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公开(公告)号：US20140171565A1
公开(公告)日：2014-06-19
申请号：US14114062
申请日：2012-04-27
IPC分类号： C08L9/06
CPC分类号： C08L9/06 , B60C1/00 , B60C1/0016 , C08K3/06 , C08K3/36 , C08K5/3415 , C08K5/37 , C08K5/38 , C08K5/39 , C08K5/41 , C08K5/548 , C08L21/00
摘要： The present invention relates to a process for producing rubber mixtures in a mixing process with, for example, a plurality of mixing stages, where these can optionally be divided into a plurality of sub-steps, comprising the mixing of the following components: one or more rubbers, one or more hydroxylated oxidic fillers, one or more sulphur-containing organosilicon and/or one or more hydroxypolysulphidic compounds, one or more anti-reversion agents selected from 1,6-bis(N,N-dibenzyl-thiocarbamoyldithio)hexane (CAS No.: 151900-44-6), 1,3-bis((3-methyl-2,5-dioxopyrrol-1-yl)methyl)benzene (CAS No.: 119462-56-5) and hexamethylene 1,6-bis(thiosulphate), disodium salt, dihydrate (CAS No.: 5719-73-3), individually and mixtures thereof, where these are incorporated into the mixture in the first mixing stage, one or more vulcanization additives, one or more rubber additives.
摘要翻译： 本发明涉及在与例如多个混合阶段的混合过程中生产橡胶混合物的方法，其中这些混合阶段可任选地分成多个子步骤，包括混合以下组分：一个或 一种或多种羟基化氧化填料，一种或多种含硫有机硅和/或一种或多种羟基多硫化合物，一种或多种选自1,6-双（N，N-二苄基 - 硫代氨基甲酰基二硫代）己烷 （CAS号：151900-44-6），1,3-双（（3-甲基-2,5-二氧代吡咯-1-基）甲基）苯（CAS号：119462-56-5）和六亚甲基1 ，六 - 二（硫代硫酸盐），二钠盐，二水合物（CAS号：5719-73-3）及其混合物，其中这些在第一混合阶段加入到混合物中，一种或多种硫化添加剂，一种或多种 更多的橡胶添加剂。
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公开(公告)号：US09023926B2
公开(公告)日：2015-05-05
申请号：US14114062
申请日：2012-04-27
IPC分类号： B32B7/12 , C08F8/34 , C08L9/06 , B60C1/00 , C08K3/06 , C08K3/36 , C08K5/37 , C08K5/39 , C08L21/00 , C08K5/3415 , C08K5/38 , C08K5/41 , C08K5/548
CPC分类号： C08L9/06 , B60C1/00 , B60C1/0016 , C08K3/06 , C08K3/36 , C08K5/3415 , C08K5/37 , C08K5/38 , C08K5/39 , C08K5/41 , C08K5/548 , C08L21/00
摘要： The present invention relates to a process for producing rubber mixtures in a mixing process with, for example, a plurality of mixing stages, where these can optionally be divided into a plurality of sub-steps, comprising the mixing of the following components: one or more rubbers, one or more hydroxylated oxidic fillers, one or more sulphur-containing organosilicon and/or one or more hydroxypolysulphidic compounds, one or more anti-reversion agents selected from 1,6-bis(N,N-dibenzyl-thiocarbamoyldithio)hexane (CAS No.: 151900-44-6), 1,3-bis((3-methyl-2,5-dioxopyrrol-1-yl)methyl)benzene (CAS No.: 119462-56-5) and hexamethylene 1,6-bis(thiosulphate), disodium salt, dihydrate (CAS No.: 5719-73-3), individually and mixtures thereof, where these are incorporated into the mixture in the first mixing stage, one or more vulcanization additives, one or more rubber additives.
摘要翻译： 本发明涉及在与例如多个混合阶段的混合过程中生产橡胶混合物的方法，其中这些混合阶段可任选地分成多个子步骤，包括混合以下组分：一个或 一种或多种羟基化氧化填料，一种或多种含硫有机硅和/或一种或多种羟基多硫化合物，一种或多种选自1,6-双（N，N-二苄基 - 硫代氨基甲酰基二硫代）己烷 （CAS号：151900-44-6），1,3-双（（3-甲基-2,5-二氧代吡咯-1-基）甲基）苯（CAS号：119462-56-5）和六亚甲基1 ，六 - 二（硫代硫酸盐），二钠盐，二水合物（CAS号：5719-73-3）及其混合物，其中这些在第一混合阶段加入到混合物中，一种或多种硫化添加剂，一种或多种 更多的橡胶添加剂。
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公开(公告)号：US09758642B2
公开(公告)日：2017-09-12
申请号：US14114368
申请日：2012-04-27
CPC分类号： C08K13/02 , B60C1/00 , C08K3/36 , C08K5/372 , C08K5/378 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00
摘要： A silica-containing rubber mixture includes at least one rubber, a sulphur-containing alkoxysilane, a crosslinking agent, a filler, and optionally further rubber auxiliaries, and the mixture also includes from 0.1 to 15 parts by weight, based on 100 parts by weight of rubber used, of a silicon-free polysulphide additive of the formula (I) A-S—(S)x—S—Y—S—(S)x—S-A (I) where x is 0, 1 or 2, Y is an optionally substituted or heteroatom-containing aliphatic, cycloaliphatic or aromatic group, and A may include hydroxy, carboxy, or carboxyphenyl groups.
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公开(公告)号：US20140155518A1
公开(公告)日：2014-06-05
申请号：US14114362
申请日：2012-04-27
CPC分类号： C08K13/02 , B60C1/00 , C08K3/36 , C08K5/372 , C08K5/378 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00
摘要： The present invention relates to silica-containing rubber mixture produced from at least one rubber, from a sulphur-containing alkoxysilane, from a crosslinking agent, from a filler, and optionally from further rubber auxiliaries, where the said mixture comprises from 0.1 to 15 parts by weight, based on 100 parts by weight of rubber used, of a silicon-free polysulphide additive of the formula (I) A-S—(S)x—S—B (I) in which x is 0, 1, 2, 3 or 4, A is a moiety and B is a moiety in which R1 to R4 are identical or different and are hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl, and R6 to R7 are identical or different and are hydrogen C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, with R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl and y, z are mutually independently 0, 1 or 2, or A and B are mutually independently one of the moieties in which R1 and R2 are identical or different and are hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl.
摘要翻译： 本发明涉及由至少一种橡胶，含硫烷氧基硅烷，交联剂，填料和任选的其它橡胶助剂制成的含二氧化硅橡胶混合物，其中所述混合物包含0.1至15份 （I）AS-（S）x-S-B（I）的无硅多硫化物添加剂，其中x为0,1,2,3重量份，基于100重量份的橡胶 或4，A是部分，B是其中R 1至R 4相同或不同且为氢，C 1 -C 6 - 烷基，C 5 -C 6 - 环烷基，C 6 -C 10 - 芳基或基团-CH 2 OR 5的部分， -CH2-CH2-OR5，-NHR5，-COR5，-COOR5，-CH2COOR5，其中R5 =氢，C1-C6-烷基，C5-C6-环烷基，C6-C10-芳基或C1-C6-酰基，R6 C 1 -C 6烷基，C 5 -C 6环烷基，C 6 -C 10 - 芳基或基团-CH 2 OR 5，-CH 2 -CH 2 -OR 5，-NHR 5，-COR 5，-COOR 5， -CH 2 COOR 5，其中R5 =氢，C1-C6-烷基，C5-C6-环烷基，C6-C1 O-芳基或C 1 -C 6 - 酰基，y，z相互独立地为0,1或2，或A和B相互独立地为R1和R2相同或不同且为氢的部分之一，C1-C6- 烷基，C 5 -C 6 - 环烷基，C 6 -C 10 - 芳基或基团-CH 2 OR 5，-CH 2 -CH 2 -OR 5，-NHR 5，-COR 5，-COOR 5，-CH 2 COOR 5，其中R 5 =氢，C 1 -C 6烷基 ，C 5 -C 6 - 环烷基，C 6 -C 10 - 芳基或C 1 -C 6 - 酰基。
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公开(公告)号：US09783658B2
公开(公告)日：2017-10-10
申请号：US14114362
申请日：2012-04-27
CPC分类号： C08K13/02 , B60C1/00 , C08K3/36 , C08K5/372 , C08K5/378 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00
摘要： A silica-containing rubber mixture is produced from a rubber, a sulphur-containing alkoxysilane, a crosslinking agent, a silica-containing filler, and 0.1 to 15 parts by weight, based on 100 parts by weight of the rubber, of a silicon-free polysulphide additive of the formula (I) A-S-(S)x-S-B where x is 0-4, and A and B are the same or different, are alkyl or aryl, and contain at last one oxygen, which may be in the form of a carboxyl group.
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公开(公告)号：US09376551B2
公开(公告)日：2016-06-28
申请号：US14237580
申请日：2012-08-09
CPC分类号： C08K5/548 , C07F7/0838 , C07F7/1804 , C07F7/1892 , C08L7/00 , C08L9/06
摘要： The present invention relates to new crosslinked organosilicon polysulphides, to processes for preparing them and to their use as additives for plastics and/or rubbers.
摘要翻译： 本发明涉及新的交联的有机硅多硫化物，其制备方法及其作为塑料和/或橡胶添加剂的用途。
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公开(公告)号：US20140350158A1
公开(公告)日：2014-11-27
申请号：US14237580
申请日：2012-08-09
CPC分类号： C08K5/548 , C07F7/0838 , C07F7/1804 , C07F7/1892 , C08L7/00 , C08L9/06
摘要： The present invention relates to new crosslinked organosilicon polysulphides, to processes for preparing them and to their use as additives for plastics and/or rubbers.
摘要翻译： 本发明涉及新的交联的有机硅多硫化物，其制备方法及其作为塑料和/或橡胶添加剂的用途。
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8.发明申请公开(公告)号：US20140142230A1
公开(公告)日：2014-05-22
申请号：US14114377
申请日：2012-04-27
IPC分类号： C08L9/06
CPC分类号： C08K13/02 , B60C1/00 , C08K3/36 , C08K5/372 , C08K5/378 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00
摘要： The present invention relates to silica-containing rubber mixture produced from at least one rubber, from a sulphur-containing alkoxysilane, from a crosslinking agent, from a filler, and optionally from further rubber auxiliaries, where the said mixture comprises from 0.1 to 15 parts by weight, based on 100 parts by weight of rubber used, of a silicon-free polysulphide additive of the formula (I) in which x is 0, 1, 2, 3 or 4 R1 to R4 are identical or different and are hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl, and R6 to R7 are identical or different and are hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl and y and z are mutually independently 0, 1 or 2.
摘要翻译： 本发明涉及由至少一种橡胶，含硫烷氧基硅烷，交联剂，填料和任选的其它橡胶助剂制成的含二氧化硅橡胶混合物，其中所述混合物包含0.1至15份 （I）的无硅多硫化物添加剂，其中x为0,1,2,3或4个R 1 -R 4的重量比相同或不同，为氢， C 1 -C 6烷基，C 5 -C 6环烷基，C 6 -C 10 - 芳基或基团-CH 2 OR 5，-CH 2 -CH 2 -OR 5，-NHR 5，-COR 5，-COOR 5，-CH 2 COOR 5，其中R 5 =氢，C 1 C 1-6 - 烷基，C 5 -C 6 - 环烷基，C 6 -C 10 - 芳基或C 1 -C 6酰基，且R 6至R 7相同或不同，为氢，C 1 -C 6烷基，C 5 -C 6环烷基，C 6 -C 10 芳基或基团-CH 2 OR 5，-CH 2 -CH 2 -OR 5，-NHR 5，-COR 5，-COOR 5，-CH 2 COOR 5，其中R 5 =氢，C 1 -C 6烷基，C 5 -C 6环烷基，C 6 -C 10 - 芳基或C 1 -C 6酰基，y和z彼此独立地为0,1或 2。
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公开(公告)号：US20140142227A1
公开(公告)日：2014-05-22
申请号：US14114368
申请日：2012-04-27
CPC分类号： C08K13/02 , B60C1/00 , C08K3/36 , C08K5/372 , C08K5/378 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00
摘要： The present invention relates to silica-containing rubber mixture produced from at least one rubber, from a sulphur-containing alkoxysilane, from a crosslinking agent, from a filler, and optionally from further rubber auxiliaries, where the said mixture comprises from 0.1 to 15 parts by weight, based on 100 parts by weight of rubber used, of a silicon-free polysulphide additive of the formula (I) A-S—(S)x—S—Y—S—(S)x—S-A (I) where x is 0, 1 or 2, Y is an optionally substituted or heteroatom-containing aliphatic, cycloaliphatic or aromatic group and A is a moiety where R1 to R2 are identical or different and are hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl, or A is a moiety in which R1 and R2 are identical or different and are hydrogen, C1-C6-alkyl, C5-C5-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl, or A is a moiety in which R1 to R2 are identical or different and hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl, and R6 is hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or a group —CH2—OR5, —CH2—CH2—OR5, —NHR5, —COR5, —COOR5, —CH2COOR5, where R5=hydrogen, C1-C6-alkyl, C5-C6-cycloalkyl, C6-C10-aryl or C1-C6-acyl and y is 0, 1 or 2.
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公开(公告)号：US08323357B2
公开(公告)日：2012-12-04
申请号：US12752425
申请日：2010-04-01
IPC分类号： C09B67/20 , C09B67/22 , C07D471/22
CPC分类号： C07D471/06 , C09B5/62 , Y10T428/10 , Y10T428/1041
摘要： The use of fluorine-substituted perylenes in color filters for liquid-crystal displays is described.
摘要翻译： 描述了氟取代的二萘嵌苯用于液晶显示器的滤色器中的用途。
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