摘要:
A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided. The sealing material for optical elements comprising a compound with a ladder structure, which contains a repeating unit of the following formula (A) in the molecule as a major component, the compound being obtained by condensing a compound (1) shown by the formula, R1Si(OR3)P(X1)3-p, and a compound (2) shown by the formula, R2Si(OR4)q(X2)3-q, at a molar ratio of 1:9 to 10:0 in the presence of a phosphoric acid catalyst, wherein R1 represents a group having a reactive functional group, R2 represents an alkyl group having 1 to 20 carbon atoms, R3 and R4 individually represents an alkyl group having 1 to 6 carbon atoms, X1 and X2 individually indicate a halogen atom, p and q individually represent an integer from 0 to 3, and l, m, and n individually represent 0 or an arbitrary integer, provided that l and n are not 0 at the same time.
摘要:
A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided. The sealing material for optical elements comprising a compound with a ladder structure, which contains a repeating unit of the following formula (A) in the molecule as a major component, the compound being obtained by condensing a compound (1) shown by the formula, R1Si(OR3)P(X1)3-p, and a compound (2) shown by the formula, R2Si(OR4)q(X2)3-q, at a molar ratio of 1:9 to 10:0 in the presence of a phosphoric acid catalyst, wherein R1 represents a group having a reactive functional group, R2 represents an alkyl group having 1 to 20 carbon atoms, R3 and R4 individually represents an alkyl group having 1 to 6 carbon atoms, X1 and X2 individually indicate a halogen atom, p and q individually represent an integer from 0 to 3, and l, m, and n individually represent 0 or an arbitrary integer, provided that l and n are not 0 at the same time.
摘要:
An adhesive containing a ladder-type polysilsesquioxane which firmly bonds metals and synthetic resins and an adhesive sheet having an adhesive layer formed by using the adhesive on at least one side of a substrate are provided. An adhesive comprises a ladder-type polysilsesquioxane having a recurring unit of the following formula (I) in the molecule, wherein R1 represents a polymerizable functional group, and R2 represents the same group as R1, an alkyl group having 1 to 6 carbon atoms which may have a substituent, an alkoxy group having 1 to 6 carbon atoms which may have a substituent, or a phenyl group which may have a substituent, and the adhesive sheet has an adhesive layer formed by using the adhesive on at least one side of the substrate.
摘要:
An adhesive containing a ladder-type polysilsesquioxane which firmly bonds metals and synthetic resins and an adhesive sheet having an adhesive layer formed by using the adhesive on at least one side of a substrate are provided. An adhesive comprises a ladder-type polysilsesquioxane having a recurring unit of the following formula (I) in the molecule, wherein R1 represents a polymerizable functional group, and R2 represents the same group as R1, an alkyl group having 1 to 6 carbon atoms which may have a substituent, an alkoxy group having 1 to 6 carbon atoms which may have a substituent, or a phenyl group which may have a substituent, and the adhesive sheet has an adhesive layer formed by using the adhesive on at least one side of the substrate.
摘要:
A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided. The sealing material for optical elements comprising a compound with a ladder structure, which contains a repeating unit of the following formula (A) in the molecule as a major component, the compound being obtained by condensing a compound (1) shown by the formula, R1Si(OR3)P(X1)3-p, and a compound (2) shown by the formula, R2Si(OR4)q(X2)3-q, at a molar ratio of 1:9 to 10:0 in the presence of a phosphoric acid catalyst, wherein R1 represents a group having a reactive functional group, R2 represents an alkyl group having 1 to 20 carbon atoms, R3 and R4 individually represents an alkyl group having 1 to 6 carbon atoms, X1 and X2 individually indicate a halogen atom, p and q individually represent an integer from 0 to 3, and l, m, and n individually represent 0 or an arbitrary integer, provided that l and n are not 0 at the same time.
摘要:
A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided. The sealing material for optical elements comprising a compound with a ladder structure, which contains a repeating unit of the following formula (A) in the molecule as a major component, the compound being obtained by condensing a compound (1) shown by the formula, R1Si(OR3)P(X1)3-p, and a compound (2) shown by the formula, R2Si(OR4)q(X2)3-q, at a molar ratio of 1:9 to 10:0 in the presence of a phosphoric acid catalyst, wherein R1 represents a group having a reactive functional group, R2 represents an alkyl group having 1 to 20 carbon atoms, R3 and R4 individually represents an alkyl group having 1 to 6 carbon atoms, X1 and X2 individually indicate a halogen atom, p and q individually represent an integer from 0 to 3, and l, m, and n individually represent 0 or an arbitrary integer, provided that l and n are not 0 at the same time.
摘要:
The present invention provides a process for producing a polysilsesquioxane graft polymer (1) which includes applying ionizing radiation or heat to a mixture including a polysilsesquioxane compound (2) and a vinyl compound (3), a polysilsesquioxane compound including an iniferter group, and a pressure-sensitive adhesive and a pressure-sensitive adhesive sheet using the polymer. According to the present invention, a process for producing a polysilsesquioxane graft polymer which may be used as a pressure-sensitive adhesive exhibiting excellent heat resistance and cohesive force, and the like are provided. In the formula, A represents a linking group, R1 represents a hydrocarbon group which may have a substituent, R2 represents a hydrogen atom or the like, R3 represents a polar group or the like, R4 represents a hydrogen atom or the like, k1 to k3 represent arbitrary positive integers, 1 to n represent zero or an arbitrary positive integer (excluding the case where “m=n=0”), and Q represents an iniferter group.
摘要:
The present invention provides a process for producing a polysilsesquioxane graft polymer (1) which includes applying ionizing radiation or heat to a mixture including a polysilsesquioxane compound (2) and a vinyl compound (3), a polysilsesquioxane compound including an iniferter group, and a pressure-sensitive adhesive and a pressure-sensitive adhesive sheet using the polymer. According to the present invention, a process for producing a polysilsesquioxane graft polymer which may be used as a pressure-sensitive adhesive exhibiting excellent heat resistance and cohesive force, and the like are provided. In the formula, A represents a linking group, R1 represents a hydrocarbon group which may have a substituent, R2 represents a hydrogen atom or the like, R3 represents a polar group or the like, R4 represents a hydrogen atom or the like, k1 to k3 represent arbitrary positive integers, 1 to n represent zero or an arbitrary positive integer (excluding the case where “m=n=0”), and Q represents an iniferter group.
摘要:
There are disclosed a silicate-containing sheet which comprises a silicate of one metal or at least two composite metals, which metal and metals are selected from the group consisting of the groups 4 to 13 series 4-metals of the periodic table, the groups 4 to 15 series 5-metals of the periodic table, and the lanthanoids series metals, and are preferably selected from the group consisting of Ti, Fe, Co, Ni, Cu, Zn, Ga, Zr, Ag, In, Sn, Sb and Ce ; and further a label comprising the above silicate-containing sheet. The silicate-containing sheet mentioned above can afford a functional sheet which has catalytic actions such as ultraviolet rays-attenuating properties, antimicrobial properties and antifouling properties at a low manufacturing cost.
摘要翻译:公开了一种含硅酸盐的片材,其包含一种金属或至少两种复合金属的硅酸盐,该金属和金属选自周期表第4至13族4族金属,第4族 优选选自Ti,Fe,Co,Ni,Cu,Zn,Ga,Zr,Ag,In,Sn,Sb和...中的15种5族元素周期表的5族金属和镧系金属, Ce 以及另外包含上述含硅酸盐的片材的标签。 上述含硅酸盐的片材能够以低制造成本提供具有紫外线衰减特性,抗菌性和防污性等催化作用的功能性片材。
摘要:
There are disclosed a silicate-containing sheet which comprises a silicate of one metal or at least two composite metals, which metal and metals are selected from the group consisting of the groups 4 to 13 series 4-metals of the periodic table, the groups 4 to 15 series 5-metals of the periodic table, and the lanthanoids series metals, and are preferably selected from the group consisting of Ti, Fe, Co, Ni, Cu, Zn, Ga, Zr, Ag, In, Sn, Sb and Ce; and further a label comprising the above silicate-containing sheet. The silicate-containing sheet mentioned above can afford a functional sheet which has catalytic actions such as ultraviolet rays-attenuating properties, antimicrobial properties and antifouling properties at a low manufacturing cost.
摘要翻译:公开了一种含硅酸盐的片材,其包含一种金属或至少两种复合金属的硅酸盐,该金属和金属选自周期表第4至13族4族金属,第4族 优选选自Ti,Fe,Co,Ni,Cu,Zn,Ga,Zr,Ag,In,Sn,Sb和...中的15种5族元素周期表的5族金属和镧系金属, Ce 以及另外包含上述含硅酸盐的片材的标签。 上述含硅酸盐的片材能够以低制造成本提供具有紫外线衰减特性,抗菌性和防污性等催化作用的功能性片材。