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    Condensation polymer containing the residue of a poly-methine compound and shaped articles produced therefrom
    5.
    发明授权
    Condensation polymer containing the residue of a poly-methine compound and shaped articles produced therefrom 失效
    含有聚次甲基化合物的残基的聚合物和由其制备的成型制品

    公开(公告)号：US4749774A

    公开(公告)日：1988-06-07

    申请号：US78434

    申请日：1987-07-27

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

    IPC分类号： C08F299/04 ,  C08F283/01 ,  C08G63/44 ,  C08G63/46 ,  C08G63/52 ,  C08G63/68 ,  C08G63/685 ,  C08G64/04 ,  C08L67/02 ,  C08G63/76 ,  C08G69/44

    CPC分类号： C07C255/00 ,  C08G63/52 ,  C08G63/6858 ,  C08G64/045

    摘要： Composition useful for molding into articles which as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more poly-methine compounds having the formula: ##STR1## wherein each R.sup.1 is independently selected from cyano, carboxy, alkenyloxycarbonyl, or a substituted or unsubstituted alkoxycarbonyl, cycloalkoxoycarbonyl or aryloxycarbonyl radical;each R.sup.2 is independently selected from one of the groups specified for R.sup.1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or aromatic, heterocyclic radical;each R.sup.3 is independently selected from hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;A.sup.1 and A.sup.2 are independently selected from 1,4-phenylene radicals; andL is an organic linking group bonded by non-oxo carbon atoms to the oxygen atoms adjacent to L; provided the poly-methine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The polymethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

    Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
    10.
    发明授权
    Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom 失效
    含有次甲基紫外线辐射吸收残基的冷凝聚合物和由其制备的成型制品

    公开(公告)号：US4749773A

    公开(公告)日：1988-06-07

    申请号：US78433

    申请日：1987-07-27

    申请人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

    发明人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

    IPC分类号： C08G63/44 ,  C08G63/54 ,  C08G63/685 ,  C08G64/04 ,  C08G64/12 ,  C08G63/76 ,  C08G69/44

    CPC分类号： C08G64/12 ,  C07C255/00 ,  C07C317/00 ,  C08G63/54 ,  C08G63/6858 ,  C08G64/045

    摘要： A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein a total of from 100 to about 800 ppm, of the residue of one or a mixture of methine reactants of the formula ##STR1## wherein R.sup.1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical;A.sup.1 is an unsubstituted or substituted phenylene radical;A.sup.2 is an unsubstituted or substituted 1,4-phenylene radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;R.sup.3 is cyano or ##STR2## and R.sup.4 is one of the substituents which R.sup.3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals.The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

    摘要翻译： 可用于模制成诸如食品容器，软饮料瓶，固化的结构塑料等的制品的组合物，其包含在其中反应或共聚合总计为100至约800ppm的残余物的成型级线性或不饱和聚酯或聚碳酸酯 其中R 1是氢或未取代或取代的烷基，链烯基，环烷基或芳基的一种或者下式的次甲基化合物的混合物： A1是未取代或取代的亚苯基; A2是未取代或取代的1,4-亚苯基; R2是氢或未取代或取代的烷基，环烷基或芳基; R 3是氰基或R 4是R 3可以代表的取代基之一或未取代或取代的氨基甲酰基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，芳基或芳族杂环基。 次甲基残基作为聚合物链的组成部分存在于聚合物中，并吸收约250至约390nm范围内的紫外线辐射。 残余物不能从聚合物中萃取，并且在制备和加工聚合物的条件下是稳定的。