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公开(公告)号：US06930141B2
公开(公告)日：2005-08-16
申请号：US10410068
申请日：2003-04-09
申请人： Matthew Stewart Gebhart , Deborah Gay Fradkin , Bonnie Elizabeth Baker , John Michael Friel , Steven Scott Edwards , Caren Ann Puschak , Cindy Eckert , Ralph Craig Even
发明人： Matthew Stewart Gebhart , Deborah Gay Fradkin , Bonnie Elizabeth Baker , John Michael Friel , Steven Scott Edwards , Caren Ann Puschak , Cindy Eckert , Ralph Craig Even
IPC分类号： C08L27/04 , C08L33/02 , C08L33/06 , C08L53/02 , C09D133/04 , C09D133/06 , C08L33/04
CPC分类号： C08L33/06 , C08L27/04 , C08L33/02 , C08L53/02 , C09D133/04 , C09D133/06 , C08L33/00 , C08L2666/06 , C08L2666/04
摘要： An aqueous polymer blend composition including a predominant amount of soft polymer particles and a minor amount of hard polymer particles is provided. The soft polymer particles contain, as copolymerized units, 70 to 99.7% by weight monoethylenically unsaturated (meth)acrylic monomer and from 0.3 to 10% by weight monoethylenically unsaturated acid monomer, based on weight of soft polymer particles. The soft polymer particles are made by a select process including redox polymerization or polymerization in the presence of excess unreacted monomer. The aqueous polymer blend composition is useful for preparing dry coatings having improved dirt pickup resistance and acceptable scrub resistance. A method is provided for preparing a dry coating from the aqueous polymer blend composition.
摘要翻译： 提供了包含主要量的软聚合物颗粒和少量硬聚合物颗粒的含水聚合物共混物组合物。 作为共聚单元，软质聚合物颗粒含有基于软聚合物颗粒重量的70-99.7重量％单烯属不饱和（甲基）丙烯酸单体和0.3-10重量％单烯属不饱和酸单体。 软聚合物颗粒通过选择的方法制备，包括在过量未反应单体的存在下进行氧化还原聚合或聚合。 水性聚合物共混物组合物可用于制备具有改进的耐污垢吸附性和可接受的耐擦洗性的干燥涂层。 提供了一种从聚合物共混混合物组合物制备干燥涂层的方法。
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公开(公告)号：US06214467B1
公开(公告)日：2001-04-10
申请号：US09357181
申请日：1999-07-20
申请人： Steven Scott Edwards , John Michael Friel , Bernhard Helmut Lieser , Alvin Michael Maurice , Edwin Hugh Nungesser , Robert David Solomon
发明人： Steven Scott Edwards , John Michael Friel , Bernhard Helmut Lieser , Alvin Michael Maurice , Edwin Hugh Nungesser , Robert David Solomon
IPC分类号： B32B2720
CPC分类号： C08F220/04 , C01P2004/62 , C01P2006/60 , C08F212/08 , C08F220/06 , C08F265/02 , C08F265/04 , C08F265/06 , C08F2220/1858 , C08F2220/281 , C08K9/12 , C09C1/3676 , C09C3/10 , Y10T428/2998
摘要： Polymer-pigment composites, aqueous dispersions of polymer-pigment composites and coating compositions containing the polymer-pigment composites are disclosed, wherein the polymer is formed from terminally-unsaturated oligomers containing acid functionality.
摘要翻译： 公开了聚合物 - 颜料复合材料，聚合物 - 颜料复合材料的水分散体和包含聚合物 - 颜料复合材料的涂料组合物，其中聚合物由含有酸官能团的末端不饱和低聚物形成。
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公开(公告)号：US06921432B2
公开(公告)日：2005-07-26
申请号：US10214509
申请日：2002-08-08
CPC分类号： C09D17/004
摘要： A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.
摘要翻译： 公开了许多稳定的混合物，其包含特定组合和增量剂颜料和增稠剂的含量。 这些稳定的混合物尤其可以在使用前涂料或作为涂料中的常规组分的涂料或使用不透明颜料的其它最终用途的方法中作为混合物使用。
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4.发明授权Method of improving viscosity stability upon addition of an aqueous tinting composition 失效添加水性着色组合物时提高粘度稳定性的方法公开(公告)号：US06812278B2
公开(公告)日：2004-11-02
申请号：US10025707
申请日：2001-12-26
申请人： Jerome Michael Harris , Henry Jude Eichman , Homayoun Jamasbi , Dennis Paul Lorah , John Michael Friel
发明人： Jerome Michael Harris , Henry Jude Eichman , Homayoun Jamasbi , Dennis Paul Lorah , John Michael Friel
IPC分类号： C08J300
CPC分类号： C09B67/0066 , C09B67/0063 , C09D7/43 , C09D7/45 , C09D7/80 , C09D17/001
摘要： An aqueous tinting composition containing a pigment and a select dispersing resin is disclosed. In addition, a method of improving the viscosity stability of an aqueous coating composition upon the addition of the aqueous tinting composition containing a pigment and a select dispersing resin is disclosed.
摘要翻译： 公开了含有颜料和选择性分散树脂的水性着色组合物。 此外，公开了在添加含有颜料和选择分散树脂的水性着色组合物时改善水性涂料组合物的粘度稳定性的方法。
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公开(公告)号：US06689824B2
公开(公告)日：2004-02-10
申请号：US09785637
申请日：2001-02-16
申请人： John Michael Friel , John William Hook, III , Bernhard Helmut Lieser , Jerry William Washel , Dennis Paul Lorah , Donald Craig Schall , Ann Robertson Hermes
发明人： John Michael Friel , John William Hook, III , Bernhard Helmut Lieser , Jerry William Washel , Dennis Paul Lorah , Donald Craig Schall , Ann Robertson Hermes
IPC分类号： F21V722
CPC分类号： B01F13/1055 , B01F13/1063 , B01F15/00123 , B01F15/00305 , B44D2/002 , B44D3/003 , B44D3/08 , C09D5/004 , C09D7/40 , C09D7/80 , C09D17/008
摘要： Sets of prepaints useful for forming a road-marking paint line are provided. Also provided are methods which permit the person applying the road-marking paint to vary the properties of the road-marking paint at the application point to suit the ambient conditions, including temperature, humidity, traffic flow and the like.
摘要翻译： 提供了一些用于形成道路标线漆线的预涂料。 还提供了允许使用道路标线漆的人改变应用点处的道路标线漆的特性以适应包括温度，湿度，交通流量等在内的环境条件的方法。
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公开(公告)号：US06613832B2
公开(公告)日：2003-09-02
申请号：US09785389
申请日：2001-02-16
申请人： John Michael Friel , John William Hook, III , Jerry William Washel , Dennis Paul Lorah , James Alexander Costanzo
发明人： John Michael Friel , John William Hook, III , Jerry William Washel , Dennis Paul Lorah , James Alexander Costanzo
IPC分类号： C09C136
CPC分类号： C09J201/00 , B01F13/1055 , B01F13/1063 , B01F15/00123 , B01F15/00305 , B01F2215/005 , B44D2/002 , B44D3/003 , B44D3/08 , C09D7/40 , C09D7/80 , C09D17/008
摘要： Sets of fluid premixes useful for adhesives and caulks are provided. Also provided are methods of providing adhesive lines and a caulk lines using the sets of premixes. Further provided are ranges of adhesives and caulks based on the adhesive and caulk lines. Utilizing these methods the manufacturer, seller, or user can to adjust the adhesive or caulk at the point of manufacture, sale, or use to suit the processing and end-use conditions, in addition to the other benefits offered by delayed product differentiation.
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公开(公告)号：US5731377A
公开(公告)日：1998-03-24
申请号：US527
申请日：1993-01-08
申请人： John Michael Friel
发明人： John Michael Friel
IPC分类号： C09D5/02 , C08L33/06 , C09D5/00 , C09D125/14 , C09D133/00 , C09D133/04 , C09D133/06 , C09D201/00 , C08J3/00 , C08K3/20 , C08L33/00 , C08L33/02
CPC分类号： C09D125/14 , C09D133/06 , C08L2205/02 , C08L33/06
摘要： A polymer blend useful as a binder in an aqueous coating composition containing no coalescent is provided. The polymer blend comprises from about 20 to about 60 weight percent of a hard emulsion polymer, having a glass transition temperature greater than about room temperature, and from about 80 to about 40 weight percent of a soft emulsion polymer, having a glass transition temperature less than about 15 degrees Centigrade.
摘要翻译： 提供了在不含聚结剂的水性涂料组合物中用作粘合剂的聚合物共混物。 聚合物共混物包含约20至约60重量％的具有玻璃化转变温度大于约室温的硬乳液聚合物和约80至约40重量％的软乳液聚合物，其玻璃化转变温度较低 比大约15摄氏度。
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公开(公告)号：US07939572B2
公开(公告)日：2011-05-10
申请号：US11210207
申请日：2005-08-23
IPC分类号： C08F2/16
摘要： An aqueous dispersion of polymeric particles, the particles including: from 5% to 80% by weight, based on the weight of the polymeric particles, of a first polymer including at least one copolymerized ethylenically unsaturated monomer; and, substantially encapsulating the first polymer, from 20% to 95% by weight, based on the weight of the polymeric particles, of a second polymer including at least one copolymerized ethylenically unsaturated monomer, the second polymer having a Tg of from −40° C. to 30° C., wherein at least 90 weight % of the second polymer is formed by polymerization at a temperature of from 5° C. to 65° C. is provided. The invention also relates to a process for forming the aqueous dispersion of polymeric particles and an aqueous coating composition including the aqueous dispersion of polymer particles, a method for providing a coated substrate, and the coated substrate so provided.
摘要翻译： 聚合物颗粒的水分散体，所述颗粒包括：基于聚合物颗粒重量的5重量％至80重量％的包含至少一种共聚烯键式不饱和单体的第一聚合物; 和基本上包封第一聚合物的基于聚合物颗粒的重量的20重量％至95重量％的包含至少一种共聚的烯属不饱和单体的第二聚合物，第二聚合物的Tg为-40℃ 至30℃，其中通过在5℃至65℃的温度下聚合形成至少90重量％的第二聚合物。 本发明还涉及形成聚合物颗粒的水性分散体的方法和包含聚合物颗粒的水性分散体的水性涂料组合物，提供涂布的基材的方法和如此提供的涂布的基材。
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公开(公告)号：US20100113646A1
公开(公告)日：2010-05-06
申请号：US12655662
申请日：2010-01-05
IPC分类号： C08L67/06
CPC分类号： C08F265/06 , C08J3/05 , C08L51/003 , C09D151/003 , Y10T428/2987 , C08L2666/02
摘要： An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, when dry, at least one void; and, substantially encapsulating the first polymer, at least one second polymer comprising, as polymerized units, at least one ethylenically unsaturated monomer.
摘要翻译： 提供聚合物颗粒的水分散体及其形成方法。 颗粒包含第一聚合物，当干燥时包含至少一个空隙; 和基本上包封第一聚合物的至少一种第二聚合物，其包含作为聚合单元的至少一种烯属不饱和单体。
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公开(公告)号：US07691942B2
公开(公告)日：2010-04-06
申请号：US11507341
申请日：2006-08-21
CPC分类号： C08F265/06 , C08J3/05 , C08L51/003 , C09D151/003 , Y10T428/2987 , C08L2666/02
摘要： An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, when dry, at least one void; and, substantially encapsulating the first polymer, at least one second polymer comprising, as polymerized units, at least one ethylenically unsaturated monomer.
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