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公开(公告)号：US3953644A
公开(公告)日：1976-04-27
申请号：US534927
申请日：1974-12-20
CPC分类号： B05D7/536 , B05D2202/00 , B05D2451/00 , Y10T428/31511 , Y10T428/31699
摘要： A method for painting automobiles and other articles of manufacture which admits of the use of medium to high concentration of metal pigments, can provide high gloss finish coatings and employs a low concentration of volatile solvents comprising application of a relatively thin, highly pigmented, water-based coating to a substrate, heat curing, application of an unpigmented or lightly pigmented powder coating that is transparent on curing, and heat curing of the powder coating. Products bearing unique finish coatings prepared by this method are claimed.This invention relates to the art of coating. More specifically, this invention relates to a novel method of coating substrates, particularly metal substrates, and to the products produced by such method.
摘要翻译： 允许使用中等至高浓度的金属颜料的汽车和其他制品的喷漆方法可以提供高光泽的表面涂层，并且采用低浓度的挥发性溶剂，其包括施加相对薄的，高着色的， 基底涂层，加热固化，施加在固化时透明的未着色或轻微着色的粉末涂料，以及粉末涂料的热固化。 要求保护由该方法制备的具有独特表面涂层的产品。
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2.发明授权
公开(公告)号：US3932349A
公开(公告)日：1976-01-13
申请号：US506489
申请日：1974-09-16
IPC分类号： C08K9/00 , C08G59/00 , C08K9/08 , C08K9/10 , C08L33/00 , C08L33/02 , C08L33/04 , C08L63/00 , C08L67/00 , C08L77/00 , C09C1/00 , C09C1/62 , C09D5/03 , C09D5/38 , C09D5/46 , C09D133/04 , C09D133/06 , C08K3/08 , C08K9/04
CPC分类号： C09D5/38 , C09D133/06
摘要： Improved powder paint compositions providing greater depth variation of metal pigment particles comprise (1) aluminum flakes individually encapsulated in a thin, continuous, thermoplastic, organic film-former containing an ammonium salt selected from tetraalkyl ammonium halides and substituted tetraalkylammonium halides wherein at least one alkyl radical is replaced with an aryl, phenoxy, or alkoxy radical and (2) a particulate, organic film-former. The encapsulated aluminum flakes are prepared by intimately dispersing the aluminum flakes in a solution of the thermoplastic, organic film-former and the ammonium salt in a volatile solvent and spray drying the resultant dispersion. In the preferred embodiment, the particulate, organic film-former is also a thermoplastic material and, in the most preferred embodiment, it is of the same composition as the coating on the aluminum flakes.
摘要翻译： 提供金属颜料颗粒更大深度变化的改进的粉末涂料组合物包括（1）单独包封在薄的连续的热塑性有机成膜剂中的铝薄片，其含有选自四烷基卤化铵和取代的四烷基卤化铵的铵盐，其中至少一个烷基 基团被芳基，苯氧基或烷氧基取代，和（2）颗粒状有机成膜剂。 封装的铝薄片通过将铝薄片紧密地分散在热塑性有机成膜剂和铵盐的溶液中挥发性溶剂中并将所得分散体喷雾干燥来制备。 在优选的实施方案中，颗粒状有机成膜剂也是热塑性材料，并且在最优选的实施方式中，其与铝片上的涂层具有相同的组成。
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公开(公告)号：US3941731A
公开(公告)日：1976-03-02
申请号：US506491
申请日：1974-09-16
IPC分类号： C09D5/03 , C08G59/00 , C08K3/08 , C08K9/10 , C08L23/00 , C08L33/00 , C08L33/02 , C08L33/08 , C08L63/00 , C08L67/00 , C08L77/00 , C08L101/00 , C09C1/00 , C09C1/62 , C09D5/08 , C09D5/14 , C09D5/38 , C09D5/46 , C09D133/06 , C08K9/04
CPC分类号： C09D5/38 , C09D133/06 , C08L33/08 , Y10S524/904
摘要： Improved powder paint compositions employing particulate metal color producing components comprise a unique combination of (a) aluminum flakes individually encapsulated in a thin, thermoplastic organic film-former (b) nickel powder, and (c) the principal film-former of the powder paint composition in particulate form. The encapsulated aluminum flake is prepared by intimately dispersing the aluminum flake in a solution of the thermoplastic, organic film-former of controlled concentration and spray drying the resultant dispersion. In the preferred embodiment, the principal film-former of the powder paint composition is also a thermoplastic material and, in the most preferred embodiment, it is also of the same composition as the principal film-former of the powder coating composition.
摘要翻译： 使用颗粒状金属颜色产生组分的改进的粉末涂料组合物包括（a）单独包封在薄的热塑性有机成膜剂（b）镍粉末中的铝薄片的独特组合，和（c）粉末涂料的主要成膜剂 颗粒状组成。 通过将铝薄片紧密地分散在具有受控浓度的热塑性有机成膜剂的溶液中并将所得分散体喷雾干燥来制备包封的铝薄片。 在优选的实施方案中，粉末涂料组合物的主要成膜剂也是热塑性材料，并且在最优选的实施方案中，它也与粉末涂料组合物的主要成膜剂具有相同的组成。
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公开(公告)号：US3932347A
公开(公告)日：1976-01-13
申请号：US506486
申请日：1974-09-16
IPC分类号： C08G59/00 , C08K9/10 , C08L33/00 , C08L33/02 , C08L63/00 , C08L67/00 , C09C1/00 , C09C1/62 , C09D5/03 , C09D5/38 , C09D5/46 , C08K3/08 , C08K9/04
摘要： Metal particles used as color producing component in powder coating compositions are individually encapsulated in a thin and continuous coating of thermosettable, organic film-former prior to mixing with the particulate, organic, material which serves as the principal film-former of the powder coating composition. The coated particles are prepared by spray drying a solution of a controlled amount of the thermosettable material in a volatile solvent in which the metal has been dispersed. In the preferred embodiment, the coating thus achieved on the metal particles is cross-linkable with the principal film-former of the powder coating composition.
摘要翻译： 在与粉末涂料组合物的主要成膜剂的颗粒状有机材料混合之前，用作粉末涂料组合物中的着色组分的金属颗粒被单独包封在可热固化的有机成膜剂的薄而连续的涂层中 。 涂覆的颗粒通过将受控量的可热固化材料的溶液喷雾干燥在其中已经分散金属的挥发性溶剂中来制备。 在优选的实施方案中，由此在金属颗粒上实现的涂层可与粉末涂料组合物的主要成膜剂交联。
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5.发明授权Organic vapor deposition process for corrosion protection of prestamped metal substrates 失效有机气相沉积工艺，用于预压金属基板的防腐蚀
公开(公告)号：US5267390A
公开(公告)日：1993-12-07
申请号：US685748
申请日：1991-04-15
CPC分类号： C23C16/0272 , C23C16/30 , Y10S29/037 , Y10T29/49986
摘要： A process for improved corrosion protection of a metal substrates involving organic vapor deposition of a thin film by polymerization of certain precursors onto one side of the phosphated flat metal substrate (15). Following stamping and assembly of the metal substrate, a primer and topcoat may be applied over the other side of the metal substrate. The process is particularly applicable to coil steel employed in the original manufacture of automobiles, trucks, and parts thereof.
摘要翻译： 一种用于改善金属基材的腐蚀保护的方法，其涉及通过将某些前体聚合成磷酸化的平坦金属基材（15）的一侧来进行薄膜的有机气相沉积。 在金属基板的冲压和组装之后，可以在金属基板的另一侧上施加底漆和面漆。 该方法特别适用于汽车，卡车及其部件的原始制造中使用的线圈钢。
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公开(公告)号：US3939114A
公开(公告)日：1976-02-17
申请号：US506487
申请日：1974-09-16
IPC分类号： C09D5/03 , C08G59/00 , C08K3/08 , C08K9/10 , C08L33/00 , C08L33/02 , C08L63/00 , C08L67/00 , C09C1/00 , C09C1/62 , C09D5/38 , C08K9/04
CPC分类号： C09D5/38
摘要： Improved powder paint compositions employing particulate metal color producing components comprise a unique combination of (a) aluminum flakes individually encapsulated in a thin, thermosettable, organic film-former, (b) nickel powder, and (c) the principal film-former of the powder paint composition in particulate form. The encapsulated aluminum flake is prepared by intimately dispersing the aluminum flake in a solution of the thermosettable, organic film-former of controlled concentration and spray drying the resultant dispersion. In the preferred embodiment, the principal film-former of the powder paint composition is also a thermosettable material and, in the most preferred embodiment, it is also crosslinkable with the thermosettable coating on the aluminum flakes.
摘要翻译： 使用颗粒状金属颜色产生组分的改进的粉末涂料组合物包括（a）单独包封在薄的可热固化的有机成膜剂中的铝片的独特组合，（b）镍粉，和（c）主成膜剂 粉末涂料组合物为颗粒状。 通过将铝薄片紧密地分散在可控热的有控制浓度的有机成膜剂的溶液中并喷雾干燥所得的分散体来制备包封的铝薄片。 在优选的实施方案中，粉末涂料组合物的主要成膜剂也是热固性材料，并且在最优选的实施方案中，其也可与铝箔上的可热固化涂层交联。
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7.发明授权Powder paints having aluminum flakes encapsulated in thermosettable material containing tetraalkylammonium halides 失效具有铝片的粉末涂料包封在含有四烷基卤化铵的热固性材料中
公开(公告)号：US3932348A
公开(公告)日：1976-01-13
申请号：US506488
申请日：1974-09-16
IPC分类号： C09D5/03 , C08G59/00 , C08K9/10 , C08L33/00 , C08L33/02 , C08L63/00 , C08L67/00 , C09C1/00 , C09C1/62 , C09D5/38 , C09D5/46 , C08K3/08 , C08K9/04
CPC分类号： C09D5/38
摘要： Improved powder paint compositions providing greater depth variation of metal pigment particles comprise (1) aluminum flakes individually encapsulated in a thin, continuous, thermosettable, organic film-former containing an ammonium salt selected from tetraalkyl ammonium halides and substituted tetraalkylammonium halides wherein at least one alkyl radical is replaced with an aryl, phenoxy or alkoxy radical and (2) a particulate, organic film-former. The encapsulated aluminum flakes are prepared by intimately dispersing the aluminum flakes in a solution of the thermosettable, organic film-former and the ammonium salt in a volatile solvent and spray drying the resultant dispersion. In the preferred embodiment, the particulate, organic film-former is also a thermosettable material and, in the most preferred embodiment, it is also crosslinkable with the thermosettable coating on the aluminum flakes.
摘要翻译： 提供金属颜料颗粒更大深度变化的改进的粉末涂料组合物包括（1）单独包封在薄的，连续的可热固的有机成膜剂中的铝薄片，其含有选自四烷基卤化铵和取代的四烷基卤化铵的铵盐，其中至少一个烷基 自由基被芳基，苯氧基或烷氧基取代，和（2）颗粒状有机成膜剂。 封装的铝薄片通过将铝薄片紧密地分散在可热固化的有机成膜剂和铵盐的溶液中挥发性溶剂中并将所得分散体喷雾干燥来制备。 在优选的实施方案中，颗粒状有机成膜剂也是热固性材料，并且在最优选的实施方案中，其也可与铝片上的可热固化涂层交联。
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公开(公告)号：US3932320A
公开(公告)日：1976-01-13
申请号：US506490
申请日：1974-09-16
IPC分类号： C08K9/00 , C08G59/00 , C08K9/08 , C08K9/10 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/08 , C08L63/00 , C08L67/00 , C08L77/00 , C09C1/00 , C09C1/62 , C09D5/03 , C09D5/38 , C09D5/46 , C09D133/04 , C09D133/06 , C08K3/08 , C08K9/04
CPC分类号： C09D5/38 , C09D133/06 , C08L33/08 , Y10S524/904
摘要： Metal particles used as a color producing component in powder coating compositions are individually encapsulated in a thin and continuous coating of thermoplastic, organic film-former prior to mixing with the particulate, organic, material which serves as the principal film-former of the powder coating composition. The coated particles are prepared by spray drying a solution of a controlled amount of the thermoplastic material in a volatile solvent in which the metal has been dispersed. In a preferred embodiment, the coating thus achieved on the metal particles is of the same composition as the principal film-former of the powder coating composition.
摘要翻译： 用作粉末涂料组合物中的着色组分的金属颗粒在与作为粉末涂料的主要成膜剂的颗粒状有机材料混合之前，单独封装在热塑性有机成膜剂的薄而连续的涂层中 组成。 涂覆的颗粒通过将受控量的热塑性材料的溶液喷雾干燥在其中已经分散金属的挥发性溶剂中来制备。 在一个优选的实施方案中，由此在金属颗粒上实现的涂层具有与粉末涂料组合物的主要成膜剂相同的组成。
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