公开(公告)号：US5112979A

公开(公告)日：1992-05-12

申请号：US619535

申请日：1990-11-29

Applicant: Jiang-Jen Lin ,  Michael Cuscurida ,  Harold G. Waddill

Inventor： Jiang-Jen Lin ,  Michael Cuscurida ,  Harold G. Waddill

IPC: C07D211/58 ,  C08K5/3435

CPC classification number: C07D211/58 ,  C08K5/3435

Abstract: A compound of the formula: ##STR1## where each of the R groups are the same and include a C.sub.1 to C.sub.4 alkyl and R' is either ##STR2## where x is a number from 2 to 10 is disclosed. The use of the prescribed component as a light, heat and oxidation stabilizer in polyurea, polyurethane and polyurethane-urea elastomers, as well as epoxy systems, is also disclosed.

公开(公告)号：US5010160A

公开(公告)日：1991-04-23

申请号：US430686

申请日：1989-10-30

Applicant: George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

Inventor： George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

IPC: C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/32 ,  C08G18/50 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08G18/80

CPC classification number: C08G18/8061 ,  C08G18/0852 ,  C08G18/089 ,  C08G18/10 ,  C08G18/282 ,  C08G18/3228 ,  C08G18/5024 ,  C08G18/73 ,  C08G18/75 ,  C08G18/765 ,  C08G18/8038

Abstract: Polyoxyalkylene diamine reaction products which contain as the principle reaction component, a diamine having the formula: ##STR1## wherein R' independently represents hydrogen or methyl and x is a number having an average value of at least 1 to about 60 and a diisocyanate of the formula: ##STR2## The products of the invention are obtained by reacting an excess of polyoxyalkylene diamine with a diisocyanate in the presence of a polar solvent and have the following general structures: ##STR3## where B is alkyl group from diisocyanates, and R' has the same meaning as above.These products are further used to prepare coatings with improved properties by reacting said amine products with isocyanates prepolymers and epoxy material.

Abstract translation: 含有作为主要反应组分的聚氧亚烷基二胺反应产物，具有下式的二胺：其中R'独立地表示氢或甲基，x是平均值至少为1至约60的数，和 本发明的产品是通过在极性溶剂存在下使过量的聚氧化烯二胺与二异氰酸酯反应得到的，并具有以下通用结构：其中B是 烷基，二烷基，R'与上述相同。 这些产品进一步用于通过使所述胺产物与异氰酸酯预聚物和环氧材料反应来制备具有改进性能的涂层。

公开(公告)号：US4906774A

公开(公告)日：1990-03-06

申请号：US78309

申请日：1987-07-27

Applicant: George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

Inventor： George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

IPC: C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/32 ,  C08G18/50 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08G18/80

CPC classification number: C08G18/8061 ,  C08G18/0852 ,  C08G18/089 ,  C08G18/10 ,  C08G18/282 ,  C08G18/3228 ,  C08G18/5024 ,  C08G18/73 ,  C08G18/75 ,  C08G18/765 ,  C08G18/8038

Abstract: Polyoxyalkylene diamine reaction products which contain as the principle reaction component, a diamine having the formula: ##STR1## wherein R' independently represents hydrogen or methyl and x is a number having an average value of at least 1 to about 60 and a diisocyanate of the formula: ##STR2## The products of the invention are obtained by reacting an excess of polyoxyalkylene diamine with a diisocyanate in the presence of a polar solvent and have the following general structures: ##STR3## where B is alkyl group from diisocyanates, and R' has the same meaning as above.These products are further used to prepare coatings with improved properties by reacting said amine products with isocyanates prepolymers and epoxy material.

Abstract translation: 含有作为主要反应组分的聚氧亚烷基二胺反应产物，具有下式的二胺：其中R'独立地表示氢或甲基，x是平均值至少为1至约60的数，和 OCN（CH 2）6 NCO本发明的产物是通过在极性溶剂存在下使过量的聚氧化亚烷基二胺与二异氰酸酯反应而得到的，具有以下通用结构： 其中B是二异氰酸酯的烷基，R'具有与上述相同的含义。 这些产品进一步用于通过使所述胺产物与异氰酸酯预聚物和环氧材料反应来制备具有改进性能的涂层。

公开(公告)号：US4904751A

公开(公告)日：1990-02-27

申请号：US135951

申请日：1987-12-21

Applicant: George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

Inventor： George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

IPC: C09D175/04 ,  C08G18/32 ,  C08G18/50 ,  C08G18/80 ,  C09D175/00 ,  C09D175/08

CPC classification number: C08G18/8061 ,  C08G18/3228 ,  C08G18/5024

Abstract: A polyurethane coating composition is disclosed which may be heat cured under relatively mild conditions. The composition comprises a chemically blocked isocyanate and a curing agent comprising an N,N'-dialkyl substituted polyoxyalkylene amine.

公开(公告)号：US4761465A

公开(公告)日：1988-08-02

申请号：US78314

申请日：1987-07-27

Applicant: George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

Inventor： George P. Speranza ,  Jiang-Jen Lin ,  Michael Cuscurida

IPC: C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/32 ,  C08G18/50 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08G18/80

CPC classification number: C08G18/8061 ,  C08G18/0852 ,  C08G18/089 ,  C08G18/10 ,  C08G18/282 ,  C08G18/3228 ,  C08G18/5024 ,  C08G18/73 ,  C08G18/75 ,  C08G18/765 ,  C08G18/8038

Abstract: Diisocyanate and polyoxyalkylene diamine reaction products which contain as the principle reaction component, a diamine having the formula: ##STR1## wherein R' independently represents hydrogen or methyl and x is a number having an average value of at least 1 to about 60 and a diisocyanate of the formula: ##STR2## The products of the invention are obtained by reacting a polyoxyalkylene diamine with an excess of diisocyanate in the presence of a polar solvent to obtain products with the following general structures: ##STR3## where B is alkyl group from diisocyanates. These products and the corresponding blocked isocyanate prepolymer are further used to prepare coatings by reaction with polyoxyalkylene polyamine.

Abstract translation: 含有作为主要反应组分的二异氰酸酯和聚氧亚烷基二胺反应产物，具有下式的二胺：其中R'独立地表示氢或甲基，x是平均值至少为1至约60的数，和二异氰酸酯 通过在极性溶剂的存在下使聚氧亚烷基二胺与过量的二异氰酸酯反应获得本发明的产物，得到具有以下一般结构的产物： 其中B是二异氰酸酯的烷基。 这些产物和相应的封端异氰酸酯预聚物进一步用于通过与聚氧化烯多胺反应来制备涂层。

公开(公告)号：US5068444A

公开(公告)日：1991-11-26

申请号：US429671

申请日：1989-10-31

Applicant: Michael Cuscurida ,  David R. McCoy ,  Jiang-Jen Lin

Inventor： Michael Cuscurida ,  David R. McCoy ,  Jiang-Jen Lin

IPC: C07C217/08 ,  C08G18/50 ,  C08G18/56 ,  C08G65/26 ,  C08G65/325 ,  C08G65/331 ,  C08L63/00

CPC classification number: C08G65/331 ,  C07C217/08 ,  C08G18/5024 ,  C08G18/56 ,  C08G65/2609 ,  C08G65/3255 ,  C08L63/00 ,  C08G2120/00

Abstract: A process in which a dialdehyde is reacted with a polyoxyalkylene glycol to form a dialdehyde glycol condensate which is alkoxylated with propylene oxide, butylene oxide or mixtures thereof and the resulting product is then catalytically aminated to provide, for example, a tetramine is disclosed. These compounds are useful as curing agents for epoxy resins and for reaction with isocyanates to prepare polyurea elastomers and to manufacture articles, such as automotive body panels by reaction injection molding.

Abstract translation: 其中二醛与聚亚氧烷基二醇反应以形成二氧化二醇缩合物，其用环氧丙烷，环氧丁烷或其混合物进行烷氧基化，然后所得产物进行催化胺化以提供例如四胺。 这些化合物可用作环氧树脂的固化剂并用于与异氰酸酯反应以制备聚脲弹性体，并通过反应注射成型制备制品，例如汽车车身面板。

公开(公告)号：US4990576A

公开(公告)日：1991-02-05

申请号：US429672

申请日：1989-10-31

Applicant: Michael Cuscurida ,  Jiang-Jen Lin

Inventor： Michael Cuscurida ,  Jiang-Jen Lin

IPC: C08G65/26 ,  C08G65/28 ,  C08G65/325 ,  C08L63/00

CPC classification number: C08G65/3255 ,  C08G65/2609 ,  C08L63/00

Abstract: A process in which a di-trimethylol alkane initiator is oxyalkylated to form an alkylene oxide adduct which is then catalytically aminated to provide, for example, a tetramine. These compounds are useful for preparing polyurethane products and as curing agents for epoxy resins.

Abstract translation: 其中二 - 三羟甲基烷烃引发剂被烷氧基化以形成烯化氧加合物的方法，然后进行催化胺化以提供例如四胺。 这些化合物可用于制备聚氨酯产品和用作环氧树脂的固化剂。

公开(公告)号：US08952087B2

公开(公告)日：2015-02-10

申请号：US12258402

申请日：2008-10-25

Applicant: Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

Inventor： Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

IPC: C08K3/08 ,  B22F9/00 ,  B22F1/00 ,  B22F9/24 ,  B82Y30/00

CPC classification number: B22F9/24 ,  B22F1/0022 ,  B22F2999/00 ,  B82Y30/00 ,  B22F1/0059

Abstract: The present invention provides a method for reducing metal ions (for example, silver ions) and stably dispersing metal nanoparticles by nanosilicate platelets. An organic dispersant, nanosilicate platelets and a metal ionic solution are mixed to perform a reductive reaction, wherein the organic dispersant is tri-sodium citrate dihydrate (SCD), chitosan or polyvinyl pyrrolidone (PVP), to produce a mixture of stably dispersed metal nanoparticles.

Abstract translation: 本发明提供了还原金属离子（例如银离子）并通过纳米硅酸盐片稳定分散金属纳米粒子的方法。 将有机分散剂，纳米硅酸盐片和金属离子溶液混合以进行还原反应，其中有机分散剂是柠檬酸三钠二水合物（SCD），壳聚糖或聚乙烯吡咯烷酮（PVP）），以产生稳定分散的金属纳米颗粒 。

公开(公告)号：US20130172447A1

公开(公告)日：2013-07-04

申请号：US13561072

申请日：2012-07-29

Applicant: Jiang-Jen Lin ,  Ying-Nan Chan ,  Jau-Yu Chiou

Inventor： Jiang-Jen Lin ,  Ying-Nan Chan ,  Jau-Yu Chiou

IPC: C09K21/12 ,  C08K3/36 ,  C08L63/02 ,  B82Y30/00

CPC classification number: C08K5/5399 ,  B82Y30/00 ,  C07F9/65815 ,  C08K9/04 ,  C08L63/00 ,  C09K21/12

Abstract: A phosphorous flame retardant including nanosilicate platelets (NSP) is made by first reacting hexachlorotriphosphazene (HCP) with poly(oxyalkylene)amine, then mixing the HCP product with nano silicate platelets (NSP) to obtain the phosphorous flame retardant including NSP. The phosphorous flame retardant can be further applied to an epoxy resin as a curing agent.

Abstract translation: 通过首先使六氯三磷腈（HCP）与聚（氧化烯）胺反应，然后将HCP产物与纳米硅酸盐血小板（NSP）混合以获得包括NSP的磷阻燃剂，制备包括纳米硅酸盐血小板（NSP）的磷阻燃剂。 磷阻燃剂可以进一步用作环氧树脂作为固化剂。

公开(公告)号：US20130005918A1

公开(公告)日：2013-01-03

申请号：US13612052

申请日：2012-09-12

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

IPC: C07C231/02 ,  C08F8/32

CPC classification number: C08F26/00

Abstract: Polymeric polyamine is produced by polymerizing polyoxyalkylene-amine and a linker. The polyoxyalkylene-amine has a structural formula H2N—R—NH2, wherein R is selected from the group consisting of dianhydride, diacid, epoxy, diisocyanate and poly(styrene-co-maleic anhydride) copolymers (SMA). The linker can be anhydride, carboxylic acid, epoxy, isocyanate or poly(styrene-co-maleic anhydride) copolymers (SMA). The polymeric polyamine so produced can be used as a stabilizer or dispersant of the Ag nanoparticles.

Abstract translation: 聚合多胺通过聚合聚氧亚烷基 - 胺和接头来制备。 聚氧化烯胺具有结构式H2N-R-NH2，其中R选自二酐，二酸，环氧，二异氰酸酯和聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 接头可以是酐，羧酸，环氧，异氰酸酯或聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 如此生产的聚合多胺可用作Ag纳米颗粒的稳定剂或分散剂。