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    Process for the preparation of polyester polyols
    1.
    发明授权
    Process for the preparation of polyester polyols 失效
    制备聚酯多元醇的方法

    公开(公告)号：US4845266A

    公开(公告)日：1989-07-04

    申请号：US36574

    申请日：1987-04-10

    申请人： Matthias Marx ,  Joachim Jaehme ,  Joachim Streu

    发明人： Matthias Marx ,  Joachim Jaehme ,  Joachim Streu

    IPC分类号： C08G63/91 ,  C08G63/18 ,  C08G63/66 ,  C08G63/87

    CPC分类号： C08G63/18 ,  C08G63/66 ,  C08G63/87

    摘要： A process for the preparation of polyester polyols having an acid number of less than 1, a hydroxyl number of approximately 20 to about 400, and having a functionality of efficaciously 2 to 3, wherein polycarboxylic acids and/or their anhydrides and multivalent alcohols are polycondensed, preferably in the absence of common esterification catalysts, at temperatures of from about 150.degree. to 250.degree. C., optionally under reduced pressure, up to an acid number of from 20 to 5. The resulting polycondensate is then oxyalkylated per carboxyl group using from 1 to 5 moles of an alkylene oxide, for example 1,2-propylene oxide and/or preferably ethylene oxide, in the presence of at least one tertiary amine catalyst from the group consisting of N-methylimidazole, diazabicyclo[2,2,2]octane, diazabicyclo[5,4,0]undec-7-ene and pentamethyldiethylenetriamine and mixtures thereof, in a quantity of from about 0.001 to 1.0 weight percent based on the weight of the polycondensate, at temperatures from about 100.degree. to 170.degree. C. and under a pressure of about 1 to 10 bar.

    摘要翻译： 一种制备酸值小于1，羟值为约20至约400，具有有效2至3的官能团的聚酯多元醇的方法，其中多元羧酸和/或其酸酐和多元醇是缩聚的 ，优选在不存在共同的酯化催化剂的情况下，在约150-250℃的温度下，任选在减压下，直到酸值为20-5。然后将所得缩聚物按羧基烷氧基化，使用 在至少一种叔胺催化剂存在下，将1-5摩尔环氧烷，例如1,2-环氧丙烷和/或优选环氧乙烷在由N-甲基咪唑，二氮杂双环[2,2,2 ]辛烷，二氮杂双环[5,4,0]十一碳-7-烯和五甲基二亚乙基三胺及其混合物的量为约0.001至1.0重量％，基于缩聚物的重量， 在100℃至170℃和约1至10巴的压力下进行。

    Polyester polyols liquid at room temperature and their preparation and use in preparing plastics by polyisocyanate addition polymerization
    2.
    发明授权
    Polyester polyols liquid at room temperature and their preparation and use in preparing plastics by polyisocyanate addition polymerization 失效
    聚酯多元醇液体在室温下及其制备和用途通过多异氰酸酯加成聚合制备塑料

    公开(公告)号：US4778830A

    公开(公告)日：1988-10-18

    申请号：US127270

    申请日：1987-12-01

    申请人： Joachim Streu ,  Matthias Marx ,  Peter Weyland ,  Dietrich Scherzer ,  Wolfgang Straehle

    发明人： Joachim Streu ,  Matthias Marx ,  Peter Weyland ,  Dietrich Scherzer ,  Wolfgang Straehle

    IPC分类号： C08G18/42 ,  C08G18/46 ,  C08G63/16 ,  C08G18/14

    CPC分类号： C08G18/4615 ,  C08G18/42 ,  C08G18/4238 ,  C08G63/16

    摘要： Disclosed are polyester polyols liquid at 25.degree. C., having an average functionality of from 2 to 3, a hydroxyl number of from 25 to 400, an acid number smaller than 10 and a viscosity at 25.degree. C. of from 200 to 10,000 mPas, which contain in bonded form units having at least one of the structures--O--CH.sub.2 --CH(CH.sub.3)--CH.sub.2 --CH.sub.2 --CH.sub.2 --O--,--O--CH.sub.2 --CH(C.sub.2 H.sub.5)--CH.sub.2 --CH.sub.2 --O--,--OC--CH(CH.sub.3)--CH.sub.2 --CH.sub.2 --CO--and--OC--CH(C.sub.2 H.sub.5)--CH.sub.2 --CO--which are prepared by the polycondensation or transesterification of 2-methyl-1,5-pentanediol, 2-ethyl-1,4-butanediol, 2-methyl-glutaric acid and/or 2-ethyl succinic acid or their derivatives, optionally while using other organic polycarboxylic acids and multivalent aliphatic alcohols and are useful for preparing non-cellular or cellular polyurethane plastics or polyurethane-polyurea plastics.

    摘要翻译： 公开了在25℃下的平均官能度为2至3，羟基数为25至400，酸值小于10，25℃下的粘度为200至10,000mPas的聚酯多元醇液体 （CH 3）-CH 2 -CH 2 -CH 2 -O - ， - O-CH 2 -CH（C 2 H 5）-CH 2 -CH 2 -O-的结构中至少一个具有键合形式的单元， -OC-CH（CH 3）-CH 2 -CH 2 -CO-和-OC-CH（C 2 H 5）-CH 2 -CO-，它们是通过2-甲基-1,5-戊二醇，2-乙基-2-甲基-1,5-戊二醇的缩聚或酯交换制备的， 1,4-丁二醇，2-甲基 - 戊二酸和/或2-乙基琥珀酸或其衍生物，任选地同时使用其它有机多元羧酸和多价脂族醇，并且可用于制备非细胞或细胞聚氨酯塑料或聚氨酯 - 聚脲塑料。

    Process for the preparation of primarily closed cell rigid foams containing urethane groups or urethane- and isocyanurate groups, and their use
    5.
    发明授权
    Process for the preparation of primarily closed cell rigid foams containing urethane groups or urethane- and isocyanurate groups, and their use 失效
    用于制备含有氨基甲酸酯基团或氨基甲酸酯和异氰脲酸酯基团的主要闭孔硬质泡沫的方法及其用途

    公开(公告)号：US4897431A

    公开(公告)日：1990-01-30

    申请号：US127269

    申请日：1987-12-01

    申请人： Dietrich Scherzer ,  Joachim Streu

    发明人： Dietrich Scherzer ,  Joachim Streu

    IPC分类号： C08G18/42 ,  C08G18/46 ,  C08G18/76

    CPC分类号： C08G18/7664 ,  C08G18/42 ,  C08G18/4238 ,  C08G18/4615 ,  C08G2101/0025 ,  C08G2101/0041 ,  C08G2105/02

    摘要： Disclosed is a process for the preparation of primarily closed cell rigid foams, useful for strengthening mechanical construction parts or for use as insulation material, containing urethane groups, or urethane and isocyanurate groups where the polyol component is a higher molecular weight polyester polyol, containing in bonded form units having one or more of the structures: ##STR1## or a mixture of said polyester polyol and known polyester polyols and/or polyether polyols.

    摘要翻译： 公开了一种用于制备主要是闭孔刚性泡沫的方法，其可用于加强机械结构部件或用作含有氨基甲酸酯基团的绝缘材料，或者聚氨酯和异氰脲酸酯基团，其中多元醇组分是较高分子量的聚酯多元醇，其含有 具有一个或多个结构的键合形式单元：-O-CH 2 -CH（CH 3）-CH 2 -CH 2 -CH 2 O-，（I）-O-CH 2 -CH（C 2 H 5）-CH 2 -CH 2 -O - ，（II ）-OC-CH（CH 3）-CH 2 -CH 2 -CO-或（III）-OC-CH 9 C 2 H 5）-CH 2 -CO-（IV）或所述聚酯多元醇与已知的聚酯多元醇和/或聚醚多元醇的混合物。

    Process for the preparation of polyester polyols, based on 2-methyl-1,4-butanediol, which are liquid at room temperature, and their use for the preparation of plastic materials
    8.
    发明授权
    Process for the preparation of polyester polyols, based on 2-methyl-1,4-butanediol, which are liquid at room temperature, and their use for the preparation of plastic materials 失效
    用于制备在室温下为液体的基于2-甲基-1,4-丁二醇的聚酯多元醇及其在制备塑料材料中的用途的方法

    公开(公告)号：US4731392A

    公开(公告)日：1988-03-15

    申请号：US36298

    申请日：1987-04-09

    申请人： Joachim Streu ,  Wolfgang Straehle

    发明人： Joachim Streu ,  Wolfgang Straehle

    IPC分类号： C08G18/42 ,  C08G63/16 ,  C08G18/14

    CPC分类号： C08G18/4238 ,  C08G63/16

    摘要： This invention relates to polyester polyols which are liquid at 25.degree. C. and contain units having the structure --OCH.sub.2 --CH(CH.sub.3)--CH.sub.2 CH.sub.2 O-- which are bound together and have an average functionality of from about 2 to 3, a hydroxyl number of from about 25 to 300, an acid number of less than about 2, and a viscosity of from about 200 to 10.sup.5 mPas at 25.degree. C. The polyols are prepared through polycondensation in the molten state, in the presence of or absence of esterification catalysts, of an aliphatic di- and/or polycarboxylic acid and/or di- and/or polycarboxylic acid ahydride and 2-methyl-1,4-butanediol or mixtures comprised of 2-methyl-1,4-butanediol and at least one linear or branched, aliphatic di- through tetravalent alcohol, which optionally contains ether bridges and has a 2-methyl-1,4-butanediol content of at least 20 weight percent based on the weight of the alcohol mixture. The polyester polyols are suited for the preparation of non-cellular or cellular polyurethane plastics or polyurethane-polyurea plastics and preferably polyurethane elastomers, using the polyisocyanates addition polymerization process.

    摘要翻译： 本发明涉及在25℃下为液体并含有结构为-OCH 2 -CH（CH 3）-CH 2 CH 2 O-的单元的聚酯多元醇，其结合在一起并具有约2至3的平均官能度，羟基数 约25至300，酸值小于约2，在25℃下的粘度为约200至105mPas。多元醇通过在存在或不存在酯化催化剂的情况下在熔融状态下缩聚制备 的脂族二 - 和/或多羧酸和/或二 - 和/或多羧酸酐和2-甲基-1,4-丁二醇或由2-甲基-1,4-丁二醇和至少一种线性 或支链的脂族二价至四价醇，其任选地含有醚桥，并且基于醇混合物的重量，其具有至少20重量％的2-甲基-1,4-丁二醇含量。 聚酯多元醇适用于使用多异氰酸酯加成聚合方法制备非细胞或细胞聚氨酯塑料或聚氨酯 - 聚脲塑料，优选聚氨酯弹性体。

    Process for the preparation of non-cellular or cellular polyurethane elastomers in the presence of a polyester polyol containing therein titanium and/or tin compounds as catalysts
    9.
    发明授权
    Process for the preparation of non-cellular or cellular polyurethane elastomers in the presence of a polyester polyol containing therein titanium and/or tin compounds as catalysts 失效
    在其中含有钛和/或锡化合物作为催化剂的聚酯多元醇存在下制备非细胞或细胞聚氨酯弹性体的方法

    公开(公告)号：US4837245A

    公开(公告)日：1989-06-06

    申请号：US116633

    申请日：1987-11-04

    申请人： Joachim Streu ,  Wolfgang Straehle ,  Gerhard Ramlow

    发明人： Joachim Streu ,  Wolfgang Straehle ,  Gerhard Ramlow

    IPC分类号： C08G18/22 ,  C08G18/46

    CPC分类号： C08G18/22 ,  C08G18/46

    摘要： This invention relates to a process for the preparation of non-cellular or cellular polyurethane elastomers by the reaction of(a) an organic polyisocyanate, preferably in the form of NCO groups containing prepolymers and/or modified urethane group containing organic polyisocyanates with(b) a higher molecular weight compound having at least two reactive hydrogen atoms,(c) a polyester polyol containing tin and/or titanium compounds as catalysts, and optionally(d) a chain extending agent and/or crosslinking agent in the presence of(e) blowing agents,(f) auxiliaries and/or additiveswhereby from 0.1 to 10 parts by weight, based on 100 parts by weight of the (b) component, of a polyester polyol is used as a catalyst, which is prepared by the polycondensation of organic polycarboxylic acid with multivalent alcohols in the presence of from 0.002 to 5 weight percent, based on the weight of the polycondensation mixture, of a titanium and/or tin compound used as a catalyst at temperatures from 150.degree. to 200.degree. C., as well as using this catalyst in the preparation of plastics using the polyisocyanate addition polymerization process, preferably for preparing polyurethane-plastics.

    摘要翻译： 本发明涉及通过（a）有机多异氰酸酯，优选以含有预聚物和/或含有机多异氰酸酯的改性氨基甲酸酯基团的形式的有机多异氰酸酯的反应制备非细胞或细胞聚氨酯弹性体的方法，（b） 具有至少两个反应性氢原子的较高分子量化合物，（c）含有锡和/或钛化合物作为催化剂的聚酯多元醇，以及任选地（d）在（e）存在下的扩链剂和/或交联剂， 发泡剂，（f）助剂和/或添加剂，其中基于100重量份（b）组分的聚酯多元醇为0.1至10重量份，其用作催化剂，其通过 有机多元羧酸与多元醇在0.002至5重量百分比的存在下，以缩聚混合物的重量计，用作催化剂的钛和/或锡化合物在温度 150℃至200℃，以及使用该催化剂在使用多异氰酸酯加成聚合方法制备塑料时，优选用于制备聚氨酯塑料。