公开(公告)号：US09035055B2

公开(公告)日：2015-05-19

申请号：US12877264

申请日：2010-09-08

申请人： Mitsumasa Hamano ,  Katsuyuki Yofu ,  Tetsuro Mitsui ,  Kimiatsu Nomura

发明人： Mitsumasa Hamano ,  Katsuyuki Yofu ,  Tetsuro Mitsui ,  Kimiatsu Nomura

IPC分类号： C07D221/22 ,  C07C223/06 ,  C07C225/22 ,  C07D209/86 ,  C07D213/74 ,  C07D219/02 ,  C07D221/18 ,  C07D223/14 ,  C07D239/62 ,  C07D239/66 ,  C07D307/66 ,  C07D333/36 ,  C07D495/04 ,  H01L27/30 ,  H01L51/00 ,  H01L51/42 ,  C09B23/04 ,  C09B57/00

CPC分类号： C07C223/06 ,  C07C225/22 ,  C07C2102/08 ,  C07C2103/14 ,  C07C2103/18 ,  C07C2103/24 ,  C07C2103/26 ,  C07C2103/50 ,  C07C2602/08 ,  C07C2603/14 ,  C07C2603/18 ,  C07C2603/24 ,  C07C2603/26 ,  C07C2603/50 ,  C07D209/86 ,  C07D213/74 ,  C07D219/02 ,  C07D221/18 ,  C07D223/14 ,  C07D239/62 ,  C07D239/66 ,  C07D307/66 ,  C07D333/36 ,  C07D495/04 ,  C09B23/04 ,  C09B57/008 ,  H01L27/307 ,  H01L51/006 ,  H01L51/4253 ,  Y02E10/549

摘要： An organic compound and a photoelectric conversion device containing the organic compound are disclosed. The organic compound and device realize high photoelectric conversion efficiency, low dark current and high-speed responsivity. It has been found that when this organic compound and an n-type semiconductor are used in combination, high-speed responsivity can be realized while maintaining high heat resistance, an aspect of which has not been seen when the connection part between a donor part and an acceptor part is a phenylene group.

摘要翻译： 公开了含有有机化合物的有机化合物和光电转换装置。 有机化合物和器件实现高光电转换效率，低暗电流和高速响应。 已经发现，当组合使用该有机化合物和n型半导体时，可以在保持高耐热性的同时实现高速响应性，当施主部分和供体部分之间的连接部分 受体部分是亚苯基。

公开(公告)号：US08525577B2

公开(公告)日：2013-09-03

申请号：US12891897

申请日：2010-09-28

申请人： Katsuyuki Yofu ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Tetsuro Mitsui

发明人： Katsuyuki Yofu ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Tetsuro Mitsui

IPC分类号： H01L31/00 ,  H01L29/08 ,  H01L35/24 ,  H01L51/00 ,  C07D209/82 ,  C07D495/02

CPC分类号： H01L51/42 ,  B82Y10/00 ,  C07D333/36 ,  C07D333/56 ,  C07D333/72 ,  C07D409/04 ,  C07D409/06 ,  C07D409/12 ,  C07D495/04 ,  C07D495/14 ,  C09B3/00 ,  C09B23/105 ,  C09B57/008 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/4253 ,  Y02E10/549

摘要： A photoelectric conversion device comprising an electrically conductive film, an organic photoelectric conversion film, and a transparent electrically conductive film, wherein the organic photoelectric conversion film contains a compound represented by the following formula (1) and an n-type organic semiconductor: wherein each of R1 and R2 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, each of R3 to R11 independently represents a hydrogen atom or a substituent provided that an acidic group is excluded, m represents 0 or 1, n represents an integer of 0 or more, R1 and R2, R3 and R4, R3 and R5, R5 and R6, R6 and R8, R7 and R8, R7 and R9, or R10 and R11 may be combined each other to form a ring, and when n is an integer of 2 or more, out of a plurality of R7's and R8's, a pair of R7's, a pair of R8's, or a pair of R7 and R8 may be combined each other to form a ring.

公开(公告)号：US08338691B2

公开(公告)日：2012-12-25

申请号：US12399417

申请日：2009-03-06

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

IPC分类号： H01L31/00 ,  H01L31/042

CPC分类号： H01L51/0032 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0047 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/424 ,  H01L51/4253

摘要： A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer; and a transparent electrically conductive thin layer. The organic photoelectric conversion layer contains: a compound represented by formula (I); and a fullerene or a fullerene derivative. In the formula, Z1 represents an atomic group necessary for forming a 5- or 6-membered ring, L1, L2 and L3 each independently represents an unsubstituted methine group or a substituted methine group, D1 represents an atomic group, and n represents an integer of 0 or more.

摘要翻译： 提供了一种光电转换元件，包括：导电薄层; 有机光电转换层; 和透明导电薄层。 有机光电转换层包含：式（I）表示的化合物; 和富勒烯或富勒烯衍生物。 在该式中，Z1表示形成5元或6元环所必需的原子团，L1，L2和L3各自独立地表示未取代的次甲基或取代的次甲基，D1表示原子团，n表示整数 为0以上。

公开(公告)号：US20090223566A1

公开(公告)日：2009-09-10

申请号：US12399417

申请日：2009-03-06

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano ,  Katsuyuki Yofu

IPC分类号： H01L31/00

CPC分类号： H01L51/0032 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0047 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/424 ,  H01L51/4253

摘要： A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer; and a transparent electrically conductive thin layer. The organic photoelectric conversion layer contains: a compound represented by formula (I); and a fullerene or a fullerene derivative. In the formula, Z1 represents an atomic group necessary for forming a 5- or 6-membered ring, L1, L2 and L3 each independently represents an unsubstituted methine group or a substituted methine group, D1 represents an atomic group, and n represents an integer of 0 or more.

摘要翻译： 提供了一种光电转换元件，包括：导电薄层; 有机光电转换层; 和透明导电薄层。 有机光电转换层包含：式（I）表示的化合物; 和富勒烯或富勒烯衍生物。 在该式中，Z1表示形成5元或6元环所必需的原子团，L1，L2和L3各自独立地表示未取代的次甲基或取代的次甲基，D1表示原子团，n表示整数 为0以上。

公开(公告)号：US08847208B2

公开(公告)日：2014-09-30

申请号：US12793195

申请日：2010-06-03

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Katsuyuki Yofu

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Katsuyuki Yofu

IPC分类号： H01L51/46 ,  H01L51/00 ,  B82Y10/00 ,  H01L51/42

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/4246 ,  H01L51/4253 ,  Y02E10/549

摘要： Provided is a photoelectric conversion device comprising a transparent electrically conductive film, a photoelectric conversion film, and an electrically conductive film, wherein the photoelectric conversion film contains a compound represented by the following formula (i): wherein each of R2 to R9 independently represents a hydrogen atom or a substituent, provided that each of at least two out of R3, R4, R7 and R8 independently represents an aryl group, a heterocyclic group or —N(Ra)(Rb), each of Ra and Rb independently represents a hydrogen atom or a substituent, and at least either Ra or Rb represents an aryl group or a heterocyclic group; and R1 represents an alkyl group, an aryl group or a heterocyclic group.

摘要翻译： 提供一种包含透明导电膜，光电转换膜和导电膜的光电转换装置，其中光电转换膜含有由下式（i）表示的化合物：其中R2至R9各自独立地表示 氢原子或取代基，条件是R3，R4，R7和R8中的至少两个独立地表示芳基，杂环基或-N（Ra）（Rb），Ra和Rb各自独立地表示氢 原子或取代基，并且至少Ra或Rb表示芳基或杂环基; R 1表示烷基，芳基或杂环基。

公开(公告)号：US08513651B2

公开(公告)日：2013-08-20

申请号：US12794220

申请日：2010-06-04

申请人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano

发明人： Tetsuro Mitsui ,  Kimiatsu Nomura ,  Mitsumasa Hamano

IPC分类号： H01L29/12

CPC分类号： H01L51/4253 ,  B82Y10/00 ,  H01L51/0012 ,  H01L51/0047 ,  H01L51/0053 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0061 ,  Y02E10/549 ,  Y02P70/521

摘要： Provided is a photoelectric conversion device comprising an electrically conductive film, a photoelectric conversion film, and a transparent electrically conductive film, wherein the photoelectric conversion film contains a fullerene or a fullerene derivative and a photoelectric conversion material having an absorption spectrum satisfying at least either the following condition (A) or (B): λM1 Δ|λM2−λL2|  (B) wherein λL1, λL2, λM1 and λM2 are the wavelength at an absorption intensity of ½ of the maximum absorption intensity in the wavelength range of from 400 to 800 nm, each of λL1 and λL2 represents the wavelength in a chloroform solution spectrum when the photoelectric conversion material is dissolved in chloroform, and each of λM1 and λM2 represents the wavelength in a thin-film absorption spectrum of the photoelectric conversion material alone, provided that λL1

摘要翻译： 本发明提供一种光电转换元件，其特征在于，具有导电膜，光电转换膜和透明导电膜，其中，所述光电转换膜含有富勒烯或富勒烯衍生物，以及具有满足以下条件的吸收光谱的光电转换材料： 以下条件（A）或（B）：λM1<λL1和λM2<λL2（A）λM1<λL1和Δ|λM1-λL1|>Δ|λM2-λL2|（B）其中λL1，λL2，λM1和λM2是 在400至800nm的波长范围内，吸收强度为最大吸收强度的1/2的波长，λL1和λL2中的每一个表示当光电转换材料溶解在氯仿中时氯仿溶液光谱中的波长，λM1 λM2表示单独的光电转换材料的薄膜吸收光谱中的波长， 条件是λL1

公开(公告)号：US20120298846A1

公开(公告)日：2012-11-29

申请号：US13574969

申请日：2011-02-08

申请人： Kimiatsu Nomura ,  Tetsuro Mitsui

发明人： Kimiatsu Nomura ,  Tetsuro Mitsui

IPC分类号： H01L51/42 ,  H01L31/0232

CPC分类号： C07D223/26 ,  C07D209/86 ,  C07D209/88 ,  C07D219/14 ,  H01L27/14621 ,  H01L27/14623 ,  H01L27/14645

摘要： A photoelectric element includes a conductive layer, an organic photoelectric layer, a blocking layer and a transparent conductive layer, the organic photoelectric layer contains a p type organic photoelectric material having a glass transition temperature of 100° C. or higher and forms an amorphous layer, and the blocking layer contains a blocking material having a glass transition temperature of 140° C. or higher.

摘要翻译： 光电元件包括​​导电层，有机光电层，阻挡层和透明导电层，有机光电层含有玻璃化转变温度为100℃以上的ap型有机光电材料，形成非晶层， 并且阻挡层含有玻璃化转变温度为140℃以上的阻挡材料。

公开(公告)号：US08278650B2

公开(公告)日：2012-10-02

申请号：US12465727

申请日：2009-05-14

申请人： Kimiatsu Nomura ,  Tetsuro Mitsui ,  Hideyuki Suzuki ,  Rui Shen

发明人： Kimiatsu Nomura ,  Tetsuro Mitsui ,  Hideyuki Suzuki ,  Rui Shen

IPC分类号： H01L35/24

CPC分类号： C07D407/06 ,  H01L27/307 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/424 ,  H01L2251/308

摘要： An organic semiconductor includes: a compound represented by formula (I): wherein A1 represents O, S or N—R15; each of R11, R12, R13, R14 and R15 independently represents a hydrogen atom or a substituent W as defined in the specification, R11 and R12 may be linked to form a ring; B1 represents a ring structure containing at least one nitrogen atom; and n1 represents an integer of 0 to 2.

摘要翻译： 有机半导体包括：由式（I）表示的化合物：其中A1表示O，S或N-R15; R 11，R 12，R 13，R 14和R 15各自独立地表示如说明书中定义的氢原子或取代基W，R 11和R 12可以连接形成环; B1表示含有至少一个氮原子的环结构; n1表示0〜2的整数。

公开(公告)号：US08232471B2

公开(公告)日：2012-07-31

申请号：US12131171

申请日：2008-06-02

申请人： Kimiatsu Nomura ,  Tetsu Kitamura ,  Tetsuro Mitsui

发明人： Kimiatsu Nomura ,  Tetsu Kitamura ,  Tetsuro Mitsui

IPC分类号： H01L31/0216 ,  H01M4/02

CPC分类号： H01L51/0064 ,  C07D209/12 ,  C07D209/60 ,  H01L27/14643

摘要： A squarylium dye represented by formula (1): wherein A1 and B1 each independently represents a ring structure, and R1 and R2 each independently represents a substituent having a carbon number of 1 to 12.

摘要翻译： 由式（1）表示的方酸菁染料：其中A1和B1各自独立地表示环结构，并且R 1和R 2各自独立地表示碳数为1至12的取代基。

公开(公告)号：US09085537B2

公开(公告)日：2015-07-21

申请号：US13574969

申请日：2011-02-08

申请人： Kimiatsu Nomura ,  Tetsuro Mitsui

发明人： Kimiatsu Nomura ,  Tetsuro Mitsui

IPC分类号： H01L51/42 ,  C07D223/26 ,  C07D209/86 ,  C07D209/88 ,  C07D219/14 ,  H01L27/146

CPC分类号： C07D223/26 ,  C07D209/86 ,  C07D209/88 ,  C07D219/14 ,  H01L27/14621 ,  H01L27/14623 ,  H01L27/14645

摘要： A photoelectric element includes a conductive layer, an organic photoelectric layer, a blocking layer and a transparent conductive layer, the organic photoelectric layer contains a p type organic photoelectric material having a glass transition temperature of 100° C. or higher and forms an amorphous layer, and the blocking layer contains a blocking material having a glass transition temperature of 140° C. or higher.

摘要翻译： 光电元件包括​​导电层，有机光电层，阻挡层和透明导电层，有机光电层含有玻璃化转变温度为100℃以上的ap型有机光电材料，形成非晶层， 并且阻挡层含有玻璃化转变温度为140℃以上的阻挡材料。