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公开(公告)号：US08262210B2
公开(公告)日：2012-09-11
申请号：US12569265
申请日：2009-09-29
CPC分类号： C09D11/101 , C09D11/34
摘要： This disclosure is generally directed to curable gel inks, such as radiation-curable phase-change inks, and their use in forming images, such as through inkjet printing. More specifically, this disclosure is directed to radiation-curable gel inks, such as ultraviolet-light-curable phase-change inks, that comprise a curable gellant and a curable solid.
摘要翻译： 本公开一般涉及可固化凝胶油墨，例如可辐射固化相变油墨，以及它们在形成图像时的用途，例如通过喷墨印刷。 更具体地，本公开涉及包含可固化胶凝剂和可固化固体的可辐射固化凝胶油墨，例如紫外光固化相变油墨。
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2.发明授权Ultra-violet curable gellant inks for tactile and regular print applications for signature and document authentication 有权用于触觉和常规打印应用程序的紫外线可固化胶凝胶，用于签名和文档认证公开(公告)号：US08758865B2
公开(公告)日：2014-06-24
申请号：US12204323
申请日：2008-09-04
IPC分类号： C08F2/48
CPC分类号： C08F2/48 , B41M3/16 , B41M7/0081 , C09D11/101 , C09D11/34 , Y10T428/24802
摘要： A system and method for creating an authentication mark on a recording medium by depositing marking material on a medium in an image area to create a marking material image and to create a marking material authentication image. The method comprises (a) depositing marking material directly onto a recording medium in an image area to create a marking material image and in an authentication image area to create a marking material authentication image, wherein the marking material is an ultraviolet curable phase change ink composition comprising an optional colorant and a phase change ink vehicle comprising a radiation curable monomer or prepolymer; a photoinitiator; a reactive wax; and a gellant; (b) depositing a predetermined amount of additional marking material upon the authentication image area to increase an amount of marking material associated with the marking material authentication image in the authentication image area; and (c) curing the marking material upon the recording medium such that the fixed marking material associated with the authentication image area is a tactilely perceptible authentication mark, the fixed marking material associated with the tactilely perceptible authentication mark having a first height, the first height being tactilely perceptible.
摘要翻译： 一种用于通过在图像区域中的介质上放置标记材料来在记录介质上创建认证标记以产生标记材料图像并创建标记材料认证图像的系统和方法。 该方法包括（a）将标记材料直接放置在图像区域中的记录介质上以产生标记材料图像，并在认证图像区域中形成标记材料认证图像，其中标记材料是紫外线固化相变油墨组合物 包括任选的着色剂和包含可辐射固化的单体或预聚物的相变油墨载体; 光引发剂; 活性蜡; 和胶凝剂; （b）在认证图像区域上放置预定量的附加标记材料以增加与认证图像区域中的标记材料认证图像相关联的标记材料的量; 和（c）在记录介质上固化标记材料，使得与认证图像区域相关联的固定标记材料是可触觉的认证标记，与可触觉认知标记相关联的固定标记材料具有第一高度，第一高度 触觉可见
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3.发明授权Gellant compositions with aromatic end-caps and oligomeric molecular weight distributions 有权具有芳香端帽和低分子量分布的胶凝剂组合物公开(公告)号：US08702221B2
公开(公告)日：2014-04-22
申请号：US13466488
申请日：2012-05-08
申请人： Naveen Chopra , Michelle N. Chretien , Barkev Keoshkerian , Daryl Vanbesien , Jenny Eliyahu , Jennifer L. Belelie , Peter Odell
发明人： Naveen Chopra , Michelle N. Chretien , Barkev Keoshkerian , Daryl Vanbesien , Jenny Eliyahu , Jennifer L. Belelie , Peter Odell
IPC分类号： B41J2/01
CPC分类号： C09D11/34 , C08G69/34 , C08G69/48 , C09D11/38 , C09D177/08
摘要： Disclosed herein are amide gellant compositions with aromatic end-caps consisting of a blend of oligomers (dimer, trimer, tetramer and pentamer) that may be optimized to stable gelling viscosity and controlled showthrough of printed inks.
摘要翻译： 本文公开了具有由低聚物（二聚体，三聚体，四聚体和五聚物）的共混物组成的芳族末端帽的酰胺胶凝剂组合物，其可以被优化以稳定的胶凝粘度和印刷油墨的受控显示。
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公开(公告)号：US08603612B2
公开(公告)日：2013-12-10
申请号：US12765309
申请日：2010-04-22
CPC分类号： C09D11/30 , B33Y10/00 , B33Y70/00 , C09D11/101 , C09D11/34 , Y10T428/24612 , Y10T428/24802
摘要： Curable, phase-change compositions and inks used for printing three-dimensional objects including a curable monomer, a photoinitiator, a wax and a gellant, where the composition of the cured formulation has a room temperature modulus of from about 0.01 to about 5 Gpa. The curable monomer includes acrylic monomer, polybutadiene adducted with maleic anhydride, aliphatic urethane acrylate, polyester acrylate, 3-acryloxypropyltrimethoxysilane, or acryloxypropyl t-structured siloxane.
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5.发明授权Curable solid inks for raised print applications and methods for using the same 有权用于凸版印刷应用的可固化固体油墨及其使用方法公开(公告)号：US08449102B2
公开(公告)日：2013-05-28
申请号：US12972138
申请日：2010-12-17
申请人： Marcel P. Breton , Michelle N. Chretien , Barkev Keoshkerian , Jennifer L. Belelie , Naveen Chopra
发明人： Marcel P. Breton , Michelle N. Chretien , Barkev Keoshkerian , Jennifer L. Belelie , Naveen Chopra
IPC分类号： B41J2/01
CPC分类号： C09D11/101 , B41J2/0057 , B41J3/32 , C09D11/34
摘要： Curable solid inks and low shrinkage curable solid inks which are solid at room temperature and molten at an elevated temperature at which the molten ink is applied to a substrate. In particular, the solid inks of the present embodiments retain the advantages of handling, safety, and print quality usually associated with conventional solid phase change inks but provide additional breakthrough performance characteristics such as enhanced robustness, lower jetting temperature, and ultra-low shrinkage upon crystallization, which allow the inks to be used as novel materials in inkjet-based Braille and raised print applications.
摘要翻译： 可固化的固体油墨和低收缩固化性固体油墨，其在室温下是固体，并在熔融油墨施加于基材的高温下熔融。 特别地，本实施例的固体油墨保持了通常与常规固相变油墨相关的处理，安全性和打印质量的优点，但提供了额外的突破性能特性，例如增强的鲁棒性，较低的喷射温度和超低的收缩率 结晶，其允许油墨用作基于喷墨的盲文和凸起印刷应用中的新型材料。
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公开(公告)号：US08403475B2
公开(公告)日：2013-03-26
申请号：US12946560
申请日：2010-11-15
IPC分类号： C09D11/00
CPC分类号： C09D17/00 , C08L53/00 , C09D7/45 , C09D11/101 , C09D11/322 , C09D11/34 , C09D153/00
摘要： A pigment dispersion includes a pigment and a dispersant, wherein an as formed curable phase change ink having the pigment dispersion added thereto, when filtered using a 1 micron filter at a temperature of 85° C., has a slope of ≧5 g/s and a T2/T1 of ≦1.6, wherein T2 represents a time to filter the last 25 g of a 100 g sample of the phase change ink through the 1 micron filter at 85° C., while T1 represents the time it takes to filter the first 25 g of the 100 g sample of the phase change ink through the 1 micron filter at 85° C.
摘要翻译： 颜料分散体包括颜料和分散剂，其中，当在85℃的温度下使用1微米过滤器过滤时，其中添加有颜料分散体的可形成的可固化相变油墨具有≥5g/ s的斜率 和T2 / T1为＆nlE; 1.6，其中T2表示通过1微米过滤器在85℃过滤最后25克相变油墨的100克样品的时间，而T1表示所需的时间 通过1微米过滤器在85℃过滤第一个25克相变油墨的100克样品。
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7.发明授权Phase change inks containing amide gellant compounds with aromatic end groups 有权含有芳族端基的酰胺胶凝剂化合物的相变油墨公开(公告)号：US08507584B2
公开(公告)日：2013-08-13
申请号：US12765138
申请日：2010-04-22
申请人： Naveen Chopra , Michelle N. Chretien , Barkev Keoshkerian , Jennifer L. Belelie , Peter G. Odell
发明人： Naveen Chopra , Michelle N. Chretien , Barkev Keoshkerian , Jennifer L. Belelie , Peter G. Odell
IPC分类号： B01F3/04 , B41J2/01 , B41J2/05 , B41J2/17 , B41J2/175 , C07D209/48 , C08F2/46 , C08G18/28 , C08G18/67 , C08J3/28 , C08K5/00 , C08K5/20 , C09D5/00 , C09D11/00 , G01D11/00
CPC分类号： B01F3/04 , B41M7/0072 , C09D11/101 , C09D11/34
摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising at least one radically curable monomer compound and a compound of the formula wherein R1 and R1′ are the same, and wherein R1 and R1′ are each an aromatic group; and wherein R2 and R2′ and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups; or wherein, in embodiments, R1 and R1′ can be the same or different, and wherein R1 and R1′ each, independently of the other is an alkyl group having a least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, an alkylaryl group having at least one ethylenic unsaturation, or an aromatic group, provided that at least one of R1 and R1′ is an aromatic group; and provided that neither of R1 or R1′ is a photoinitiator group. Also disclosed herein is a method of printing with the phase change ink.
摘要翻译： 公开了一种相变油墨，其包含着色剂，引发剂和相变油墨载体，所述载体包含至少一种可自由基固化的单体化合物和下式化合物其中R1和R1'相同，并且其中R1和R1 “都是芳香族群; 并且其中R2和R2'和R3各自独立地是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基; 或其中，在实施方案中，R 1和R''可以相同或不同，并且其中R 1和R 1'各自独立地是具有至少一个烯属不饱和度的烷基，具有至少一个烯属不饱和度的芳基烷基， 具有至少一个烯属不饱和基团的烷基芳基或芳族基团，条件是R 1和R 1'中的至少一个为芳族基团; 并且条件是R1或R1'都不是光引发剂基团。 本文还公开了用相变油墨进行印刷的方法。
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8.发明授权Urea-urethane gellant compositions with controlled molecular weight and methods of preparation 有权具有受控分子量的尿素 - 聚氨酯胶凝剂组合物和制备方法公开(公告)号：US08450385B2
公开(公告)日：2013-05-28
申请号：US12974083
申请日：2010-12-21
IPC分类号： C09D11/10
CPC分类号： C09D11/10 , C07C275/14 , C09D11/101
摘要： Urea-urethane gellant compositions and methods of preparing the urea-urethane gellant compositions. The method includes adding an isocyanate, an alcohol or a diamine, and a solvent to a reaction vessel; stirring the reaction vessel at either ambient or elevated temperature; isolating an intermediate product from the reaction vessel; and converting the intermediate product to the organic gellant. The urea-urethane gellants are prepared in a manner to control the molecular weight and control the formation of dimers and trimers. The gellants may be used in curable gel inks.
摘要翻译： 脲 - 聚氨酯胶凝剂组合物和制备尿素 - 聚氨酯胶凝剂组合物的方法。 该方法包括向反应容器中加入异氰酸酯，醇或二胺和溶剂; 在环境温度或升高的温度下搅拌反应容器; 从反应容器中分离中间产物; 并将中间产物转化为有机胶凝剂。 尿素 - 聚氨酯胶凝剂以控制分子量并控制二聚体和三聚体的形成的方式制备。 胶凝剂可用于可固化凝胶油墨中。
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公开(公告)号：US08308286B2
公开(公告)日：2012-11-13
申请号：US12881921
申请日：2010-09-14
IPC分类号： B41J2/01 , B41J2/175 , B41M5/00 , C08F220/56
CPC分类号： C09D11/34 , C09D11/101
摘要： A phase change ink includes an ink vehicle that includes at least one curable carrier, at least one gellant, at least one wax and at least one alkoxysilane monomer. In a method of forming an image with the ink, the phase change ink is melted, then jetted onto an image receiving substrate, wherein the phase change ink forms a gel state, and exposed to ultraviolet light to cure the curable components of the phase change ink. The alkoxysilane participates in crosslinking to form silicon-oxygen-silicon bonds, thereby producing an ink with advantageous stability and high image quality.
摘要翻译： 相变油墨包括油墨载体，其包含至少一种可固化载体，至少一种胶凝剂，至少一种蜡和至少一种烷氧基硅烷单体。 在用油墨形成图像的方法中，相变油墨熔化，然后喷射到图像接收基板上，其中相变油墨形成凝胶状态，并暴露于紫外光以固化相变的可固化组分 墨水。 烷氧基硅烷参与交联以形成硅 - 氧 - 硅键，从而产生具有有利的稳定性和高图像质量的油墨。
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10.发明申请CURABLE SOLID INKS FOR RAISED PRINT APPLICATIONS AND METHODS FOR USING THE SAME 有权用于提高打印应用的可固化固体油墨及其使用方法公开(公告)号：US20120154496A1
公开(公告)日：2012-06-21
申请号：US12972138
申请日：2010-12-17
申请人： Marcel P. Breton , Michelle N. Chretien , Barkev Keoshkerian , Jennifer L. Belelie , Naveen Chopra
发明人： Marcel P. Breton , Michelle N. Chretien , Barkev Keoshkerian , Jennifer L. Belelie , Naveen Chopra
CPC分类号： C09D11/101 , B41J2/0057 , B41J3/32 , C09D11/34
摘要： Curable solid inks and low shrinkage curable solid inks which are solid at room temperature and molten at an elevated temperature at which the molten ink is applied to a substrate. In particular, the solid inks of the present embodiments retain the advantages of handling, safety, and print quality usually associated with conventional solid phase change inks but provide additional breakthrough performance characteristics such as enhanced robustness, lower jetting temperature, and ultra-low shrinkage upon crystallization, which allow the inks to be used as novel materials in inkjet-based Braille and raised print applications.
摘要翻译： 可固化的固体油墨和低收缩固化性固体油墨，其在室温下是固体，并在熔融油墨施加于基材的高温下熔融。 特别地，本实施例的固体油墨保持了通常与常规固相变油墨相关的处理，安全性和打印质量的优点，但提供了额外的突破性能特性，例如增强的鲁棒性，较低的喷射温度和超低的收缩率 结晶，其允许油墨用作基于喷墨的盲文和凸起印刷应用中的新型材料。
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