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公开(公告)号：US20070293705A1
公开(公告)日：2007-12-20
申请号：US10587207
申请日：2005-02-01
IPC分类号： C07C215/08
CPC分类号： C07C213/02 , C07C45/89 , C07C49/88 , C07C217/08
摘要： Severely sterically hindered secondary aminoether alcohols are prepared by reacting organic carboxylic, organic carboxylic acid halides, acid anhydrides or a ketene with an alkyl, alkaryl or alkylhalo sulfonate to yield a sulfonic-carboxylic anhydride compound which is then reacted with a dioxane to cleave the ring of the dioxane, yielding a cleavage product which cleavage product is then animated with an alkylamine and hydrolyzed with base to yield the severely sterically hindered secondary aminoether alcohol.
摘要翻译： 通过使有机羧酸，有机羧酸卤化物，酸酐或烯酮与烷基，烷基芳基或烷基卤代磺酸反应制得极度空间位阻的仲氨基醚醇，得到磺酸羧酸酐化合物，然后与二恶烷反应以切割环 的二恶烷，产生裂解产物，然后将裂解产物用烷基胺进行动画化，并用碱水解，得到严重位阻的仲氨基醚醇。
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2.发明申请公开(公告)号：US20070287866A1
公开(公告)日：2007-12-13
申请号：US10587204
申请日：2005-02-01
IPC分类号： C07C213/00
CPC分类号： C07C213/02 , C07C215/08
摘要： Severely sterically hindered secondary aminoether alcohols are prepared by a process comprising reacting a ketene with sulfuric acid to produce an anhydride which is then reacted with, to cleave the ring of, a dioxane to yield a cleavage product which is then aminated using an amine, followed by hydrolysis with a base to yield the desired severely sterically hindered secondary aminoether alcohol.
摘要翻译： 通过包括使乙烯酮与硫酸反应以产生酸酐的方法来制备严格位阻的仲氨基醚醇，所述酸酐然后与二恶烷的环进行反应以切割二环环，得到裂解产物，然后使用胺将其胺化，随后 通过用碱水解产生所需的严格空间位阻的仲氨基醚醇。
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3.发明申请Synthesis of Sterically Hindered Secondary Aminoether Alcohols from Acid Anhydride and/or Acid Halide and Sulfur Trioxide 有权由酸酐和/或酰基卤化铝和三氧化硫合成从第二个氨基醚醇引发的受阻的二级氨基醚公开(公告)号：US20070260092A1
公开(公告)日：2007-11-08
申请号：US10587199
申请日：2005-02-01
IPC分类号： C07C209/00
CPC分类号： C07C213/08 , C07C217/08
摘要： Severely sterically hindered secondary aminoether alcohols are prepared by reacting acid anhydrides or organic carboxylic acid halides with SO3 to yield a sulfonic carboxylic anhydride compound which is then reacted with a dioxane to cleave the ring of the dioxane yielding a cleavage product which is then aminated with an alkylamine and hydrolyzed with a base to yield the severely sterically hindered secondary aminoether alcohol.
摘要翻译： 通过使酸酐或有机羧酸卤化物与SO 3 3反应制备严格的空间位阻的仲氨基醚醇，得到磺酸酐化合物，然后与二恶烷反应以切割二烷环，产生 裂解产物然后用烷基胺胺化并用碱水解，得到严重位阻的仲氨基醚醇。
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4.发明申请Catalytic Preparation of Severely Sterically Hindered Amino-Ether Alcohols Using a Metal Loaded Catalyst 有权使用金属负载催化剂催化制备严重受阻的氨基醚醇公开(公告)号：US20070276162A1
公开(公告)日：2007-11-29
申请号：US10587198
申请日：2005-02-01
IPC分类号： C07C209/16
CPC分类号： C07C213/02 , C07C217/08
摘要： The present invention relates to a process for the production of severely sterically hindered amino-ether alcohols using a catalyst based on the combination of one or more catalytically active metals supported in a dispersed form on one or more ordered mesoporous materials as support.
摘要翻译： 本发明涉及使用基于以一种或多种有序介孔材料作为载体以分散形式负载的一种或多种催化活性金属的组合的催化剂来生产严格位阻氨基醚醇的方法。
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5.发明申请公开(公告)号：US20050150815A1
公开(公告)日：2005-07-14
申请号：US10652389
申请日：2003-08-29
申请人： Jack Johnson , Adeana Bishop , William Genetti , Loren Ansell , Rocco Fiato
发明人： Jack Johnson , Adeana Bishop , William Genetti , Loren Ansell , Rocco Fiato
IPC分类号： C10G45/58 , C10G45/62 , C10G45/64 , C10G65/04 , C10M101/02 , C10M105/04 , C10M171/00 , C10M171/02 , C10M11/02
CPC分类号： C10G45/64 , C10G45/58 , C10G45/62 , C10G65/043 , C10M101/025 , C10M105/04 , C10M171/00 , C10M171/02 , C10M2203/1025 , C10M2205/173 , C10N2220/022 , C10N2220/025 , C10N2220/028
摘要： A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI−0.5(CH2>4) 4)
摘要翻译： 具有至少95重量％的石蜡分子的重质烃组合物是含有连续碳原子的烃分子的至少95重量％的链烷烃分子，其中至少90重量％是异链烷烃，是100℃的液体， 在该温度下，其通过ASTM D-445测量的运动粘度高于8cSt，具有至少850°F（454℃）的初始沸点和至少1000°F的终沸点（ 538℃），其中通过甲基氢的百分比测量的支化指数（BI）和通过重复亚甲基碳的百分比测量的支化邻近度（CH 2 N 2） 其是从所述异链烷烃分子的端基或分支中除去的四个或更多个碳原子，使得：（a）BI-0.5（CH 2 2 4）<15; 和（b）BI + 0.85（CH 2 2 > 4）<45; 如在整个重质烃组合物上测得的。
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公开(公告)号：US20060219597A1
公开(公告)日：2006-10-05
申请号：US11374726
申请日：2006-03-14
申请人： Adeana Bishop , Loren Ansell , W. Genetti , Michel Daage , Daniel Ryan , Eric Sirota , Jack Johnson , Patrick Brant
发明人： Adeana Bishop , Loren Ansell , W. Genetti , Michel Daage , Daniel Ryan , Eric Sirota , Jack Johnson , Patrick Brant
CPC分类号： C10G73/00 , C10L1/16 , C10L1/1616 , C10L1/1691 , C10L10/16 , C10M111/04 , C10M169/041 , C10M2205/022 , C10M2205/0225 , C10M2205/17 , C10M2205/173 , C10N2230/08
摘要： Heavy fractions of paraffinic lubes produced over dewaxing catalysts are effective as wax crystal modifiers for being hydrocarbons notwithstanding that such heavy fractions have pour points above that of the liquid hydrocarbon.
摘要翻译： 在脱蜡催化剂上生产的石蜡油的重馏分作为用作烃的蜡结晶改性剂是有效的，尽管这种重馏分的倾点高于液态烃的倾点。
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公开(公告)号：US20080083648A1
公开(公告)日：2008-04-10
申请号：US11974080
申请日：2007-10-11
申请人： Adeana Bishop , William Genetti , Nancy Page , Loren Ansell , Jack Johnson
发明人： Adeana Bishop , William Genetti , Nancy Page , Loren Ansell , Jack Johnson
IPC分类号： C10G73/02
CPC分类号： C10G2/30 , C10G2400/10
摘要： A heavy lubricant base stock is made by (a) producing a synthesis gas from natural gas, (b) reacting the H2 and CO in the gas in the presence of a cobalt Fischer-Tropsch catalyst, at reaction conditions effective to synthesize waxy hydrocarbons boiling in the heavy lubricant oil range, which are hydrodewaxed it at least two stages, with interstage separation and removal of the lighter material.
摘要翻译： 重质润滑剂基础原料是通过（a）从天然气生产合成气制备的，（b）使钴 - 费 - 托催化剂存在下的气体中的H 2 H 2和CO与 有效地合成在重润滑油范围内沸腾的蜡质烃的反应条件，其被加氢脱蜡至少两个阶段，通过级间分离和去除较轻的材料。
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公开(公告)号：US20070155614A1
公开(公告)日：2007-07-05
申请号：US11708947
申请日：2007-02-20
申请人： Adeana Bishop , William Genetti , Jack Johnson , Loren Ansell , Nancy Page
发明人： Adeana Bishop , William Genetti , Jack Johnson , Loren Ansell , Nancy Page
CPC分类号： B01J29/7461 , B01J29/068 , B01J29/67 , B01J29/7453 , B01J29/7484 , B01J29/7492 , B01J31/0201 , B01J37/12 , B01J37/18 , C10G2/332 , C10G45/64
摘要： Fischer-Tropsch hydrocarbon synthesis using a cobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided 10-ring, 1-dimensional zeolite catalyst that has been reduced and then treated by contacting it with the synthesized hydrocarbons containing one or more oxygenates, including indigenous oxygenate. Tail gas from the hydrodewaxing reactor can be used for the hydrocarbon synthesis.
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9.发明申请Integrated plant process to produce high molecular weight basestocks from fischer-tropsch wax 审中-公开从费 - 托蜡生产高分子量基础油的综合植物过程公开(公告)号：US20050284797A1
公开(公告)日：2005-12-29
申请号：US11109122
申请日：2005-04-19
申请人： William Genetti , Adeana Bishop , Louis Burns , Loren Ansell , Jack Johnson , Charles Mauldin
发明人： William Genetti , Adeana Bishop , Louis Burns , Loren Ansell , Jack Johnson , Charles Mauldin
CPC分类号： C10G2/32 , C10G2400/10
摘要： High viscosity lube base oils are produced from syngas by converting syngas under Fischer-Tropsch reaction conditions which are sufficient to produce hydrocarbon products containing greater than 20 lbs of 700° F.+(371° C.+) product per 100 lbs of CO converted. A 450° F.+(232° C.+) cut is separated from the hydrocarbon products and catalytically hydroisomerized and distilled to provide high viscosity lube base oils.
摘要翻译： 通过在费 - 托反应条件下转化合成气制备高粘度润滑油基础油，该条件足以产生含有大于20磅700°F +（371℃+）产物的烃产物，每100磅CO转化 。 将450°F +（232°C +）切割与烃产物分离并进行催化加氢异构化和蒸馏，以提供高粘度润滑油基础油。
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