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1.发明授权
公开(公告)号：US4950811A
公开(公告)日：1990-08-21
申请号：US388936
申请日：1989-08-03
IPC分类号： B01J27/18 , C07B61/00 , C07C27/00 , C07C29/09 , C07C29/124 , C07C31/38 , C07C31/40 , C07C67/00
CPC分类号： C07C29/124 , C07C31/40
摘要： A process for the preparation of trifluoroethanol by hydrolysis, in the gas phase, of chlorotrifluoroethane. A gaseous mixture of 1-chloro-2,2,2-trifluoroethane and water is contacted with a solid catalyst and taken to a temperature greater than 350.degree. C. and preferably between 400.degree. and 500.degree. C. 2,2,2-Trifluoroethanol (TFE) is a trifluorinated alcohol possessing very good thermal stability, which makes it suitable for a certain number of applications, in particular in the synthesis of fluorinated anesthetics, in pharmacology in general, and as a solvent.
摘要翻译： 一种通过在气相中水解氯三氟乙烷制备三氟乙醇的方法。 将1-氯-2,2,2-三氟乙烷和水的气体混合物与固体催化剂接触，并使其温度高于350℃，优选400至500℃。 三氟乙醇（TFE）是具有非常好的热稳定性的三氟化醇，其适用于一定数量的应用，特别是合成氟化麻醉剂，通常在药理学和溶剂中。
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2.发明授权Chemical compound containing alkali metals or alkaline earth metals, catalyst containing the compound and process for the production of the catalyst 失效包含碱金属或碱性金属的化学化合物，含有化合物的催化剂和催化剂生产方法
公开(公告)号：US5118651A
公开(公告)日：1992-06-02
申请号：US648621
申请日：1991-02-01
申请人： Michel Gubelmann , Philippe-Jean Tirel , Claude Doussain , Helene Pernot , Laurent Gilbert , Jean-Michel Popa
发明人： Michel Gubelmann , Philippe-Jean Tirel , Claude Doussain , Helene Pernot , Laurent Gilbert , Jean-Michel Popa
CPC分类号： C07C29/124 , B01J27/1804 , B01J27/1806
摘要： The invention relates to chemical compounds and their use as catalysts in the solvolysis of alkyl halides. The chemical compounds, when dry, have formula (I):(EO.sub.4 M).multidot.(Imp)p (I)wherein E is selected from the group consisting of phosphorus, arsenic, antimony and bismuth, and is preferably phosphorus, and M is a metal or a mixture of metals.Imp corresponds to a basic impregnating compound consisting of alkaline earth metal, or preferably alkali metal, and their mixtures in combination with a counter-anion to ensure electrical neutrality.The coefficient p is between 10.sup.-2 and 1/3.
摘要翻译： 本发明涉及化学化合物及其在烷基卤化物溶剂解中作为催化剂的用途。 化学化合物在干燥时具有式（I）：（EO4M）x（Imp）p（I）其中E选自磷，砷，锑和铋，优选为磷，M为 金属或金属的混合物。 Imp对应于由碱土金属或优选碱金属组成的基本浸渍化合物，以及它们与抗衡阴离子组合的混合物以确保电中性。 系数p在10-2和1/3之间。
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公开(公告)号：US5019657A
公开(公告)日：1991-05-28
申请号：US346529
申请日：1989-05-02
IPC分类号： B01J29/06 , B01J29/08 , B01J29/18 , B01J29/40 , C07B61/00 , C07C37/60 , C07C39/27 , C07C41/00 , C07C41/26 , C07C43/23 , C07C67/00
CPC分类号： C07C37/60 , B01J2229/37 , B01J29/08 , B01J29/18 , B01J29/40
摘要： A process for the preparation of halophenols. A halobenzene is brought into contact with nitrous oxide on an acidified zeolite.
摘要翻译： 一种制备卤代酚的方法。 在酸化的沸石上使卤代苯与一氧化二氮接触。
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公开(公告)号：US5132468A
公开(公告)日：1992-07-21
申请号：US643181
申请日：1991-01-18
IPC分类号： B01J21/06 , B01J21/10 , B01J23/10 , B01J23/26 , B01J29/08 , C07B61/00 , C07C37/16 , C07C37/20 , C07C39/08 , C07C41/18 , C07C43/23 , C07C43/253
CPC分类号： C07C37/115
摘要： The alkyl hydroquinones, e.g., methyl hydroquinone (a useful intermediate in the preparation of the monomer methyl hydroquinone diacetate, itself used for the synthesis of thermotropic polymers), are prepared by reacting (C-alkylating) hydroquinone or a monoether thereof with a lower alkanal, in the vapor phase, with a catalytically effective amount of at least one solid metal oxide.
摘要翻译： 烷基氢醌，例如甲基氢醌（制备单体甲基氢醌二乙酸酯，本身用于合成热致聚合物的有用中间体）通过（C-烷基化）氢醌或其单醚与低级链烷烃 在气相中，具有催化有效量的至少一种固体金属氧化物。
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公开(公告)号：US5001280A
公开(公告)日：1991-03-19
申请号：US346216
申请日：1989-05-02
摘要： Phenol is prepared by directly hydroxylating benzene with nitrous oxide, preferably in vapor phase, on a substrate of acidified zeolite particulates, advantageously ZSM-5 zeolite particulates, and such acidified zeolite particulates having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of greater than about 90, preferably up to 500.
摘要翻译： 苯酚通过在酸化的沸石颗粒的底物（有利地为ZSM-5沸石颗粒）的底物上直接羟基化，一氧化二氮，优选气相羟化，并且这种具有大于约90的摩尔比SiO 2 / Al 2 O 3的酸化的沸石颗粒，优选 最多500。
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公开(公告)号：US4982013A
公开(公告)日：1991-01-01
申请号：US346215
申请日：1989-05-02
CPC分类号： C07C37/60
摘要： Polyhydroxybenzenes, e.g., the dihydroxybenzenes, are prepared by directly hydroxylating a phenol with nitrous oxide, preferably in vapor phase, on a substrate of acidified zeolite particulates, advantageously ZSM-5 zeolite particulates, and such acidified zeolite particulates advantageously having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of greater than about 90, preferably up to 500.
摘要翻译： 多羟基苯，例如二羟基苯，通过在酸化的沸石颗粒（优选ZSM-5沸石颗粒）的底物上直接用一氧化二氮直接羟基化苯酚，优选气相制备，并且这种酸化的沸石微粒有利地具有SiO 2 / Al 2 O 3大于约90，优选至多500。
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公开(公告)号：US5288906A
公开(公告)日：1994-02-22
申请号：US24440
申请日：1993-03-01
IPC分类号： B01J31/02 , C07B61/00 , C07C213/00 , C07C213/02 , C07C215/76 , C07C209/36
CPC分类号： C07C213/00
摘要： Optionally substituted p-aminophenol compounds, easily converted into the N-acylated derivatives thereof, are prepared by hydrogenating the corresponding nitrobenzene, in solution in a saturated aliphatic monocarboxylic acid, notably acetic acid, in the presence of an effective amount of a protonic acid.
摘要翻译： 通过在有效量的质子酸存在下，在饱和脂肪族单羧酸（特别是乙酸）的溶液中氢化相应的硝基苯来制备易于转化为N-酰化衍生物的任选取代的对氨基苯酚化合物。
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公开(公告)号：US5003114A
公开(公告)日：1991-03-26
申请号：US362584
申请日：1989-06-07
IPC分类号： B01J29/04 , C07B61/00 , C07C37/60 , C07C39/08 , C07C41/00 , C07C41/26 , C07C43/23 , C07C43/295 , C07C67/00
摘要： Phenols/phenol ethers are hydroxylated by reaction with hydrogen peroxide in the presence of a catalytically effective amount of a calcined germanozeosilite MFI zeolite.
摘要翻译： 苯酚/酚醚通过与催化有效量的煅烧锗烷基硅沸石MFI沸石的存在下与过氧化氢反应而羟化。
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公开(公告)号：US5149888A
公开(公告)日：1992-09-22
申请号：US486429
申请日：1990-02-28
IPC分类号： B01J21/06 , C07B61/00 , C07C37/60 , C07C39/08 , C07C39/15 , C07C39/17 , C07C41/26 , C07C43/23 , C07C43/295
摘要： The phenols and phenol ethers, e.g., phenol itself, are effectively hydroxylated by reacting hydrogen peroxide therewith, in the presence of a catalytically effective amount of titanium dioxide.
摘要翻译： 在催化有效量的二氧化钛的存在下，苯酚和酚醚（例如苯酚本身）通过使过氧化氢与其反应而被有效羟化。
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10.发明授权Preparation of phenols by direct N.sub.2 O hydroxylation of aromatic substrates 失效通过芳香底物的直接N2O羟基化制备酚类
公开(公告)号：US5055623A
公开(公告)日：1991-10-08
申请号：US541956
申请日：1990-06-22
IPC分类号： B01J29/04 , B01J29/86 , B01J29/87 , B01J29/88 , C07B61/00 , C07C37/60 , C07C39/04 , C07C39/08 , C07C39/26 , C07C41/26
CPC分类号： C07C41/26 , B01J29/40 , B01J29/46 , B01J29/87 , B01J29/88 , C07C37/60 , B01J2229/183 , B01J29/86
摘要： Phenol/substituted phenols are prepared by directly hydroxylating an aromatic substrate with nitrous oxide, in vapor phase, in the presence of a modified (acidified) ZSM-5 or ZSM-11 zeolite, containing such elements as Ga, Fe, B, In, Cr, Sc, Co, Ni, Be, Zn, Cu, Sb, As or V.
摘要翻译： 苯酚/取代的酚通过在气相中，在含有诸如Ga，Fe，B，In等元素的改性（酸化的）ZSM-5或ZSM-11沸石的存在下，用一氧化二氮直接羟基化芳族底物来制备， Cr，Sc，Co，Ni，Be，Zn，Cu，Sb，As或V.
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