公开(公告)号：US20140151543A1

公开(公告)日：2014-06-05

申请号：US13884755

申请日：2011-11-08

申请人： Hisashi Nagano ,  Yasutaka Suzuki ,  Hideo Kashima ,  Yuichiro Hashimoto ,  Masuyuki Sugiyama ,  Masakazu Sugaya ,  Yasunori Doi ,  Koichi Terada

发明人： Hisashi Nagano ,  Yasutaka Suzuki ,  Hideo Kashima ,  Yuichiro Hashimoto ,  Masuyuki Sugiyama ,  Masakazu Sugaya ,  Yasunori Doi ,  Koichi Terada

IPC分类号： H01J49/00 ,  H01J49/04

CPC分类号： H01J49/0422 ,  G01N1/2211 ,  G01N1/2214 ,  G01N33/0057 ,  G01N2001/028 ,  H01J49/00 ,  H01J49/0036 ,  H01J49/04 ,  H01J49/0459 ,  H01J49/0468 ,  Y02A50/25

摘要： Provided is a technique of analyzing particles in real time while collecting and condensing the particles continuously. Gas and/or particles as a detection target substance that are attached to an authentication target 2 are removed by air flow from a blowing region 5. The removed sample is sucked and is condensed and sampled at a sampling region 10, and ions of the sample are generated at an ion source 21 and are then subjected to mass analysis at a mass analysis region 23. Determination of the obtained mass spectrum is made as to the presence or not of a mass spectrum derived from the detection target substance, and a monitor 27 displays a result thereof. Thereby, the detection target substance attached to the authentication target 2 can be detected continuously in real time, promptly and with a less error rate.

摘要翻译： 提供了一种在连续收集和冷凝颗粒时实时分析颗粒的技术。 作为检测对象物质的作为检测对象物质的气体和/或颗粒被从吹扫区域5的空气流除去。将取出的样品抽吸并在采样区域10被冷凝并取样，并且样品的离子 在离子源21处产生，然后在质量分析区域23进行质量分析。对获得的质谱进行测定，确定是否存在从检测目标物质得到的质谱，以及监测器27 显示其结果。 因此，可以实时，及时且误码率较小的连续检测附着于认证对象2的检测对象物质。

公开(公告)号：US07663098B2

公开(公告)日：2010-02-16

申请号：US11704351

申请日：2007-02-09

申请人： Yasuo Seto ,  Isaac Ohsawa ,  Hiroshi Sekiguchi ,  Hisashi Maruko ,  Yasuaki Takada ,  Akihiko Okumura ,  Hidehiro Okada ,  Hisashi Nagano ,  Izumi Waki

发明人： Yasuo Seto ,  Isaac Ohsawa ,  Hiroshi Sekiguchi ,  Hisashi Maruko ,  Yasuaki Takada ,  Akihiko Okumura ,  Hidehiro Okada ,  Hisashi Nagano ,  Izumi Waki

IPC分类号： H01J49/00 ,  G01N1/22

CPC分类号： H01J49/0036 ,  Y10T436/24

摘要： A gas monitoring apparatus capable of real-time detection of a kind of chemical warfare agent, namely diphenylcyanoarsine (DC) and/or diphenylchloroarsine (DA). Atmospheric pressure chemical ionization mass spectrometry is carried out in the positive ionization mode, the total amount of DC and DA is determined from the intensity of an ion common to DC and DA, the DC concentration is determined from the intensity of an ion specific to DC, and the difference between them is regarded as the DA concentration.

摘要翻译： 一种能够实时检测一种化学战剂（即二苯基氰胺（DC））和/或二苯氯胂（DA）的气体监测装置。 大气压化学电离质谱在正电离模式下进行，DC和DA的总量由DC和DA共同的离子强度确定，DC浓度由特定于DC的离子的强度确定 ，它们之间的差异被认为是DA浓度。

公开(公告)号：US20080054172A1

公开(公告)日：2008-03-06

申请号：US11704351

申请日：2007-02-09

申请人： Yasuo Seto ,  Isaac Ohsawa ,  Hiroshi Sekiguchi ,  Hisashi Maruko ,  Yasuaki Takada ,  Akihiko Okumura ,  Hidehiro Okada ,  Hisashi Nagano ,  Izumi Waki

发明人： Yasuo Seto ,  Isaac Ohsawa ,  Hiroshi Sekiguchi ,  Hisashi Maruko ,  Yasuaki Takada ,  Akihiko Okumura ,  Hidehiro Okada ,  Hisashi Nagano ,  Izumi Waki

IPC分类号： B01D59/44

CPC分类号： H01J49/0036 ,  Y10T436/24

摘要： A gas monitoring apparatus capable of real-time detection of a kind of chemical warfare agent, namely diphenylcyanoarsine (DC) and/or diphenylchloroarsine (DA). Atmospheric pressure chemical ionization mass spectrometry is carried out in the positive ionization mode, the total amount of DC and DA is determined from the intensity of an ion common to DC and DA, the DC concentration is determined from the intensity of an ion specific to DC, and the difference between them is regarded as the DA concentration.

摘要翻译： 一种能够实时检测一种化学战剂（即二苯基氰胺（DC））和/或二苯氯胂（DA）的气体监测装置。 大气压化学电离质谱在正电离模式下进行，DC和DA的总量由DC和DA共同的离子强度确定，DC浓度由特定于DC的离子的强度确定 ，它们之间的差异被认为是DA浓度。

公开(公告)号：US07164124B2

公开(公告)日：2007-01-16

申请号：US11009485

申请日：2004-12-13

申请人： Yasuaki Takada ,  Hisashi Nagano ,  Masao Suga ,  Hideo Kashima ,  Izumi Waki

发明人： Yasuaki Takada ,  Hisashi Nagano ,  Masao Suga ,  Hideo Kashima ,  Izumi Waki

IPC分类号： H01J49/10

CPC分类号： H01J49/0095 ,  H01J49/0422 ,  H01J49/168

摘要： A mass spectrometric apparatus capable of generating and detecting positive and negative ions stably at the same time. The apparatus preferably comprises: an opening through which a sample gas is introduced; an ion source to generate ions of the sample gas; and a mass spectrometer to analyze the mass of the generated ions. The ion source utilized with the mass spectrometric device comprises: a first needle electrode on which a voltage is applied in order to generate positive ions of the sample gas introduced through the opening; a first counter electrode having a first opening through which the sample gas and the positive ions pass; a second counter electrode disposed opposite the first counter electrode having a second opening through which the sample gas and the positive ions pass; a second needle electrode on which voltage is applied in order to generate negative ions of the sample gas; and a vent through which the sample gas is ejected. Generated ions are then introduced into a vacuum region via an aperture and subjected to mass analysis.

摘要翻译： 能够同时稳定地产生和检测正离子和负离子的质谱仪。 该装置优选地包括：开口，样品气体通过该开口被引入; 用于产生样品气体的离子的离子源; 和用于分析所产生的离子质量的质谱仪。 与质谱仪一起使用的离子源包括：第一针电极，其上施加电压以产生通过开口引入的样品气体的正离子; 第一对电极，其具有第一开口，样品气体和正离子通过该第一开口; 与第一对置电极相对配置的第二对置电极，具有第二开口，样品气体和正离子通过该第二开口; 第二针电极，其上施加电压以产生样品气体的负离子; 以及排出样品气体的排气口。 然后将产生的离子经由孔引入真空区域并进行质量分析。

公开(公告)号：US20060289742A1

公开(公告)日：2006-12-28

申请号：US11336989

申请日：2006-01-23

申请人： Yasuaki Takada ,  Masao Suga ,  Hisashi Nagano ,  Izumi Waki ,  Hidehiro Okada ,  Tatsuo Nojiri ,  Yasuo Seto ,  Yasuhiro Sano ,  Shigeharu Yamashiro ,  Isaac Ohsawa

发明人： Yasuaki Takada ,  Masao Suga ,  Hisashi Nagano ,  Izumi Waki ,  Hidehiro Okada ,  Tatsuo Nojiri ,  Yasuo Seto ,  Yasuhiro Sano ,  Shigeharu Yamashiro ,  Isaac Ohsawa

IPC分类号： H01J49/00

CPC分类号： H01J49/04 ,  Y10T436/16

摘要： A gas monitoring apparatus includes a sample introducing portion, a measurement portion, an ionization portion, a mass analysis portion, a data processing portion and a display. The sample introducing portion introduces a sample gas including an object material to be measured. The measurement portion measures a concentration of a predetermined coexisting material, which coexists with the object material in the sample gas. The ionization portion ionizes the sample gas. The mass analysis portion analyzes mass of an ion produced by the ionization portion. The data processing portion analyzes signals detected by the mass analysis portion to calculate a concentration of the object material. And the display displays results of analysis conducted by the data processing portion. The data processing portion includes an adjustment portion which adjusts the concentration of the object material according to the concentration of the predetermined coexisting material.

公开(公告)号：US20060108522A1

公开(公告)日：2006-05-25

申请号：US11324231

申请日：2006-01-04

申请人： Hisashi Nagano ,  Izumi Waki ,  Yasuaki Takada

发明人： Hisashi Nagano ,  Izumi Waki ,  Yasuaki Takada

IPC分类号： H01J49/00

CPC分类号： H01J49/0027 ,  H01J49/0077 ,  Y10T436/24

摘要： An apparatus for detecting chemical substances which is high in sensitivity and selectivity is provided. An organic acid or an organic acid salt is used to generate an organic acid gas from an organic acid gas generator 3 to be mixed with a sample gas for introduction into an ion source 4 for ionization, thereby obtaining a mass spectrum by a mass analysis region 5. A data processor 6 determines the detection or non-detection of a specific m/z of an organic acid adduct ion obtained by adding a molecule generated from the organic acid to a molecule with specific m/z generated from a target chemical substance to be detected based on the obtained mass spectrum. When there is an ion peak with the m/z of the organic acid adduct ion, the presence of the target chemical substance to be detected is determined, and an alarm is sounded. False detection can be prevented.

摘要翻译： 提供一种用于检测灵敏度和选择性高的化学物质的装置。 使用有机酸或有机酸盐从有机酸气体发生器3产生有机酸性气体，与用于引入离子源4的样品气体混合，从而通过质量分析区域获得质谱 5。 数据处理器6确定通过将由有机酸产生的分子加入到由待检测的目标化学物质产生的具有特定m / z的分子而获得的有机酸加合物的特定m / z的检测或非检测 基于获得的质谱。 当存在有机酸加合离子的m / z的离子峰时，确定要检测的目标化学物质的存在，并发出报警。 可以防止误检。

公开(公告)号：US06943343B2

公开(公告)日：2005-09-13

申请号：US10628139

申请日：2003-07-29

申请人： Shigeru Honjo ,  Yasuaki Takada ,  Hisashi Nagano ,  Masumi Fukano ,  Yasuo Seto ,  Teruo Itoi ,  Kazumitsu Iura ,  Mieko Kataoka ,  Kouichiro Tsuge

发明人： Shigeru Honjo ,  Yasuaki Takada ,  Hisashi Nagano ,  Masumi Fukano ,  Yasuo Seto ,  Teruo Itoi ,  Kazumitsu Iura ,  Mieko Kataoka ,  Kouichiro Tsuge

IPC分类号： G01N27/62 ,  G01N27/64 ,  G01N27/68 ,  H01J49/04 ,  H01J49/10 ,  H01J49/42 ,  B01D59/44

CPC分类号： G01N27/622

摘要： An apparatus for detecting a chemical agent, capable of increasing a detection speed of a chemical agent, decreasing a false alarm rate, pinning down the kind of a chemical agent, and meeting specifications for unattended continuous monitoring equipment suitable for detecting sarin or soman. This detection apparatus comprises a sample introduction unit for introducing a sample, an ionizing unit for positively ionizing the sample from the sample introduction unit, a mass spectrometer unit for analyzing ions of the sample, and a computer for analyzing data, and is best suited for identifying a dangerous substance by detecting signals peculiar to chemical agents, such as sarin or soman.

摘要翻译： 用于检测化学试剂的装置，能够提高化学试剂的检测速度，降低误报率，固定化学试剂的种类，并满足适合于检测沙林或索曼的无人值守连续监测设备的规格。 该检测装置包括用于引入样品的样品引入单元，用于从样品引入单元正电离样品的离子化单元，用于分析样品的离子的质谱仪单元和用于分析数据的计算机，并且最适合于 通过检测诸如沙林或索曼等化学剂特有的信号来识别危险物质。

公开(公告)号：US20050092915A1

公开(公告)日：2005-05-05

申请号：US10644806

申请日：2003-08-21

申请人： Masumi Fukano ,  Shigeru Honjo ,  Hisashi Nagano ,  Yasuaki Takada ,  Yasuo Seto ,  Teruo Itoi ,  Kazumitsu Iura

发明人： Masumi Fukano ,  Shigeru Honjo ,  Hisashi Nagano ,  Yasuaki Takada ,  Yasuo Seto ,  Teruo Itoi ,  Kazumitsu Iura

IPC分类号： G01N27/62 ,  G01N27/68 ,  G01N33/00 ,  H01J49/04 ,  H01J49/00 ,  B01D59/44

CPC分类号： G01N33/0044 ,  G01N27/68 ,  H01J49/04

摘要： An object of the present invention is to obtain an apparatus and a method for the detection of chemical agents which are suitable for detecting sulfur mustard and lewisite 1 and are satisfactory from the viewpoint of the speed of detection of chemical agents, the reduction of the rate of wrong information, the specification of the kinds of the chemical agents, and an unmanned continuous-monitoring apparatus. In the present invention, the detecting apparatus comprises a sample introduction section 1 into which a sample is introduced to be heated, an ionization section 2 in which the sample from the sample introduction section is ionized, a mass spectrometry section 3, and a computer 6 for data analysis. When predetermined signals characteristic of sulfur mustard or lewisite 1 are observed, it becomes possible to specify the sample.

摘要翻译： 本发明的目的是获得一种适用于检测硫芥和虱子1的化学试剂的检测装置和方法，从化学试剂的检测速度，速率的降低的观点来看是令人满意的 错误信息，化学剂种类的规格，以及无人值守的连续监测装置。 在本发明中，检测装置包括：试样导入部1，其中导入待加热的试样，将来自试样导入部的试样离子化的电离部2，质谱分析部3和计算机6 用于数据分析。 当观察到硫芥子或虱子1的特征的预定信号时，可以指定样品。

公开(公告)号：US06844546B2

公开(公告)日：2005-01-18

申请号：US10229057

申请日：2002-08-28

申请人： Hisashi Nagano ,  Yasuaki Takada ,  Izumi Waki ,  Koushou Aikawa ,  Masayuki Takizawa ,  Shigenori Morishima

发明人： Hisashi Nagano ,  Yasuaki Takada ,  Izumi Waki ,  Koushou Aikawa ,  Masayuki Takizawa ,  Shigenori Morishima

IPC分类号： G01N27/62 ,  G01N1/22 ,  H01J49/00 ,  H01J49/04

CPC分类号： H01J49/0031

摘要： An explosive detection system including a sample injection region, an ion source region for generating ions of a sample injected by the ion injection region, a mass analysis region for analyzing mass of the ions, a heater for heating the sample injection region and the ion source region, a plurality of pumps for exhausting a chamber in which the mass analysis region is disposed, and a controller for controlling the regions and the plurality of pumps. The controller conducts control so as to heat the sample injection region and the ion source region with the heaters, then reduce heating electric power supplied to the heaters in order to prevent a predetermined electric power value from being exceeded, and drive the plurality of pumps successively to exhaust the chamber.

摘要翻译： 一种爆炸检测系统，包括样品注入区域，用于产生由离子注入区域注入的样品的离子的离子源区域，用于分析离子质量的质量分析区域，用于加热样品注入区域的加热器和离子源 区域，用于排出其中设置质量分析区域的室的多个泵，以及用于控制区域和多个泵的控制器。 控制器进行控制，以便利用加热器加热样品注入区域和离子源区域，然后减少供给到加热器的加热电力，以防止超过预定的电功率值，并且依次驱动多个泵 排气室。

公开(公告)号：US5561300A

公开(公告)日：1996-10-01

申请号：US994968

申请日：1992-12-22

申请人： Yasuo Wada ,  Seiichi Kondo ,  Tsuyoshi Uda ,  Masukazu Igarashi ,  Hiroshi Kajiyama ,  Hisashi Nagano ,  Akito Sakurai ,  Tsuneo Ichiguchi

发明人： Yasuo Wada ,  Seiichi Kondo ,  Tsuyoshi Uda ,  Masukazu Igarashi ,  Hiroshi Kajiyama ,  Hisashi Nagano ,  Akito Sakurai ,  Tsuneo Ichiguchi

IPC分类号： G01Q90/00 ,  G11B9/00 ,  G11C11/34 ,  G11C13/00 ,  G11C19/00 ,  H01L27/06 ,  H01L27/085 ,  H01L49/00 ,  H03F3/04 ,  H03K17/51 ,  H03K17/54 ,  H03K17/56 ,  H03K19/02 ,  H03K19/08 ,  H01J37/30 ,  H02B1/24

CPC分类号： B82Y15/00 ,  B82Y10/00 ,  G11B9/14 ,  G11B9/1463 ,  G11C11/34 ,  G11C13/00 ,  G11C19/00 ,  H01L27/06 ,  H01L27/085 ,  H01L49/00 ,  H01L49/006 ,  H03F3/04 ,  H03K17/51 ,  H03K17/545 ,  H03K17/56 ,  H03K19/02 ,  H03K19/08 ,  G11C13/025 ,  G11C2213/81 ,  G11C2216/08 ,  Y10S977/94 ,  Y10T307/74 ,  Y10T307/937

摘要： In an atomic switch, opposite ends of an atom wire are connected to an input and output, and a switching gate is connected to a switching power supply. An input signal is outputted when a switching atom is connected to the atom wire, whereas an input signal is not outputted when the switching atom is moved to disconnect from the atom wire. There are provided an atom wire having a plurality of atoms arranged in a line or in a plurality of lines, in a ring shape, or in a curved line, and a switching gate made of an atom wire. The atom wire is switched by the field effect of the switching gate.

摘要翻译： 在原子开关中，原子线的相对端连接到输入和输出，并且开关栅极连接到开关电源。 当切换原子连接到原子线时输出输入信号，而当切换原子移动以与原子线分离时，输出信号不输出。 提供一种原子线，其具有以线状或多条排列成环状或曲线的多个原子以及由原子线构成的开关栅极。 原子线由开关栅极的场效应切换。