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    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
    1.
    发明授权
    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
    含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法

    公开(公告)号：US5296566A

    公开(公告)日：1994-03-22

    申请号：US992381

    申请日：1992-12-16

    申请人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormic

    发明人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormic

    IPC分类号： C08F4/06 ,  C08F4/42 ,  C08F4/80 ,  C08G61/06 ,  C08G61/08 ,  C08L61/08

    CPC分类号： C08G61/08 ,  Y10S526/943

    摘要： Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1)(L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ; wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC.dbd.CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least one of ##STR1## groups, (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.

    摘要翻译： 环应变环状烯烃的聚合在其为空气和湿气稳定的，并且其包括一个含过渡金属的化合物的一部分或两部分催化剂的存在下进行。 单部分含过渡金属的催化剂选自（a）式（L1）（L2）Q，其中Q代表Mo或W的化合物的组中选择; L1代表一至六个CO（羰基）配体; L2代表无5个配体，它们各自是可以相同或不同的非离子化合物或聚合物单元，每个赋予金属二，四或六个电子，并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18，（b）至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐，和（c）（Ir （RO2CHC = CHCO2R）2Cl）2，其中每个R独立地为氢或低级烷基（C1-C4），条件是金属的氧化态在+3至0的范围内，并且含有C-卤键的助催化剂为 不存在。 两部分催化剂包括（a）含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，和（b）选自（i）的助催化剂， 末端或甲硅烷基炔，（ii）含有（*化学结构*）基团中的至少一个的有机硅烷，（iii）含氧原子与非氧原子双键的氧化性盐或氧化性化合物，和（iv）含杂原子的烯烃 。 所述聚合的组合物是提供模塑制品，弹性体，电介质支撑件，离子载体或生物活性材料，复合材料，等是有用的。

    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
    2.
    发明授权
    Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor 失效
    含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法

    公开(公告)号：US5198511A

    公开(公告)日：1993-03-30

    申请号：US811785

    申请日：1991-12-20

    申请人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormick

    发明人： Katherine A. Brown-Wensley ,  Michael C. Palazzotto ,  William M. Lamanna ,  Larry D. Boardman ,  John E. Gozum ,  Fred B. McCormick

    IPC分类号： C08F4/06 ,  C08F4/42 ,  C08F4/80 ,  C08G61/06 ,  C08G61/08 ,  C08L61/08

    CPC分类号： C08G61/08 ,  Y10S526/943

    摘要： Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1) (L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ;wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC=CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least ##STR1## (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.

    摘要翻译： 环应变环烯烃的聚合在空气和水分稳定的含有过渡金属的化合物的一部分或两部分催化剂存在下进行。 一部分过渡金属的催化剂选自（a）式（L1）（L2）Q化合物，其中Q表示Mo或W; L1代表一至六个CO（羰基）配体; L2代表无5个配体，它们各自是可以相同或不同的非离子化合物或聚合物单元，每个赋予金属二，四或六个电子，并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18，（b）至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐，和（c）[Ir （RO2CHC = CHCO2R）2Cl] 2，其中每个R独立地为氢或低级烷基（C1-C4），条件是金属的氧化态在+3至0的范围内，并且含有C-卤键的助催化剂为 不存在。 两部分催化剂包含（a）含过渡金属的催化剂，条件是过渡金属的氧化态在+3至0的范围内，和（b）选自（i）的助催化剂， （ii）至少含有（iii）氧化盐或含有氧原子的氧化化合物与非氧原子双键的有机硅烷，（iv）含杂原子的烯烃的有机硅烷。 聚合的组合物可用于提供模塑制品，弹性体，电介质载体，离子或生物活性材料，复合材料等。

    Flowable dry powder composition
    5.
    发明授权
    Flowable dry powder composition 有权
    可流动的干粉组合物

    公开(公告)号：US09310310B2

    公开(公告)日：2016-04-12

    申请号：US13534030

    申请日：2012-06-27

    申请人： John E. Gozum

    发明人： John E. Gozum

    IPC分类号： G01N21/78 ,  G01N31/22

    CPC分类号： G01N21/78 ,  G01N31/22

    摘要： A flowable dry powder composition comprising a mixture of diphenylcarbazide particles and glass bubbles; kits containing such compositions; methods of filling containers with such compositions; and, methods of using such compositions in the detecting of hexavalent chromium.

    摘要翻译： 包含二苯基卡巴肼颗粒和玻璃泡的混合物的可流动的干粉组合物; 含有此类组合物的试剂盒; 用这种组合物填充容器的方法; 以及使用这些组合物检测六价铬的方法。

    Illumination device
    7.
    发明授权
    Illumination device 失效
    照明装置

    公开(公告)号：US06799880B2

    公开(公告)日：2004-10-05

    申请号：US10039970

    申请日：2001-12-31

    申请人： John E. Gozum ,  Thomas J. Reid ,  Gerald L. Uhl

    发明人： John E. Gozum ,  Thomas J. Reid ,  Gerald L. Uhl

    IPC分类号： F21V800

    CPC分类号： G02B6/001 ,  Y10S385/901

    摘要： Illumination devices comprising a light source and a light fiber are reported. The light fiber is optically coupled to the light source such that at least a portion of the light emitted from the light source impinges on the input end of the light fiber. The light fiber comprises an elongate polymeric core having an input end for receiving light from a light source, an output end for emitting light transmitted through the core, and a lateral surface extending along a longitudinal axis of the core between the input end and the output end. The light fiber includes a light-emitting region including at least one optical element that directs light traveling though the light fiber out of at least a portion the lateral surface of the light fiber in a direction generally transverse to the longitudinal axis. A continuous outer cladding layer comprising a polymeric material having a lower index of refraction than the core extends over the lateral surface of the core and the optical elements.

    摘要翻译： 报道了包括光源和光纤的照明装置。 光纤光学耦合到光源，使得从光源发射的光的至少一部分撞击光纤的输入端。 光纤包括细长的聚合物芯，其具有用于接收来自光源的光的输入端，用于发射透过芯的光的输出端以及在输入端和输出端之间沿着芯的纵向轴线延伸的侧表面 结束。 光纤包括包括至少一个光学元件的发光区域，该至少一个光学元件将通过光纤行进的光从大致横向于纵向轴线的方向引导出光纤的侧表面的至少一部分。 包括具有比芯更低的折射率的聚合物材料的连续外包层在芯的侧表面和光学元件上延伸。

    DYE COMPOSITIONS
    8.
    发明申请
    DYE COMPOSITIONS 有权
    DYE组合物

    公开(公告)号：US20130052741A1

    公开(公告)日：2013-02-28

    申请号：US13534035

    申请日：2012-06-27

    申请人： John E. Gozum

    发明人： John E. Gozum

    IPC分类号： G01N21/75

    CPC分类号： G01N31/22 ,  G01N21/78

    摘要： Dye compositions comprising rhodizonate dye particles encapsulated within a shearable hydrophobic organic encapsulant composition.

    摘要翻译： 包含包含在可剪切的疏水性有机密封剂组合物内的靛红染料颗粒的染料组合物。

    Centralized management of replacement vehicle labels
    9.
    发明授权
    Centralized management of replacement vehicle labels 有权
    集中管理更换车辆标签

    公开(公告)号：US07540420B2

    公开(公告)日：2009-06-02

    申请号：US11866188

    申请日：2007-10-02

    申请人： Mark F. Schulz ,  Jeffrey R. Janssen ,  John E. Gozum ,  Gary L. Asmus

    发明人： Mark F. Schulz ,  Jeffrey R. Janssen ,  John E. Gozum ,  Gary L. Asmus

    IPC分类号： G06F17/60

    CPC分类号： G06Q10/06

    摘要： A central labeling data (CLD) management system provides centralized management, assembly, and distribution of labeling data for use in generating replacement labels for damaged vehicles. For example, the CLD management system includes a database that stores label data for a plurality of vehicles produced by a plurality of different manufacturers. The CLD management system presents an interface to receive an electronic communication from a client computing device associated with a repair shop. The electronic communication includes a request for label data associated with an original vehicle label. The CLD management system retrieves the requested label data from the database and communicates the label data to an output device for printing a new vehicle label for use by the repair shop.

    摘要翻译： 中央标签数据（CLD）管理系统提供集中管理，组装和分发标签数据，用于为损坏的车辆生成替换标签。 例如，CLD管理系统包括存储由多个不同制造商生产的多个车辆的标签数据的数据库。 CLD管理系统提供接口，用于从与修理车间相关联的客户端计算设备接收电子通信。 电子通信包括与原始车辆标签相关联的标签数据的请求。 CLD管理系统从数据库中检索所请求的标签数据，并将标签数据传送到输出设备，以打印修理车间使用的新车辆标签。