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    Conductive polymers or prepolymers from a polymer containing ethylenic unsaturations and from a silane compound and conductive polymers or prepolymers
    1.
    发明授权
    Conductive polymers or prepolymers from a polymer containing ethylenic unsaturations and from a silane compound and conductive polymers or prepolymers 失效
    来自含有烯属不饱和基团和硅烷化合物的聚合物或导电聚合物或预聚物的导电聚合物或预聚物

    公开(公告)号：US4845153A

    公开(公告)日：1989-07-04

    申请号：US105449

    申请日：1987-10-05

    申请人： Michel Fontanille ,  Nicolas Krantz ,  Jean-Claude Gautier ,  Serge Raynal

    发明人： Michel Fontanille ,  Nicolas Krantz ,  Jean-Claude Gautier ,  Serge Raynal

    IPC分类号： C08C19/25 ,  C08F8/42 ,  H01B1/12

    CPC分类号： C08F8/42 ,  C08C19/25 ,  H01B1/12

    摘要： The invention relates to a process for the preparation of conductive polymers or prepolymers and to conductive polymers or prepolymers.The process of the invention consists of reacting a polymer containing ethylenic unsaturations such as a hydroxytelechelic polybutadiene with a silane compound of formula ##STR1## in which R.sub.1 denotes a hydrocarbon group containing at least one heteroatom bearing mobile electrons, such as the oxygen of an ether group, andR.sub.2 and R.sub.3 denote a substituted or unsubstituted organic residue or a group R.sub.1.The polymer obtained is precipitated by the addition of a compound which is not a solvent for the polymer, and is separated from the reaction medium.The polymers obtained have an electrical conductivity which is multiplied by a factor of 10.sup.5 relative to the unmodified polymer.The present invention applies in particular in the field of the polymer industry.

    摘要翻译： 本发明涉及制备导电聚合物或预聚物以及导电聚合物或预聚物的方法。 本发明的方法包括使包含乙烯不饱和基团的聚合物如羟基可卡因聚丁二烯与式（IMAGE）的硅烷化合物反应，其中R 1表示含至少一个带有移动电子的杂原子的烃基，例如醚的氧 基团，R 2和R 3表示取代或未取代的有机残基或基团R 1。 所得聚合物通过加入不是聚合物溶剂的化合物而沉淀，并与反应介质分离。 获得的聚合物相对于未改性聚合物的电导率乘以105倍。 本发明特别适用于聚合物工业领域。

    1,1,1 Tris-(4-isopropenyl-phenyl)ethane
    4.
    发明授权
    1,1,1 Tris-(4-isopropenyl-phenyl)ethane 失效
    1,1,1-三 - （4-异丙烯基 - 苯基）乙烷

    公开(公告)号：US4236035A

    公开(公告)日：1980-11-25

    申请号：US27295

    申请日：1979-04-05

    申请人： Pierre Sigwalt ,  Patrick Guyot ,  Michel Fontanille

    发明人： Pierre Sigwalt ,  Patrick Guyot ,  Michel Fontanille

    IPC分类号： C07C2/86 ,  C07C45/46 ,  C07C49/782 ,  C07F1/02 ,  C07F9/54 ,  C08F4/42 ,  C08F36/04 ,  C07C15/12

    CPC分类号： C07C45/46 ,  C07C2/861 ,  C07C49/782 ,  C07F1/02 ,  C07F9/5442 ,  C08F36/04

    摘要： New organo-lithium initiators, their synthesis, and their use. The initiators have the formula: ##STR1## in which R" is either a hydrogen atom or a methyl radical; either n is 1, in which case R' = H and m and p are integers, the sum of which is between 0 and 10 inclusive, or n is 2, R' then being an alkyl radical of 2 to 8 carbon atoms and m =p =0; and R is an alkyl radical of 1 to 4 carbon atoms.The initiators are prepared by reacting compounds of the formula: ##STR2## with an alkyl-lithium RLi in a non-polar solvent in the absence of any polar solvent or complexing agent.The initiators are used to prepare polydienes of high stereoregularity by reacting with a diene, and the polydiene is used to prepare a three-block or star copolymer by reacting with an anionically polymerizable monomer.

    摘要翻译： 新的有机锂引发剂，它们的合成及其用途。 引发剂具有以下分子式：其中R“为氢原子或甲基; n为1，在这种情况下R'= H，m和p为整数，其总和在0和10之间，或n为2，R'为2至8个碳原子的烷基，m = p = 0; 且R为1至4个碳原子的烷基。 在不存在任何极性溶剂或络合剂的情况下，通过使下式的化合物与下式的化合物反应来制备引发剂：在非极性溶剂中使下式的化合物与下式的烷基锂锂化合物反应。 引发剂用于通过与二烯反应制备高立构规整性的聚二烯，并且聚二烯用于通过与阴离子聚合单体反应制备三嵌段或星形共聚物。

    Cement for fixing a bone prosthesis
    8.
    发明授权
    Cement for fixing a bone prosthesis 失效
    用于固定骨假体的水泥

    公开(公告)号：US4782118A

    公开(公告)日：1988-11-01

    申请号：US876675

    申请日：1986-06-20

    申请人： Michel Fontanille ,  Myrna Timar

    发明人： Michel Fontanille ,  Myrna Timar

    IPC分类号： A61L33/00 ,  A61L24/00 ,  A61L24/06 ,  A61L26/00

    CPC分类号： A61L24/06

    摘要： A cement for fixing a bone prosthesis, the cement containing:(a) a solid phase comprising firstly polymethylmethacrylate and a copolymer of methyl methacrylate with an acrylate or a methacrylate of another alcohol, both in powder form, and secondly an organic peroxide suitable for generating free radicals; and(b) a liquid phase comprising methyl methacrylate and an accelerator for accelerating decomposition of the organic peroxide.The copolymer is an oligomer, and the liquid phase includes as the accelerator for accelerating decomposition of said organic peroxide an acrylate or a methacrylate carrying a tertiary amine function, and as a cross-linking agent a compound having at least two functions in its molecule suitable for reacting with the reactive functions carried by the polymers of the solid phase, or else a double bond and a function suitable for reacting with the reactive functions carried by the polymers of the solid phase.

    摘要翻译： 一种用于固定骨假体的水泥，所述水泥包含：（a）首先包含聚甲基丙烯酸甲酯和甲基丙烯酸甲酯与丙烯酸酯或另一种醇的甲基丙烯酸酯的共聚物的固相，其均为粉末形式，其次为适于产生的有机过氧化物 自由基; 和（b）包含甲基丙烯酸甲酯和促进有机过氧化物分解促进剂的液相。 共聚物是低聚物，液相包含作为促进有机过氧化物分解的促进剂，丙烯酸酯或甲基丙烯酸酯具有叔胺官能团，作为交联剂，分子中具有至少两个功能的化合物适合 用于与由固相聚合物所承载的反应性功能反应，或与双键和适于与固相聚合物所携带的反应性功能反应的功能反应。