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公开(公告)号：US5369186A
公开(公告)日：1994-11-29
申请号：US790630
申请日：1991-11-12
申请人： Maurizio Galimberti , Umberto Giannini , Romano Mazzocchi , Enrico Albizzati , Umberto Zucchini
发明人： Maurizio Galimberti , Umberto Giannini , Romano Mazzocchi , Enrico Albizzati , Umberto Zucchini
IPC分类号： C08F8/00 , C08F8/12 , C08F8/26 , C08F10/00 , C08F210/00 , C08F210/06 , C08F210/16 , C08F214/16 , C08F226/06
CPC分类号： C08F210/00 , C08F210/06 , C08F210/16
摘要： Disclosed are polymers and copolymers of CH.sub.2 .dbd.CHR alpha olefins where R is hydrogen or a 1-6 carbon atom alkyl radical, containing in the chain from 0.1 to 40 mole % of monomeric units ##STR1## where X is selected from the group consisting of (CH.sub.2).sub.r CH.sub.2 CH.sub.2 Y ##STR2## where r=0-10, Y is a halogen atom, R.sup.1 is a hydrocarbon radical with 1-18 carbon atoms.
摘要翻译： 公开了CH2 =CHRα烯烃的聚合物和共聚物，其中R是氢或1-6个碳原子的烷基，其中链中含有0.1至40摩尔％的单体单元，其中X选自 （CH2）rCH2CH2Y CH2）rCHCH2（CH2）r + 2OCOR1（CH2）r + 2OR1（CH2）r + 2CH（COOR1）2（CH2）r + 2OH（CH2）r + 2CH2COOH
其中r = ，Y是卤素原子，R1是具有1-18个碳原子的烃基。 -
公开(公告)号：US5196496A
公开(公告)日：1993-03-23
申请号：US721049
申请日：1991-06-26
IPC分类号： C08F4/642 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F210/06
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/901
摘要： Essentially syndiotactic crystalline copolymers of propylene with minor proportions of 1-butene, endowed with good mechanical properties, lowered melting point and limited solubility in xylene at 25.degree. C. and the process for their preparation by polymerizing mixtures of propylene with 1-butene, by using catalysts obtained form stereorigid and chiral zirconium and hafnium compounds and from polymethylalumoxane compounds.
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3.发明申请公开(公告)号：US20050087906A1
公开(公告)日：2005-04-28
申请号：US10484494
申请日：2002-07-22
申请人： Renato Caretta , Maurizio Galimberti , Cesare Amurri , Cristiano Puppi , Giuseppe Ducoli , Enrico Albizzati
发明人： Renato Caretta , Maurizio Galimberti , Cesare Amurri , Cristiano Puppi , Giuseppe Ducoli , Enrico Albizzati
IPC分类号： B29C47/10 , B29B7/88 , B29C31/02 , B29C31/10 , B29C47/00 , B29C47/50 , B29K21/00 , B29K105/16 , C08J3/22 , B29C47/38 , B29C47/60
CPC分类号： B29C47/0004 , B29B7/42 , B29B7/48 , B29B7/603 , B29B7/7495 , B29B7/88 , B29C31/02 , B29C31/06 , B29C31/10 , B29C47/0009 , B29C47/1045 , B29C47/1063 , B29C47/1081 , B29C47/109 , B29C47/364 , B29C47/367 , B29C47/369 , B29C47/38 , B29K2021/00 , B29K2105/0005 , B29K2105/0085 , B29K2105/06 , B29K2105/16
摘要： A process for continuously producing an elastomeric composition includes providing at least one extruder, metering and feeding at least one elastomer, at least one filler, and ingredients different from elastomers and fillers into the at least one extruder, mixing and dispersing the at least one filler and the ingredients different from elastomers and fillers into the at least one elastomer using the at least one extruder, and extruding a resulting elastomeric composition. The at least one extruder includes the housing and at least one screw rotatably mounted in the housing. The housing includes at least one feed opening and a discharge opening. At least one of the ingredients different from elastomers and fillers includes a subdivided product including one or more minor ingredients dispersed in at least one thermoplastic binding agent. An apparatus for continuously producing the elastomeric composition is also disclosed.
摘要翻译： 用于连续生产弹性体组合物的方法包括提供至少一个挤出机，计量并将至少一种弹性体，至少一种填料和与弹性体和填料不同的成分进料至至少一个挤出机中，将至少一种填料 以及使用至少一种挤出机将不同于弹性体和填料的成分加入到至少一种弹性体中，并挤出所得的弹性体组合物。 所述至少一个挤出机包括壳体和可旋转地安装在壳体中的至少一个螺杆。 壳体包括至少一个进料口和排出口。 与弹性体和填料不同的成分中的至少一种包括包含分散在至少一种热塑性粘合剂中的一种或多种次要成分的细分产品。 还公开了用于连续生产弹性体组合物的设备。
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公开(公告)号：US06262215B1
公开(公告)日：2001-07-17
申请号：US09499481
申请日：2000-02-07
IPC分类号： C08F21016
CPC分类号： C08F210/18 , C08F210/16 , Y10S526/902 , Y10S526/916 , C08F2/14 , C08F210/06 , C08F210/08 , C08F2500/03 , C08F2500/21 , C08F2500/17 , C08F2500/20
摘要： Elastomeric ethylene/propylene or ethylene/propylene/polyene copolymers containing small amounts of one or more &agr;-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin.
摘要翻译： 通过淤浆法制备含有少量一种或多种α-烯烃的弹性体乙烯/丙烯或乙烯/丙烯/多烯共聚物，其中聚合反应在液态丙烯和α-烯烃的混合物中进行。
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公开(公告)号：US06331600B1
公开(公告)日：2001-12-18
申请号：US08841473
申请日：1997-04-22
IPC分类号： C08F21016
CPC分类号： C08F210/18 , C08F210/16 , Y10S526/943 , C08F4/6428 , C08F210/06 , C08F2500/17 , C08F2500/21 , C08F2500/15 , C08F2500/03
摘要： Novel copolymers of ethylene with propylene and optionally with minor proportions of a diene or polyene having good elastomeric properties in their uncured state. The copolymers are characterized by a structure in which the propylene is partially present in the form of short isotactic sequences. Tension set values (200%) of less than 15 are obtained by when the ethylene/propylene ratio has specific values and the intrinsic viscosity values are higher than 3.
摘要翻译： 乙烯与丙烯的新型共聚物和任选的少量二烯或其未固化状态下具有良好弹性体性质的多烯的共聚物。 共聚物的特征在于其中丙烯以短全同立构序列的形式部分存在的结构。 当乙烯/丙烯比具有特定值并且特性粘度值高于3时，获得小于15的张力设定值（200％）。
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6.发明授权Elastomeric copolymers of ethylene with .alpha.-olefins and process for their preparation 失效乙烯与α-烯烃的弹性共聚物及其制备方法
公开(公告)号：US6160071A
公开(公告)日：2000-12-12
申请号：US876864
申请日：1997-06-16
IPC分类号： C08F4/642 , C08F4/42 , C08F4/60 , C08F10/00 , C08F210/16 , C08F210/18 , C08J5/00 , C08F10/04
CPC分类号： C08F210/16 , Y10S526/943 , C08F2/14 , C08F210/18 , C08F2500/03 , C08F2500/08 , C08F2500/17 , C08F2500/20 , C08F2500/21 , C08F210/08
摘要： Amorphous copolymers of ethylene with .alpha.-olefins and optionally minor amounts of polyenes are disclosed, having the following characteristics:(A) the % by mole content of .alpha.-olefin in the copolymer (%.alpha.) and the ratio between the molar amount of .alpha.-olefin diads and the molar content of .alpha.-olefin in the copolymer (.alpha..alpha./.alpha.) satisfy the following relationship:(%.alpha.)-250(.alpha..alpha./.alpha.).gtoreq.10(B) less than 2% of the CH.sub.2 groups in the polymeric chain are in sequences (CH.sub.2).sub.n, wherein n is an even number.These copolymers are obtainable by operating in the presence of particular metallocene-based catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译： 公开了乙烯与α-烯烃和任选的少量多烯的无定形共聚物，具有以下特征：（A）共聚物中α-烯烃的摩尔％摩尔比（％α）和α的摩尔量之比 α-烯烃二烷基和α-烯烃在共聚物中的摩尔含量（αα/α）满足以下关系：（％α）-250（αα/α）> / = 10（B）小于 聚合物链中的CH 2基团是（CH 2）n序列，其中n是偶数。 这些共聚物可通过在具有通过桥连基团连接在一起的两个芴基的特定茂金属基催化剂存在下操作而获得。
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7.发明授权公开(公告)号：US08236215B2
公开(公告)日：2012-08-07
申请号：US10520530
申请日：2002-07-11
IPC分类号： B29C47/00
CPC分类号： B29C47/362 , B29B7/325 , B29B7/42 , B29B7/7461 , B29B7/7495 , B29C47/0011 , B29C47/0014 , B29C47/0021 , B29C47/1045 , B29C47/1063 , B29C47/1081 , B29C47/364 , B29C47/366 , B29C47/367 , B29C47/662 , B29C47/8815 , B29C47/885 , B29C2793/009 , B29K2009/00 , B29K2105/0005 , B29K2105/16
摘要： A process for continuously producing an elastomeric composition includes metering and feeding at least one elastomer and at least one filler into at least one extruder, mixing and dispersing the at least one filler into the at least one elastomer using the at least one extruder, and passing the composition that results through at least one static mixer. An apparatus for continuously producing the composition includes at least one twin-screw extruder, at least one metering device, and at least one static mixer. The at least one extruder includes a housing and two screws rotatably mounted in the housing. The housing includes at least one feed opening and a discharge opening. The at least one metering device meters and feeds at least one elastomer and at least one filler into the at least one extruder. The composition discharged from the discharge opening passes through the at least one static mixer.
摘要翻译： 用于连续生产弹性体组合物的方法包括计量并将至少一种弹性体和至少一种填料进料到至少一个挤出机中，使用至少一个挤出机将至少一种填料混合并分散到至少一种弹性体中，并通过 通过至少一个静态混合器产生的组合物。 用于连续生产组合物的设备包括至少一个双螺杆挤出机，至少一个计量装置和至少一个静态混合器。 至少一个挤出机包括壳体和可旋转地安装在壳体中的两个螺钉。 壳体包括至少一个进料口和排出口。 所述至少一个计量装置计量并将至少一种弹性体和至少一种填料进料至所述至少一个挤出机中。 从排出口排出的组合物通过至少一个静态混合器。
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8.发明授权Elastomeric copolymers of ethylene with &agr;-olefins and process for their preparation 失效乙烯与α-烯烃的弹性共聚物及其制备方法公开(公告)号：US06403737B1
公开(公告)日：2002-06-11
申请号：US09694160
申请日：2000-10-24
IPC分类号： C08F442
CPC分类号： C08F210/16 , Y10S526/943 , C08F2/14 , C08F210/18 , C08F2500/03 , C08F2500/08 , C08F2500/17 , C08F2500/20 , C08F2500/21 , C08F210/08
摘要： A process for the preparation of amorphous copolymers of ethylene with &agr;-olefins and optionally minor amounts of polyenes are disclosed, which have the following characteristics: (A) the % by mole content of &agr;-olefin in the copolymer (%&agr;) and the ratio between the molar amount of &agr;-olefin diads and the molar content of &agr;-olefin in the copolymer (&agr;&agr;/&agr;) satisfy the following relationship: (%&agr;)−250 (&agr;&agr;/&agr;)≧10 (B) less than 2% of the CH2 groups in the polymeric chain are in sequences (CH2)n, wherein n is an even number. These copolymers are obtained by operating in the presence of particular metallocene-based catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译： 公开了一种制备乙烯与α-烯烃和任选少量多烯的无定形共聚物的方法，其具有以下特征：（A）共聚物中α-烯烃的摩尔％摩尔％（％）和 α-烯烃二单元摩尔量与共聚物中α-烯烃的摩尔含量之比（αalpha/α）满足以下关系：（B）聚合物链中少于2％的CH 2基团为顺序（ CH2）n，其中n是偶数。这些共聚物通过在具有通过桥连基团连接在一起的两个芴基的特定茂金属基催化剂存在下操作而获得。
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公开(公告)号：US6046287A
公开(公告)日：2000-04-04
申请号：US825660
申请日：1997-04-03
IPC分类号： C08F2/02 , C08F2/14 , C08F4/60 , C08F4/622 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/16 , C08F210/18 , C08F4/68
CPC分类号： C08F210/18 , C08F210/16 , Y10S526/902 , Y10S526/916
摘要： Elastomeric ethylene/propylene or ethylene/propylene/-polyene copolymers containing small amounts of one or more .alpha.-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin. Problems due to fouling phenomena in the reactor are avoided.
摘要翻译： 通过淤浆法制备含有少量一种或多种α-烯烃的弹性体乙烯/丙烯或乙烯/丙烯/ - 多烯共聚物，其中聚合反应在液态丙烯和α-烯烃的混合物中进行。 避免了由于反应器中的结垢现象引起的问题。
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公开(公告)号：US08460590B2
公开(公告)日：2013-06-11
申请号：US10484494
申请日：2002-07-22
申请人： Renato Caretta , Maurizio Galimberti , Cesare Amurri , Cristiano Puppi , Giuseppe Ducoli , Enrico Albizzati
发明人： Renato Caretta , Maurizio Galimberti , Cesare Amurri , Cristiano Puppi , Giuseppe Ducoli , Enrico Albizzati
CPC分类号： B29C47/0004 , B29B7/42 , B29B7/48 , B29B7/603 , B29B7/7495 , B29B7/88 , B29C31/02 , B29C31/06 , B29C31/10 , B29C47/0009 , B29C47/1045 , B29C47/1063 , B29C47/1081 , B29C47/109 , B29C47/364 , B29C47/367 , B29C47/369 , B29C47/38 , B29K2021/00 , B29K2105/0005 , B29K2105/0085 , B29K2105/06 , B29K2105/16
摘要： A process for continuously producing an elastomeric composition includes providing at least one extruder, metering and feeding at least one elastomer, at least one filler, and ingredients different from elastomers and fillers into the at least one extruder, mixing and dispersing the at least one filler and the ingredients different from elastomers and fillers into the at least one elastomer using the at least one extruder, and extruding a resulting elastomeric composition. The at least one extruder includes the housing and at least one screw rotatably mounted in the housing. The housing includes at least one feed opening and a discharge opening. At least one of the ingredients different from elastomers and fillers includes a subdivided product including one or more minor ingredients dispersed in at least one thermoplastic binding agent. An apparatus for continuously producing the elastomeric composition is also disclosed.
摘要翻译： 用于连续生产弹性体组合物的方法包括提供至少一个挤出机，计量并将至少一种弹性体，至少一种填料和与弹性体和填料不同的成分进料至至少一个挤出机中，将至少一种填料 以及使用至少一种挤出机将不同于弹性体和填料的成分加入到至少一种弹性体中，并挤出所得的弹性体组合物。 所述至少一个挤出机包括壳体和可旋转地安装在壳体中的至少一个螺杆。 壳体包括至少一个进料口和排出口。 与弹性体和填料不同的成分中的至少一种包括包含分散在至少一种热塑性粘合剂中的一种或多种次要成分的细分产品。 还公开了用于连续生产弹性体组合物的设备。
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