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    Preparation of dialkoxybutenes
    5.
    发明授权
    Preparation of dialkoxybutenes 失效
    DIALKOXYBUTENES的制备

    公开(公告)号：US5159120A

    公开(公告)日：1992-10-27

    申请号：US714584

    申请日：1991-06-13

    申请人： Michel Costantini ,  Dominique Laucher

    发明人： Michel Costantini ,  Dominique Laucher

    IPC分类号： B01J27/057 ,  C07B61/00 ,  C07C41/06 ,  C07C43/15

    CPC分类号： C07C41/06

    摘要： Dialkoxybutenes are selectively prepared in high yields by reacting 1,3-butadiene with an alcohol in the presence of oxygen and a catalytically effective amount of solid particulates which comprise a catalytically active phase deposited onto particles of a support therefor, such catalytically active phase comprising at least one Group VIII noble metal first component, at least one tellurium, selenium and/or sulfur second component, and, optionally, at least one bismuth, antimony, copper and/or tin third component.

    摘要翻译： 通过在氧的存在下使1,3-丁二烯与醇反应并且催化有效量的固体颗粒包含沉积在其载体的颗粒上的催化活性相来选择性地制备二烷氧基丁烯，所述催化活性相包含在 至少一种VIII族贵金属第一组分，至少一种碲，硒和/或硫第二组分，以及任选的至少一种铋，锑，铜和/或锡第三组分。

    Epoxidation of olefinic compounds
    6.
    发明授权
    Epoxidation of olefinic compounds 失效
    烯烃化合物的环氧化

    公开(公告)号：US4093636A

    公开(公告)日：1978-06-06

    申请号：US768630

    申请日：1977-02-14

    申请人： Pierre-Etienne Bost ,  Michel Costantini

    发明人： Pierre-Etienne Bost ,  Michel Costantini

    IPC分类号： B01J31/12 ,  B01J37/24 ,  C07D301/20

    CPC分类号： B01J37/24 ,  B01J31/122 ,  B01J2231/72

    摘要： Tin catalysts are provided for epoxidizing olefinic compounds in the presence of organic hydroperoxides, in the liquid phase. These catalysts give good yields of the epoxide and of the alcohol derived from the organic hydroperoxide. They have the formula: RR 'SnCl.sub.2 (I) in which:R represents a wholly aliphatic or cycloaliphatic or aromatic or mixed aliphatic/aromatic, aliphatic/cycloaliphatic or cycloaliphatic/aromatic, inter alia alkylaryl or aralkyl, linear or branched, saturated or unsaturated monovalent hydrocarbon radical, which can optionally carry substituents, such as chlorine atoms, the number of carbon atoms being at most 20,R' represents either a chlorine atom or a monovalent organic radical of the formula: R"--Y (II) in which:Y represents an oxygen atom, or a (--O--O--) group, or a carbonyloxy group (--CO--O--), the radical R" being attached to the carbon atom of the (--CO--O--),R" may be identical or different to R and is as defined under R.

    摘要翻译： 在有机氢过氧化物存在下，在液相中提供锡催化剂用于环氧化烯属化合物。 这些催化剂产生环氧化物和衍生自有机氢过氧化物的醇的良好产率。 他们有公式：

    Hydrocarbon, alcohol and/or ketone oxidation method
    8.
    发明授权
    Hydrocarbon, alcohol and/or ketone oxidation method 失效
    烃，醇和/或酮氧化方法

    公开(公告)号：US06762319B1

    公开(公告)日：2004-07-13

    申请号：US09937764

    申请日：2002-04-16

    申请人： Eric Fache ,  Michel Costantini

    发明人： Eric Fache ,  Michel Costantini

    IPC分类号： C07C5116

    CPC分类号： C07C29/50 ,  C07C51/313 ,  C07C2601/14 ,  C07C55/14 ,  C07C35/08

    摘要： The present invention relates to the oxidation, by means of oxygen or a gas containing it, of hydrocarbons to the corresponding carboxylic acids, alcohols and/or ketones or of alcohols and/or ketones to the corresponding carboxylic acids. It consists more precisely in a process for oxidizing hydrocarbon, alcohol and/or ketone, using oxygen or a gas containing it, in liquid phase and in the presence of a catalyst dissolved in the reaction medium, characterized in that the catalyst comprises a soluble manganese compound and at least one soluble chromium compound.

    摘要翻译： 本发明涉及通过氧气或含有它的气体将烃与相应的羧酸，醇和/或酮或醇和/或酮与相应的羧酸氧化。 它更精确地包括在液相中和在溶解在反应介质中的催化剂存在下，使用氧气或含有它的气体氧化烃，醇和/或酮的方法，其特征在于催化剂包含可溶性锰 化合物和至少一种可溶性铬化合物。

    Method for crystallizing carboxylic acid
    9.
    发明授权
    Method for crystallizing carboxylic acid 失效
    结晶羧酸的方法

    公开(公告)号：US06559339B1

    公开(公告)日：2003-05-06

    申请号：US09787127

    申请日：2001-05-31

    申请人： Michel Costantini ,  Eric Fache

    发明人： Michel Costantini ,  Eric Fache

    IPC分类号： C07C5142

    CPC分类号： C07C51/42 ,  C07C51/43 ,  C07C55/14

    摘要： The present invention relates to a process for the crystallization of carboxylic acid, more particularly adipic acid, and a process for manufacturing crystalline carboxylic acid, more specifically a process for treating the reaction medium resulting from the direct oxidation of a hydrocarbon into carboxylic acid such as adipic acid, for example. More specifically, the invention relates to the crystallization of adipic acid from an organic solvent, thus removing the organic impurities contained in the said acid and thus optionally facilitating its purification by a crystallization from water.

    摘要翻译： 本发明涉及一种结晶羧酸，更特别是己二酸的方法，以及一种制备结晶羧酸的方法，更具体地说，涉及一种处理由烃直接氧化成羧酸的反应介质的方法，例如 己二酸。 更具体地，本发明涉及己二酸从有机溶剂中的结晶，从而除去所述酸中所含的有机杂质，从而任选地通过从水中结晶而促进其纯化。

    Co/Cr catalyzyed oxidation of cyclohexane
    10.
    发明授权
    Co/Cr catalyzyed oxidation of cyclohexane 失效
    Co / Cr催化氧化环己烷

    公开(公告)号：US6147256A

    公开(公告)日：2000-11-14

    申请号：US58175

    申请日：1998-04-10

    申请人： Michel Costantini ,  Eric Fache

    发明人： Michel Costantini ,  Eric Fache

    IPC分类号： B01J31/04 ,  C07B61/00 ,  C07C27/12 ,  C07C51/21 ,  C07C51/215 ,  C07C51/235 ,  C07C51/245 ,  C07C51/31 ,  C07C55/14

    CPC分类号： C07C51/313

    摘要： Carboxylic acids, e.g., adipic acid, are more selectively prepared by oxidizing cyclohexane with oxygen or an oxygen-containing gas, in liquid phase, in a solvent reaction medium which comprises a polar protic or aprotic solvent, and also in the presence of a catalytically effective amount of catalyst values dissolved in said solvent reaction medium, the catalyst values comprising at least one solvent-soluble cobalt compound and at least one solvent-soluble chromium compound.

    摘要翻译： 通过在包含极性质子或非质子溶剂的溶剂反应介质中以及在催化剂存在下，在液相中用氧或含氧气体氧化环己烷，可以更有选择地制备羧酸，例如己二酸 有效量的溶解在所述溶剂反应介质中的催化剂值，所述催化剂值包含至少一种溶剂可溶性钴化合物和至少一种溶剂可溶性铬化合物。