公开(公告)号：US07317072B2

公开(公告)日：2008-01-08

申请号：US10530027

申请日：2003-10-02

申请人： Minoru Senga ,  Koichi Suga ,  Tomio Ohno

发明人： Minoru Senga ,  Koichi Suga ,  Tomio Ohno

IPC分类号： C08F6/00

CPC分类号： C08F228/04 ,  C08G75/0213 ,  C08G75/0254 ,  C08G75/0277 ,  C08G75/0281

摘要： The present invention is a process for the production of polyarylene sulfide based resin, wherein in washing a polyarylene sulfide based resin with a mixed solvent of an aprotic organic solvent and water in a softened or molten state, the polyarylene sulfide based resin partially dissolved in the washing liquid is recovered, to be specific, the polyarylene sulfide based resin dissolved in the washing liquid is precipitated, separated and recovered by cooling the washing liquid after washing and/or adding water to the washing liquid, and it is reused. According to the present invention, capable of being provided is a process for the production of polyarylene sulfide based resin in which the polyarylene sulfide based resin formed by polymerization is scarcely lost in washing the above resin with a solvent.

摘要翻译： 本发明是一种聚芳硫醚系树脂的制造方法，其中，在软化或熔融状态下用非质子性有机溶剂和水的混合溶剂洗涤聚芳硫醚系树脂时，聚芳硫醚系树脂部分溶解于 特别地回收洗涤液，溶解在洗涤液中的聚芳硫醚系树脂通过在洗涤和/或向洗涤液中添加水后冷却洗涤液而分离和回收，并重复使用。 根据本发明，能够提供一种制备聚芳硫醚类树脂的方法，其中通过聚合形成的聚芳硫醚基树脂在用溶剂洗涤上述树脂时几乎不失去。

公开(公告)号：US20060128819A1

公开(公告)日：2006-06-15

申请号：US10530027

申请日：2003-10-02

申请人： Minoru Senga ,  Koichi Suga ,  Tomio Ohno

发明人： Minoru Senga ,  Koichi Suga ,  Tomio Ohno

IPC分类号： C08J11/04

CPC分类号： C08F228/04 ,  C08G75/0213 ,  C08G75/0254 ,  C08G75/0277 ,  C08G75/0281

摘要： The present invention is a process for the production of polyarylene sulfide based resin, wherein in washing a polyarylene sulfide based resin with a mixed solvent of an aprotic organic solvent and water in a softened or molten state, the polyarylene sulfide based resin partially dissolved in the washing liquid is recovered, to be specific, the polyarylene sulfide based resin dissolved in the washing liquid is precipitated, separated and recovered by cooling the washing liquid after washing and/or adding water to the washing liquid, and it is reused. According to the present invention, capable of being provided is a process for the production of polyarylene sulfide based resin in which the polyarylene sulfide based resin formed by polymerization is scarcely lost in washing the above resin with a solvent.

摘要翻译： 本发明是一种聚芳硫醚系树脂的制造方法，其中，在软化或熔融状态下用非质子性有机溶剂和水的混合溶剂洗涤聚芳硫醚系树脂时，聚芳硫醚系树脂部分溶解于 特别地回收洗涤液，溶解在洗涤液中的聚芳硫醚系树脂通过在洗涤和/或向洗涤液中添加水后冷却洗涤液而分离和回收，并重新使用。 根据本发明，能够提供一种制备聚芳硫醚类树脂的方法，其中通过聚合形成的聚芳硫醚基树脂在用溶剂洗涤上述树脂时几乎不失去。

公开(公告)号：US06316536B1

公开(公告)日：2001-11-13

申请号：US09306050

申请日：1999-05-06

申请人： Masaya Okamoto ,  Minoru Senga ,  Koichi Suga ,  Kenji Seki

发明人： Masaya Okamoto ,  Minoru Senga ,  Koichi Suga ,  Kenji Seki

IPC分类号： C08J510

CPC分类号： C08L65/02 ,  C08G65/2612 ,  C08G2261/312 ,  C08K3/01 ,  C08K7/14 ,  C08L81/02

摘要： Provided is a polyarylene sulfide resin composition of which the moldings are burred little and which has good mechanical properties and good flow moldability. The composition comprises from 20 to 90% by weight of a polyarylene sulfide and from 10 to 80% by weight of an inorganic filler, and is characterized in that its burrs are on the level of at most 120 &mgr;m, that it has a weld strength of at least 50 MPa and that the length of its spiral flow having a thickness of 1 mm is at least 100 mm. Preferably, the polyarylene sulfide to be in the composition has a specific index to the degree of branching and a specific flexural strength.

摘要翻译： 本发明提供一种聚酰亚胺硫化物树脂组合物，其模制品几乎没有被磨损，并且具有良好的机械性能和良好的流动成型性。 该组合物包含20至90重量％的聚芳硫醚和10至80重量％的无机填料，其特征在于其毛刺的水平至多为120微米，其焊接强度 至少50MPa，并且其具有1mm厚度的螺旋流的长度为至少100mm。 优选地，组合物中的聚芳硫醚具有对支化度的特定指标和特定的弯曲强度。

公开(公告)号：US09051201B2

公开(公告)日：2015-06-09

申请号：US13260054

申请日：2010-04-07

申请人： Ryo Aburatani ,  Minoru Senga ,  Tsuyoshi Ota ,  Masaru Nakagawa

发明人： Ryo Aburatani ,  Minoru Senga ,  Tsuyoshi Ota ,  Masaru Nakagawa

IPC分类号： H01M10/0562 ,  C03B19/12 ,  H01B1/12 ,  H01M4/13 ,  H01M4/62 ,  H01M10/052

CPC分类号： H01M10/0562 ,  C03B19/12 ,  C03B2201/86 ,  C03C1/02 ,  C03C3/321 ,  C03C4/18 ,  C03C10/00 ,  C03C12/00 ,  H01B1/122 ,  H01M4/13 ,  H01M4/62 ,  H01M10/052 ,  H01M2300/0068 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Glass includes an aggregate of solid electrolyte particles including Li, P, and S, wherein when a Raman spectrum of the glass is repeatedly measured and a peak at 330 to 450 cm−1 in each Raman spectrum is separated to waveforms of individual components, a standard deviation of a waveform area ratio of each component is less than 4.0.

摘要翻译： 玻璃包括包含Li，P和S的固体电解质颗粒的聚集体，其中当重复测量玻璃的拉曼光谱并且在每个拉曼光谱中在330至450cm -1处的峰分离成各个组分的波形时， 各部件的波形面积比的标准偏差小于4.0。

公开(公告)号：US20130295464A1

公开(公告)日：2013-11-07

申请号：US13981024

申请日：2012-01-25

申请人： Kazuaki Yanagi ,  Minoru Senga ,  Ryo Aburatani ,  Tsuyoshi Ota

发明人： Kazuaki Yanagi ,  Minoru Senga ,  Ryo Aburatani ,  Tsuyoshi Ota

IPC分类号： H01M4/136

CPC分类号： H01M4/136 ,  C01B17/22 ,  C01P2002/72 ,  C01P2002/85 ,  C01P2004/04 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  H01M4/0497 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5815 ,  H01M4/624 ,  H01M4/625 ,  H01M4/626 ,  H01M10/0525

摘要： A composite material including a conducting material and an alkali metal sulfide formed integrally on the surface of the conducting material.

摘要翻译： 一种复合材料，包括导电材料和一种碱金属硫化物，其一体地形成在导电材料的表面上。

公开(公告)号：US07026439B2

公开(公告)日：2006-04-11

申请号：US10473366

申请日：2002-03-15

申请人： Minoru Senga ,  Masaya Okamoto ,  Mikiya Hayashi

发明人： Minoru Senga ,  Masaya Okamoto ,  Mikiya Hayashi

IPC分类号： C08G75/00 ,  C08G75/14 ,  C08G75/18

CPC分类号： C08G75/025

摘要： There is disclosed a process for continuously producing a polyarylene sulfide which comprises reacting a sulfur source with a dihalogenated aromatic compound in an aprotic organic solvent, characterized by maintaining the content of the dihalogenated aromatic compound in the polymerization liquid after the substantial completion of the polymerization reaction at 5 mg/g or higher. It is made possible by the process according to the present invention to efficiently produce the polyarylene sulfide which has a high molecular weight and is excellent in thermal stability.

摘要翻译： 公开了一种连续生产聚芳硫醚的方法，其包括在非质子有机溶剂中使硫源与二卤代芳族化合物反应，其特征在于在聚合反应基本上完成后维持聚合液中的二卤代芳族化合物的含量 在5mg / g以上。 通过本发明的方法可以有效地制备分子量高且热稳定性优异的聚芳硫醚。

公开(公告)号：US20050118093A1

公开(公告)日：2005-06-02

申请号：US10498895

申请日：2002-12-17

申请人： Minoru Senga ,  Junji Matsui ,  Hideaki Kakimoto

发明人： Minoru Senga ,  Junji Matsui ,  Hideaki Kakimoto

IPC分类号： C01B17/22 ,  C08G75/02

CPC分类号： C08G75/0204 ,  C01B17/22 ,  C01P2006/80 ,  C08G75/0254

摘要： A method for reproducing lithium sulfide, including the steps of reacting lithium halide generated as a byproduct during the production of a polyarylene sulfide by a reaction between lithium sulfide and a halogenated aromatic compound with sodium carbonate to generate lithium sulfide, isolating the lithium carbonate and reacting the lithium carbonate with a sulfur compound to generate the lithium sulfide. According to the above method, lithium sulfide having a less Na content can be reproduced from lithium halide generated as a byproduct during the production of a polyarylene sulfide.

摘要翻译： 一种再生硫化锂的方法，包括以下步骤：在硫化亚铜与卤代芳族化合物与碳酸钠反应生成聚芳硫醚期间作为副产物生成的卤化锂，生成硫化锂，分离碳酸锂并反应 碳酸锂与硫化合物一起生成硫化锂。 根据上述方法，可以在生产聚芳硫醚期间作为副产物产生的卤化锂再现具有较少Na含量的硫化锂。

公开(公告)号：US09196925B2

公开(公告)日：2015-11-24

申请号：US14345809

申请日：2012-09-20

申请人： Ryo Aburatani ,  Minoru Senga ,  Tadanori Junke ,  Masao Aida

发明人： Ryo Aburatani ,  Minoru Senga ,  Tadanori Junke ,  Masao Aida

IPC分类号： C03C12/00 ,  H01M10/0562 ,  H01M10/0525 ,  C03C4/18 ,  C03C3/32 ,  H01B1/10 ,  C03C1/02 ,  C03C10/00 ,  C01B17/22 ,  C01B17/36

CPC分类号： H01M10/0562 ,  C01B17/22 ,  C01B17/36 ,  C01B25/14 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/80 ,  C03C1/02 ,  C03C3/321 ,  C03C4/18 ,  C03C10/00 ,  C03C12/00 ,  H01B1/10 ,  H01M10/0525 ,  H01M2300/0068

摘要： Glass particles including Li, P and S, wherein when a Raman spectrum of the glass particles is measured five times or more and a peak at 330 to 450 cm−1 in the Raman spectrum is separated into peaks of components by waveform separation, the standard deviation of the area ratio of each of the peaks of the components is 3.0 or less, the area of the peak of PS43− component obtained by the waveform separation is 10 to 95% of the total area, and the area of P2S74− component obtained by the waveform separation is 5 to 45% of the total area, and the area of the peak of PS43− component is larger than the area of the peak of P2S74− component.

摘要翻译： 包括Li，P和S的玻璃颗粒，其中当拉曼光谱中的玻璃颗粒的拉曼光谱测量为五次以上且在330〜450cm -1处的峰值通过波形分离被分离成分量的峰值时，标准 各部分的峰面积比的偏差为3.0以下，通过波形分离获得的PS43成分的峰面积为总面积的10〜95％，得到的P2S74-成分的面积 通过波形分离占总面积的5〜45％，PS43-成分的峰面积大于P2S74-组分峰的面积。

公开(公告)号：US08012631B2

公开(公告)日：2011-09-06

申请号：US12096481

申请日：2006-11-28

申请人： Yoshikatsu Seino ,  Masaru Nakagawa ,  Minoru Senga ,  Masatoshi Shibata

发明人： Yoshikatsu Seino ,  Masaru Nakagawa ,  Minoru Senga ,  Masatoshi Shibata

IPC分类号： H01M6/18 ,  H01M4/13 ,  B05D5/12 ,  B05D3/00 ,  B05D3/04 ,  B05D3/10

CPC分类号： H01B1/122 ,  C03C3/321 ,  C03C4/18 ,  C03C10/00 ,  H01M10/052 ,  H01M10/0562 ,  H01M2300/0068 ,  Y02T10/7011

摘要： A solid electrolyte including a lithium (Li) element, a phosphorus (P) element and a sulfur (S) element, the 31P MAS NMR spectrum thereof having a peak ascribed to a crystal at 90.9±0.4 ppm and 86.5±0.4 ppm; and the ratio (xc) of the crystal in the solid electrolyte being from 60 mol % to 100 mol %.

摘要翻译： 包含锂（Li）元素，磷（P）元素和硫（S））元素的固体电解质，具有归属于90.9±0.4ppm和86.5±0.4ppm的晶体的峰的31P MAS NMR光谱; 固体电解质中的结晶比例（xc）为60〜100摩尔％。

公开(公告)号：US20090159839A1

公开(公告)日：2009-06-25

申请号：US12096481

申请日：2006-11-28

申请人： Yoshikatsu Seino ,  Masaru Nakagawa ,  Minoru Senga ,  Masatoshi Shibata

发明人： Yoshikatsu Seino ,  Masaru Nakagawa ,  Minoru Senga ,  Masatoshi Shibata

IPC分类号： H01M4/90

CPC分类号： H01B1/122 ,  C03C3/321 ,  C03C4/18 ,  C03C10/00 ,  H01M10/052 ,  H01M10/0562 ,  H01M2300/0068 ,  Y02T10/7011

摘要： A solid electrolyte including a lithium (Li) element, a phosphorus (P) element and a sulfur (S) element, the 31P MAS NMR spectrum thereof having a peak ascribed to a crystal at 90.9±0.4 ppm and 86.5±0.4 ppm; and the ratio (xc) of the crystal in the solid electrolyte being from 60 mol % to 100 mol %.

摘要翻译： 包含锂（Li）元素，磷（P）元素和硫（S））元素的固体电解质，具有归属于90.9±0.4ppm和86.5±0.4ppm的晶体的峰的31P MAS NMR光谱; 固体电解质中的结晶比例（xc）为60〜100摩尔％。