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    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
    7.
    发明授权
    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
    含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法

    公开(公告)号：US5198511A

    公开(公告)日：1993-03-30

    申请号：US811785

    申请日：1991-12-20

    申请人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormick

    发明人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormick

    IPC分类号： C08F4/06 ,  C08F4/42 ,  C08F4/80 ,  C08G61/06 ,  C08G61/08 ,  C08L61/08

    CPC分类号： C08G61/08 ,  Y10S526/943

    摘要： Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1) (L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ;wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC=CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least ##STR1## (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.

    摘要翻译： 环应变环烯烃的聚合在空气和水分稳定的含有过渡金属的化合物的一部分或两部分催化剂存在下进行。 一部分过渡金属的催化剂选自（a）式（L1）（L2）Q化合物，其中Q表示Mo或W; L1代表一至六个CO（羰基）配体; L2代表无5个配体，它们各自是可以相同或不同的非离子化合物或聚合物单元，每个赋予金属二，四或六个电子，并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18，（b）至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐，和（c）[Ir （RO2CHC = CHCO2R）2Cl] 2，其中每个R独立地为氢或低级烷基（C1-C4），条件是金属的氧化态在+3至0的范围内，并且含有C-卤键的助催化剂为 不存在。 两部分催化剂包含（a）含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，和（b）选自（i）的助催化剂， （ii）至少含有（iii）氧化盐或含有氧原子的氧化化合物与非氧原子双键的有机硅烷，（iv）含杂原子的烯烃的有机硅烷。 聚合的组合物可用于提供模塑制品，弹性体，电介质载体，离子或生物活性材料，复合材料等。

    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
    8.
    发明授权
    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
    含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法

    公开(公告)号：US5296566A

    公开(公告)日：1994-03-22

    申请号：US992381

    申请日：1992-12-16

    申请人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormic

    发明人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormic

    IPC分类号： C08F4/06 ,  C08F4/42 ,  C08F4/80 ,  C08G61/06 ,  C08G61/08 ,  C08L61/08

    CPC分类号： C08G61/08 ,  Y10S526/943

    摘要： Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1)(L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ; wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC.dbd.CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least one of ##STR1## groups, (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.

    摘要翻译： 环应变环状烯烃的聚合在其为空气和湿气稳定的，并且其包括一个含过渡金属的化合物的一部分或两部分催化剂的存在下进行。 单部分含过渡金属的催化剂选自（a）式（L1）（L2）Q，其中Q代表Mo或W的化合物的组中选择; L1代表一至六个CO（羰基）配体; L2代表无5个配体，它们各自是可以相同或不同的非离子化合物或聚合物单元，每个赋予金属二，四或六个电子，并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18，（b）至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐，和（c）（Ir （RO2CHC = CHCO2R）2Cl）2，其中每个R独立地为氢或低级烷基（C1-C4），条件是金属的氧化态在+3至0的范围内，并且含有C-卤键的助催化剂为 不存在。 两部分催化剂包括（a）含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，和（b）选自（i）的助催化剂， 末端或甲硅烷基炔，（ii）含有（*化学结构*）基团中的至少一个的有机硅烷，（iii）含氧原子与非氧原子双键的氧化性盐或氧化性化合物，和（iv）含杂原子的烯烃 。 所述聚合的组合物是提供模塑制品，弹性体，电介质支撑件，离子载体或生物活性材料，复合材料，等是有用的。

    Multiphoton photosensitization system
    9.
    发明授权
    Multiphoton photosensitization system 有权
    多光子光敏化系统

    公开(公告)号：US06750266B2

    公开(公告)日：2004-06-15

    申请号：US10033507

    申请日：2001-12-28

    申请人： James G. Bentsen ,  Robert J. DeVoe ,  Michael C. Palazzotto

    发明人： James G. Bentsen ,  Robert J. DeVoe ,  Michael C. Palazzotto

    IPC分类号： G03F7038

    CPC分类号： G03F7/038 ,  G03F7/0037 ,  G03F7/0042 ,  G03F7/0043 ,  G03F7/029 ,  G03F7/0385 ,  G03F7/039

    摘要： A multiphoton-activatable, photoreactive composition comprises: (a) at least one reactive species that is capable of undergoing an acid- or radical-initiated chemical reaction; (b) a photochemically-effective amount of a multiphoton photosensitizer comprising at least one multiphoton up-converting inorganic phosphor; and (c) a photochemically-effective amount of a one-photon photoinitiator system that is capable of being photosensitized by the multiphoton photosensitizer.

    摘要翻译： 多光子活化的光反应性组合物包含：（a）能够经历酸或自由基引发的化学反应的至少一种反应性物质; （b）光化学有效量的多光子光敏剂，其包括至少一个多光子上转换无机磷光体; 和（c）光化学有效量的能够被多光子光敏剂光敏化的单光子光引发剂体系。