。 在第二气相色谱装置中，将样品中所含的目标物质和背景成分进一步分离并引入电子轰击离子化离子源。 通过将目标物质与背景成分分离，可以获得目标物质的电子轰击电离光谱，而不影响背景成分。

公开(公告)号：US20090039250A1

公开(公告)日：2009-02-12

申请号：US12039762

申请日：2008-02-29

申请人： Masako ISHIMARU ,  Masuyoshi Yamada

发明人： Masako ISHIMARU ,  Masuyoshi Yamada

IPC分类号： H01J49/00

CPC分类号： H01J49/168 ,  G01N30/461 ,  G01N30/7213 ,  H01J49/147

摘要： In a mass spectrometer having ion sources capable of switching between atmospheric pressure chemical ionization and electron impact ionization, a first gas chromatography device capable of separating a sample to meet a condition suitable for atmospheric pressure chemical ionization measurement is connected to upstream of an atmospheric pressure chemical ionization ion source. Part of the sample separated by the first gas chromatography device is introduced to a second gas chromatography device by distributing a flow channel. In the second gas chromatography device, a target substance and background ingredients contained in the sample are further separated and are introduced to an electron impact ionization ion source. By separating the target substance from the background ingredients, an electron impact ionization spectrum of the target substance is obtained without an effect of the background ingredients.

摘要翻译： 在具有能够在大气压化学电离和电子轰击电离之间切换的离子源的质谱仪中，能够分离样品以满足适于大气压化学电离测量的条件的第一气相色谱装置连接到大气压化学品 电离离子源。 通过分配流动通道将由第一气相色谱装置分离的样品的一部分引入第二气相色谱装置。 在第二气相色谱装置中，将样品中所含的目标物质和背景成分进一步分离并引入电子轰击离子化离子源。 通过将目标物质与背景成分分离，可以获得目标物质的电子轰击电离光谱，而不影响背景成分。

公开(公告)号：US20120326022A1

公开(公告)日：2012-12-27

申请号：US13527627

申请日：2012-06-20

申请人： Shun KUMANO ,  Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Hidetoshi Morokuma ,  Shuhei Hashiba

发明人： Shun KUMANO ,  Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Hidetoshi Morokuma ,  Shuhei Hashiba

IPC分类号： H01J49/04

CPC分类号： H01J49/0409 ,  H01J49/0495

摘要： A mass spectrometer including a sample attaching member of attaching a sample, an ionizing chamber including an introductory port of the sample attaching member and an ionization source of generating a sample ion, a vacuumed chamber having a mass analyzer of analyzing the sample ion, and an opening/closing mechanism provided between the ionizing chamber and the vacuumed chamber, in which the opening/closing mechanism is controlled from a closed state to an open state after introducing the sample attaching member into the ionizing chamber to thereby enable to perform ionization with inconsiderable fragmentation at a high sensitivity with a high throughput

摘要翻译： 一种质谱仪，包括附着样品的样品附着构件，包括样品附着构件的入口的电离室和产生样品离子的离子源，具有分析样品离子的质量分析器的真空室，以及 设置在离子化室和真空室之间的开/关机构，其中将样品附着构件引入电离室之后，将开/关机构从关闭状态控制到打开状态，从而能够以不可分割的碎片进行电离 灵敏度高，吞吐量高

公开(公告)号：US20120112059A1

公开(公告)日：2012-05-10

申请号：US13383371

申请日：2010-07-09

申请人： Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hisashi Nagano ,  Hideki Hasegawa ,  Yasuaki Takada ,  Masuyoshi Yamada

发明人： Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hisashi Nagano ,  Hideki Hasegawa ,  Yasuaki Takada ,  Masuyoshi Yamada

IPC分类号： H01J49/26

CPC分类号： H01J49/004

摘要： An object is to measure both cations and anions with high duty cycle. In a mass spectrometer comprising an ion source (1), an ion guide part (31), and an ion trap (32), while ions are being mass-selectively ejected from the ion trap, ions having a polarity reverse to that of the ions trapped in the ion trap are introduced into the ion guide part.

摘要翻译： 一个目标是测量阳离子和阴离子高占空比。 在离子源（1），离子引导部（31）和离子阱（32）的质谱仪中，离子从离子阱中质量选择性地喷出时，具有与 捕获在离子阱中的离子被引入离子引导部。

公开(公告)号：US20060266353A1

公开(公告)日：2006-11-30

申请号：US11210738

申请日：2005-08-25

申请人： Masuyoshi Yamada ,  Masao Suga ,  Izumi Waki

发明人： Masuyoshi Yamada ,  Masao Suga ,  Izumi Waki

IPC分类号： A62B18/08 ,  A62B7/10

CPC分类号： A61B5/097 ,  G01N1/2214 ,  G01N33/497

摘要： For collecting a component of an exhaled air, a filter comprises an adsorbent for adsorbing the component of the exhaled air, and a collector body including a passage hole which the adsorbent is contained and through which the exhaled air is capable of passing.

摘要翻译： 为了收集呼出空气的组分，过滤器包括用于吸附呼出空气的组分的吸附剂，以及包含吸附剂被容纳并且呼出的空气能够通过的通道孔的集电体。

公开(公告)号：US06840120B2

公开(公告)日：2005-01-11

申请号：US10443042

申请日：2003-05-22

申请人： Minoru Sakairi ,  Masao Suga ,  Yuichiro Hashimoto ,  Masuyoshi Yamada

发明人： Minoru Sakairi ,  Masao Suga ,  Yuichiro Hashimoto ,  Masuyoshi Yamada

IPC分类号： G01V9/00 ,  G01N1/02 ,  G01N1/22 ,  G01N1/28 ,  G01N27/62 ,  G01N27/68 ,  H01J49/04 ,  G01N1/00

CPC分类号： H01J49/0422 ,  G01N1/22 ,  G01N2001/024

摘要： An explosive detection system includes an X-ray inspection apparatus, a mover for moving an object to be inspected to the X-ray inspection apparatus, a sample introduction probe for sampling a gas sample from the object to be inspected, a pipe for introducing the sampled gas into a corona discharge region and for subjecting the sampled gas to negative corona discharge to ionize the sampled gas and to generate negative ions. A mass spectrometer is provided to analyze the mass of the negative ions of the sampled gas and to provide results thereof. Inspection by the X-ray inspection apparatus is performed in relation to sampling of the gas sample, and explosive detection system inspects whether or not an explosive is present in the object to be inspected, from the analysis results of the sampled gas.

摘要翻译： 爆炸检测系统包括：X射线检查装置，用于将待检查物体移动到X射线检查装置的移动器;用于从待检查对象取样气体样本的样品引入探针; 取样气体进入电晕放电区域，并使采样气体进行负电晕放电，使取样气体离子化并产生负离子。 提供质谱仪来分析取样气体的负离子的质量并提供其结果。 根据采样气体的分析结果，对气体样品的取样进行X射线检查装置的检查，爆炸检测系统检查是否存在待检查对象物中的爆炸物。

公开(公告)号：US06639215B2

公开(公告)日：2003-10-28

申请号：US10053567

申请日：2002-01-24

申请人： Yasuaki Takada ,  Masuyoshi Yamada ,  Masao Suga ,  Yuichiro Hashimoto

发明人： Yasuaki Takada ,  Masuyoshi Yamada ,  Masao Suga ,  Yuichiro Hashimoto

IPC分类号： B01D5944

CPC分类号： H01J49/168 ,  H01J49/0445

摘要： To provide a mass spectrometer having a high sensitivity to dioxins. In the mass spectrometer including: a sample supply tube for supplying a sample solution containing a sample to be measured; a nebulizer for nebulizing the sample solution supplied from the sample supply tube; an ion source having a needle electrode for ionizing the sample nebulized and vaporized in the nebulizer; and a mass analyzer for analyzing ions formed in the ion source, and a gas of a flow rate corresponding to the flow rate of the sample solution is mixed to the vaporized sample, and a moving direction of the sample is made opposite to a moving direction of ions at a tip of the needle electrode.

摘要翻译： 提供对二恶英具有高度敏感性的质谱仪。 在质谱仪中，包括：供给含有待测样品的样品溶液的样品供给管; 用于将从样品供应管提供的样品溶液雾化的雾化器; 离子源，其具有针状电极，用于将在雾化器中雾化和蒸发的样品电离; 以及用于分析在离子源中形成的离子的质量分析器，将与样品溶液的流量对应的流量的气体混合到蒸发的样品中，使样品的移动方向与移动方向相反 的针电极尖端的离子。

公开(公告)号：US07882754B2

公开(公告)日：2011-02-08

申请号：US11907905

申请日：2007-10-18

申请人： Masao Suga ,  Masuyoshi Yamada ,  Izumi Waki

发明人： Masao Suga ,  Masuyoshi Yamada ,  Izumi Waki

IPC分类号： G01N1/22

CPC分类号： A61B5/097 ,  G01N1/2205 ,  G01N2001/2244

摘要： A gas component collector comprises a filter assembly 3 comprising an adsorbent and an adsorbent holding plate having a first face, a second face and a plurality of holes that are bored through from the first face to the second face and are filled with the adsorbent adsorbing at least one gas component to be analyzed, the filter assembly satisfying (AL−V)2/L3≧0.003 mm3 and V/AL≧0.3, where V is a total volume of the adsorbent, A is a sum of an opening areas of the holes, and L is an average length of the holes, and a holding container 2 housing the filter assembly 3. On at least one of the holding container 2 a first opening portion for introducing gas and a second opening portion for allowing the introduced gas to be discharged are formed.

摘要翻译： 气体成分收集器包括一个过滤器组件3，它包括一个吸附剂和一个吸附剂保持板，该吸附剂保持板具有第一面，第二面和多个从第一面到第二面穿透的孔，并填充吸附在 至少一个要分析的气体组分，过滤器组件满足（AL-V）2 /L3≥0.003mm3，V /AL≥0.3，其中V是吸附剂的总体积，A是 并且L是孔的平均长度，以及容纳过滤器组件3的保持容器2.在保持容器2中的至少一个上用于引入气体的第一开口部分和用于允许引入气体的第二开口部分 被排出形成。