公开(公告)号：US06756471B1

公开(公告)日：2004-06-29

申请号：US10129110

申请日：2002-05-13

申请人： Matthias Kroner ,  Karl-Heinz Büchner ,  Johannes Perner

发明人： Matthias Kroner ,  Karl-Heinz Büchner ,  Johannes Perner

IPC分类号： C08G6300

CPC分类号： C04B24/2647 ,  C04B2103/30 ,  C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/061 ,  C08F290/062 ,  C08F290/14 ,  C08G65/3322 ,  C08L71/02 ,  C08F290/00 ,  C08L2666/04

摘要： The invention relates to a process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains and having molecular weights of from 15,000 to 65,000 by solution polymerization of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols which are masked on the end groups at one end, if desired together with another monomer in at least one hydrocarbon at monomer concentrations of from 70 to 95% by weight in the presence of free-radical-forming polymerization initiators and, if desired, polymerization regulators at temperatures of up to 200° C., removal of the solvent used in the solution polymerization, and dissolution of the polymers in water to give from 50 to 80% strength by weight solutions, with polymers containing acid groups being neutralized if desired.

摘要翻译： 本发明涉及一种制备含聚亚烷基二醇醚侧链的水溶性聚合物的方法，其分子量为15,000至65,000，通过在末端基上被掩蔽的烯属不饱和羧酸和聚亚烷基二醇的酯的溶液聚合 一方面，如果需要，在形成自由基的聚合引发剂的存在下，在70至95重量％的单体浓度下，在至少一种烃中与另一种单体一起使用，如果需要，聚合调节剂的温度高达200° C.去除溶液聚合中使用的溶剂，并将聚合物溶解在水中，得到50-80％重量的强度溶液，如果需要，含有酸基团的聚合物被中和。

公开(公告)号：US06855762B1

公开(公告)日：2005-02-15

申请号：US10130611

申请日：2000-11-16

申请人： Matthias Kroner ,  Karl-Heinz Büchner ,  Johannes Perner ,  Hans-Jürgen Raubenheimer ,  Dieter Faul

发明人： Matthias Kroner ,  Karl-Heinz Büchner ,  Johannes Perner ,  Hans-Jürgen Raubenheimer ,  Dieter Faul

IPC分类号： C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/14 ,  C08G65/332 ,  C08L71/02 ,  C08L33/00

CPC分类号： C08G65/3322 ,  C08F8/44 ,  C08F290/06 ,  C08F290/061 ,  C08F290/14 ,  C08L71/02 ,  C08F290/00 ,  C08L2666/04

摘要： A process for the preparation of water-soluble polymers of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols by azeotropic esterification, in the presence of organic solvents which form an azeotrope with water, of ethylenically unsaturated carboxylic acids with polyalkylene oxides which are capped at one end by end groups, to a degree of at least 85 wt %, followed by free-radical polymerization of the resulting esters optionally together with other ethylenically unsaturated monomers, in aqueous medium, wherein the organic solvents are removed by azeotropic distillation from the reaction mixture during polymerization and the water that is removed by distillation is recycled or the quantity of water removed by distillation from the reaction mixture is replaced by a feed of fresh water.

摘要翻译： 烯键式不饱和羧酸与聚亚烷基二醇的水溶性聚合物的制备方法，在有机溶剂与水形成共沸物的情况下通过共沸酯化制备烯键式不饱和羧酸与聚合环氧烷封端的聚烯烃 末端以达到至少85重量％的程度，然后将所得酯任选地与其它烯属不饱和单体一起在水性介质中进行自由基聚合，其中通过共沸蒸馏从反应混合物中除去有机溶剂 并且通过蒸馏除去的水被再循环，或者通过蒸馏从反应混合物中除去的水量被淡水的进料代替。

公开(公告)号：US06846882B2

公开(公告)日：2005-01-25

申请号：US10239053

申请日：2001-03-27

申请人： Matthias Kroner ,  Johannes Perner ,  Karl-Heinz Büchner ,  Jochen Wild ,  Jürgen Pfister

发明人： Matthias Kroner ,  Johannes Perner ,  Karl-Heinz Büchner ,  Jochen Wild ,  Jürgen Pfister

IPC分类号： C08G81/02 ,  C04B24/26 ,  C08F8/14 ,  C08F8/30

CPC分类号： C04B24/2658 ,  C04B2103/408 ,  C08G81/025

摘要： Polymers containing acid groups are modified by reaction of (a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4, with (b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acids at up to 250° C.

摘要翻译： 含有酸基的聚合物通过（a）包含至少5重量％的含酸基团的共聚单烯属不饱和单体的聚合物的反应进行改性，摩尔质量为200至100,000，可通过单烯键不饱和的自由基聚合获得 在存在或不存在其它单烯键式不饱和单体的情况下，在基于聚合中使用的单体的至少4重量％存在下，在水溶液中的硫在其中氧化的水溶性硫化合物 状态+4，其中（b）在一端被封端的聚亚烷基二醇，烷基聚亚烷基二醇胺或其混合物，或基于混合物，至多30重量％指定的两种化合物中的至少一种的混合物， 的氨，胺，醇，羟基羧酸或至多250℃的氨基羧酸

公开(公告)号：US06545067B1

公开(公告)日：2003-04-08

申请号：US09805773

申请日：2001-03-16

申请人： Karl-Heinz Büchner ,  Michael Ehle ,  Johannes Perner ,  Knut Oppenländer ,  Markus Hartmann ,  Wolfgang Günther ,  Matthias Kroner

发明人： Karl-Heinz Büchner ,  Michael Ehle ,  Johannes Perner ,  Knut Oppenländer ,  Markus Hartmann ,  Wolfgang Günther ,  Matthias Kroner

IPC分类号： C08K300

CPC分类号： C04B40/0039 ,  C04B24/121 ,  C04B24/125 ,  C04B24/32 ,  C04B2103/30 ,  C04B2103/50 ,  C04B24/2647 ,  C04B24/122

摘要： Mixtures of at least one polycarboxylate-based plasticizer for cement-comprising mineral building materials, and butoxylated polyalkylenepolyamines or their salts as air detrainers, and the use of such mixtures as additives for mineral building materials comprising cement, are described.

摘要翻译： 描述了至少一种用于包含水泥的矿物建筑材料的聚羧酸酯类增塑剂和作为空气脱盐剂的丁氧基化聚亚烷基多胺或其盐的混合物，以及这些混合物作为包含水泥的矿物建筑材料的添加剂的用途。

公开(公告)号：US06849703B2

公开(公告)日：2005-02-01

申请号：US10136534

申请日：2002-05-02

申请人： Matthias Kroner ,  Karl-Heinz Büchner ,  Gregor Brodt

发明人： Matthias Kroner ,  Karl-Heinz Büchner ,  Gregor Brodt

IPC分类号： C04B7/52 ,  C04B24/26 ,  C04B24/32 ,  C04B103/52 ,  C08F2/10 ,  C08F2/38 ,  C08F6/10 ,  C08F8/00 ,  C08F20/28 ,  C08F290/06 ,  C08G65/332 ,  C08L71/02 ,  C08F220/46

CPC分类号： C04B24/2647 ,  C04B2103/0053 ,  C04B2103/006 ,  C04B2103/408 ,  C04B2103/52 ,  C08F290/062 ,  C08G65/3322 ,  C08L71/02 ,  C08L2666/04

摘要： Water-soluble polymers of esters made from acrylic acid and alkylpolyalkylene glycols, obtainable by azeotropic esterification of a mixture of acrylic acid and alkylpolyalkylene glycol in a molar ratio of from 2 to 3:1 in the presence of at least 85% by weight, based on the alkylpolyalkylene glycol, of an organic solvent which forms an azeotrope with water, followed by free-radical polymerization, in an aqueous medium, of the mixture obtained during the esterification, where the organic solvent is distilled off azeotropically from the reaction mixture during the polymerization, and the water removed by distillation is returned to the mixture or replaced by a feed of fresh water, and preparation and use of these polymers as an additive to cementitious systems.

摘要翻译： 由丙烯酸和烷基聚亚烷基二醇制成的酯的水溶性聚合物，其可通过丙烯酸和烷基聚亚烷基二醇的混合物在摩尔比为2至3:1的条件下在至少85重量％的存在下共价酯化 在烷基聚亚烷基二醇上与在水中形成共沸物的有机溶剂，然后在水性介质中自由基聚合在酯化期间获得的混合物，其中在反应混合物期间从反应混合物共沸蒸馏出有机溶剂 通过蒸馏除去的水返回到混合物中或用淡水的进料代替，并且这些聚合物的制备和使用作为水泥体系的添加剂。

公开(公告)号：US06872848B2

公开(公告)日：2005-03-29

申请号：US10450529

申请日：2001-12-14

申请人： Matthias Kroner ,  Jürgen Pfister ,  Dieter Faul ,  Hans-Jürgen Raubenheimer ,  Karl-Heinz Büchner

发明人： Matthias Kroner ,  Jürgen Pfister ,  Dieter Faul ,  Hans-Jürgen Raubenheimer ,  Karl-Heinz Büchner

IPC分类号： C08G65/48 ,  C08G65/332 ,  C07C69/63

CPC分类号： C08G65/3322

摘要： Alkylpolyalkylene glycol esters of monoethylenically unsaturated carboxylic acids are prepared by esterifying (a) monoethylenically unsaturated carboxylic acids with (b) polyalkylene glycols which are endcapped at one end, in the absence of a solvent and in the presence of polymerization inhibitors and esterification catalysts at not more than 160° C. by a process in which the esterification is first carried out under atmospheric pressure or at up to 50 bar, the water formed in the esterification is then distilled from the reaction mixture at from 10 to 500 mbar and the esterification is then continued under atmospheric pressure or at up to 50 bar.

摘要翻译： 单烯键式不饱和羧酸的烷基聚亚烷基二醇酯通过（a）单烯键式不饱和羧酸与（b）在不存在溶剂的情况下在一端封端的聚亚烷基二醇酯化，并且在不存在聚合抑制剂和酯化催化剂的情况下 通过首先在大气压或高达50巴下进行酯化的方法超过160℃，然后在10-500毫巴下从反应混合物中蒸馏酯化产生的水，酯化为 然后继续在大气压或高达50巴。

公开(公告)号：US20090025896A1

公开(公告)日：2009-01-29

申请号：US12278408

申请日：2007-01-30

申请人： Karl-Heinz Büchner ,  Stephan Nied ,  Alexander Gothlich ,  Frank Klippel ,  Gunnar Schornick

发明人： Karl-Heinz Büchner ,  Stephan Nied ,  Alexander Gothlich ,  Frank Klippel ,  Gunnar Schornick

IPC分类号： D21H17/37 ,  C02F5/14 ,  C02F5/10

CPC分类号： C02F5/14 ,  C02F1/441 ,  C02F1/56 ,  C02F5/10 ,  C02F5/12 ,  C02F2103/08 ,  C02F2103/10 ,  C02F2103/28 ,  C02F2303/04 ,  C02F2303/08 ,  C08F220/06 ,  C08F222/06 ,  C08F230/02 ,  C09K8/12 ,  Y02A20/131

摘要： A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of at least 3000 g/mol to at most 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and other ethylenically unsaturated comonomers, the polymerization for producing the copolymer being performed in the presence of from 0.01 to 100 mol % of at least one base, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids, the quantitative figures in % by weight being respectively based on the total amount of all monomers used.

摘要翻译： 一种用于控制包含硅酸盐的水性体系增稠的方法，其包括向所述水性体系中加入至少一种平均分子量Mw至少为3000g / mol至至多60000g / mol的共聚物，并且所述共聚物由 基本上从单烯键式不饱和一元羧酸，单烯键式不饱和二羧酸和其它烯属不饱和共聚单体基本上无规共聚物，基于所有COOH的总量，在0.01至100摩尔％的至少一个碱的存在下进行共聚合 一元羧酸和二羧酸的基团，以重量％计的定量数据分别基于所使用的所有单体的总量。