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公开(公告)号：US5003114A
公开(公告)日：1991-03-26
申请号：US362584
申请日：1989-06-07
IPC分类号： B01J29/04 , C07B61/00 , C07C37/60 , C07C39/08 , C07C41/00 , C07C41/26 , C07C43/23 , C07C43/295 , C07C67/00
摘要： Phenols/phenol ethers are hydroxylated by reaction with hydrogen peroxide in the presence of a catalytically effective amount of a calcined germanozeosilite MFI zeolite.
摘要翻译： 苯酚/酚醚通过与催化有效量的煅烧锗烷基硅沸石MFI沸石的存在下与过氧化氢反应而羟化。
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公开(公告)号：US5254746A
公开(公告)日：1993-10-19
申请号：US930457
申请日：1992-08-19
摘要： The phenols and phenol ethers are hydroxylated by reaction with hydrogen peroxide in the presence of a catalytically effective amount of a titanozeosilite, advantageously a silicon oxide/titanium oxide MFI zeolite having the general formula:SI.sub.(96-x), Ti.sub.x O.sub.192.
摘要翻译： 苯酚和酚醚通过在催化有效量的钛硅硅酸盐存在下与过氧化氢反应而羟化，有利地是具有通式SI（96-x），TixO192的氧化硅/氧化钛MFI沸石。
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公开(公告)号：US5149888A
公开(公告)日：1992-09-22
申请号：US486429
申请日：1990-02-28
IPC分类号： B01J21/06 , C07B61/00 , C07C37/60 , C07C39/08 , C07C39/15 , C07C39/17 , C07C41/26 , C07C43/23 , C07C43/295
摘要： The phenols and phenol ethers, e.g., phenol itself, are effectively hydroxylated by reacting hydrogen peroxide therewith, in the presence of a catalytically effective amount of titanium dioxide.
摘要翻译： 在催化有效量的二氧化钛的存在下，苯酚和酚醚（例如苯酚本身）通过使过氧化氢与其反应而被有效羟化。
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4.发明授权Stannozeosilite/zirconozeosilite zeolites and catalytic hydroxylation of phenolics therewith 失效硅酸锌/氧化锆硅沸石沸石和酚醛树脂的催化羟基化
公开(公告)号：US5399336A
公开(公告)日：1995-03-21
申请号：US724215
申请日：1991-07-01
IPC分类号： B01J29/89 , B01J29/04 , B01J29/40 , C01B39/04 , C01B39/08 , C01B39/10 , C01B39/36 , C07C37/60 , C07C41/26 , C10G11/05 , C10G35/095 , C01B33/20
CPC分类号： C07C41/26 , B01J29/04 , C07C37/60 , Y10S423/22
摘要： Calcined silica/oxide zeolites, characteristically MFI stannozeosilites or zirconozeosilites, well adopted for catalyzing the H.sub.2 O.sub.2 hydroxylation of phenols or phenol ethers, have the formula (I):(Si.sub.96-x T'.sub.x)0.sub.192 (I)in which x is a number ranging from 0.1 to 5.0 and T' is tetravalent tin or tetravalent zirconium.
摘要翻译： 煅烧二氧化硅/氧化物沸石，特别是用于催化苯酚或酚醚的H 2 O 2羟基化的MFI锡酮化合物或氧化锆沸石具有式（I）：（Si96-xT'x）0192（I），其中x是数字范围 0.1〜5.0，T'为四价锡或四价锆。
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公开(公告)号：US4918238A
公开(公告)日：1990-04-17
申请号：US318911
申请日：1989-03-03
IPC分类号： B01J23/46 , C07B61/00 , C07C27/00 , C07C27/16 , C07C29/48 , C07C33/20 , C07C35/02 , C07C45/00 , C07C45/28 , C07C45/53 , C07C49/403 , C07C49/78 , C07C67/00
CPC分类号： C07C45/28 , C07C29/48 , C07C2101/14 , C07C2101/18
摘要： Mixtures of alcohols and ketones are selectively and actively produced by catalytically oxidizing at least one alkane with an organic hydroperoxide, in the presence of a catalytically effective amount of osmium or an osmium compound, notably osmium tetroxide.
摘要翻译： 在催化有效量的锇或锇化合物，特别是四氧化锇的存在下，通过用有机氢过氧化物催化氧化至少一种烷烃来选择性和主动地制备醇和酮的混合物。
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公开(公告)号：US5159120A
公开(公告)日：1992-10-27
申请号：US714584
申请日：1991-06-13
IPC分类号： B01J27/057 , C07B61/00 , C07C41/06 , C07C43/15
CPC分类号： C07C41/06
摘要： Dialkoxybutenes are selectively prepared in high yields by reacting 1,3-butadiene with an alcohol in the presence of oxygen and a catalytically effective amount of solid particulates which comprise a catalytically active phase deposited onto particles of a support therefor, such catalytically active phase comprising at least one Group VIII noble metal first component, at least one tellurium, selenium and/or sulfur second component, and, optionally, at least one bismuth, antimony, copper and/or tin third component.
摘要翻译： 通过在氧的存在下使1,3-丁二烯与醇反应并且催化有效量的固体颗粒包含沉积在其载体的颗粒上的催化活性相来选择性地制备二烷氧基丁烯，所述催化活性相包含在 至少一种VIII族贵金属第一组分，至少一种碲，硒和/或硫第二组分，以及任选的至少一种铋，锑，铜和/或锡第三组分。
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公开(公告)号：US4093636A
公开(公告)日：1978-06-06
申请号：US768630
申请日：1977-02-14
IPC分类号： B01J31/12 , B01J37/24 , C07D301/20
CPC分类号： B01J37/24 , B01J31/122 , B01J2231/72
摘要： Tin catalysts are provided for epoxidizing olefinic compounds in the presence of organic hydroperoxides, in the liquid phase. These catalysts give good yields of the epoxide and of the alcohol derived from the organic hydroperoxide. They have the formula: RR 'SnCl.sub.2 (I) in which:R represents a wholly aliphatic or cycloaliphatic or aromatic or mixed aliphatic/aromatic, aliphatic/cycloaliphatic or cycloaliphatic/aromatic, inter alia alkylaryl or aralkyl, linear or branched, saturated or unsaturated monovalent hydrocarbon radical, which can optionally carry substituents, such as chlorine atoms, the number of carbon atoms being at most 20,R' represents either a chlorine atom or a monovalent organic radical of the formula: R"--Y (II) in which:Y represents an oxygen atom, or a (--O--O--) group, or a carbonyloxy group (--CO--O--), the radical R" being attached to the carbon atom of the (--CO--O--),R" may be identical or different to R and is as defined under R.
摘要翻译： 在有机氢过氧化物存在下，在液相中提供锡催化剂用于环氧化烯属化合物。 这些催化剂产生环氧化物和衍生自有机氢过氧化物的醇的良好产率。 他们有公式：
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8.发明授权Process for the preparation of 3,5,5-trimethyl-cyclohex-2-ene-1,4-dione 失效制备3,5,5-三甲基 - 环己-2-烯-1,4-二酮的方法
公开(公告)号：US4092361A
公开(公告)日：1978-05-30
申请号：US751159
申请日：1976-12-16
IPC分类号： C07C49/403 , C07C45/00 , C07C45/34 , C07C45/35 , C07C49/603 , C07C67/00
CPC分类号： C07C45/34
摘要： 3,5,5-Trimethyl-cyclohex-2-ene-1,4-dione is prepared by a liquid phase oxidation of .beta.-isophorone using carbon black as catalyst in the presence of a base.
摘要翻译： 通过在碱存在下使用炭黑作为催化剂，通过β-异佛尔酮的液相氧化制备3,5,5-三甲基 - 环己-2-烯-1,4-二酮。
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公开(公告)号：US06762319B1
公开(公告)日：2004-07-13
申请号：US09937764
申请日：2002-04-16
申请人： Eric Fache , Michel Costantini
发明人： Eric Fache , Michel Costantini
IPC分类号： C07C5116
CPC分类号： C07C29/50 , C07C51/313 , C07C2601/14 , C07C55/14 , C07C35/08
摘要： The present invention relates to the oxidation, by means of oxygen or a gas containing it, of hydrocarbons to the corresponding carboxylic acids, alcohols and/or ketones or of alcohols and/or ketones to the corresponding carboxylic acids. It consists more precisely in a process for oxidizing hydrocarbon, alcohol and/or ketone, using oxygen or a gas containing it, in liquid phase and in the presence of a catalyst dissolved in the reaction medium, characterized in that the catalyst comprises a soluble manganese compound and at least one soluble chromium compound.
摘要翻译： 本发明涉及通过氧气或含有它的气体将烃与相应的羧酸，醇和/或酮或醇和/或酮与相应的羧酸氧化。 它更精确地包括在液相中和在溶解在反应介质中的催化剂存在下，使用氧气或含有它的气体氧化烃，醇和/或酮的方法，其特征在于催化剂包含可溶性锰 化合物和至少一种可溶性铬化合物。
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公开(公告)号：US06559339B1
公开(公告)日：2003-05-06
申请号：US09787127
申请日：2001-05-31
申请人： Michel Costantini , Eric Fache
发明人： Michel Costantini , Eric Fache
IPC分类号： C07C5142
摘要： The present invention relates to a process for the crystallization of carboxylic acid, more particularly adipic acid, and a process for manufacturing crystalline carboxylic acid, more specifically a process for treating the reaction medium resulting from the direct oxidation of a hydrocarbon into carboxylic acid such as adipic acid, for example. More specifically, the invention relates to the crystallization of adipic acid from an organic solvent, thus removing the organic impurities contained in the said acid and thus optionally facilitating its purification by a crystallization from water.
摘要翻译： 本发明涉及一种结晶羧酸，更特别是己二酸的方法，以及一种制备结晶羧酸的方法，更具体地说，涉及一种处理由烃直接氧化成羧酸的反应介质的方法，例如 己二酸。 更具体地，本发明涉及己二酸从有机溶剂中的结晶，从而除去所述酸中所含的有机杂质，从而任选地通过从水中结晶而促进其纯化。
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