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公开(公告)号：US4777321A
公开(公告)日：1988-10-11
申请号：US43716
申请日：1987-04-29
申请人： Mohsen N. Harandi , Hartley Owen , Sean C. Smyth
发明人： Mohsen N. Harandi , Hartley Owen , Sean C. Smyth
CPC分类号： C07C1/20 , C07C2529/40 , Y02P20/52
摘要： A process for converting crude aqueous methanol feedstock or the like to olefinic hydrocarbons in contact with a medium pore shape selective crystalline acid zeolite catalyst, wherein the improvement comprises contacting the aqueous methanol feedstock with a liquid propane-rich hydrocarbon extractant under liquid extraction conditions, recovering an aqueous phase containing the major amount of water introduced with the feedstock, recovering an organic extract phase comprising the hydrocarbon extractant and a portion of methanol introduced in the feedstock, and converting the extracted methanol at elevated temperature under catalytic reaction conditions to produce predominantly olefinic hydrocarbons.
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公开(公告)号：US4709113A
公开(公告)日：1987-11-24
申请号：US43718
申请日：1987-04-29
申请人： Mohsen N. Harandi , Hartley Owen , Sean C. Smyth
发明人： Mohsen N. Harandi , Hartley Owen , Sean C. Smyth
CPC分类号： C07C1/20 , C10L1/023 , C07C2529/40 , Y02P30/20 , Y10S203/24
摘要： A process for converting crude aqueous methanol feedstock to liquid hydrocarbons in contact witha medium pore shape selective crystalline acid zeolite catalyst, such as HZSM-5. In a preferred embodiment, the novel technique comprises the steps of: (a) contacting a crude methanol feedstock containing a minor amount of water with a liquid hydrocarbon extraction stream under extraction conditions favorable to selective extraction of the methanol, thereby providing an extract liquid stream rich in methanol and an aqueous raffinate stream lean in methanol; (b) charging the extracted methanol substantially free of water to said reaction zone under process conditions to convert substantially all methanol to hydrocarbons; (c) cooling reaction effluent to recover aqueous liquid byproduct stream, gas rich in C.sub.2.sup.- hydrocarbons, liquid rich in C.sub.3 -C.sub.4 and C.sub.5.sup.+ hydrocarbons; and (d) contacting crude methanol feedstock with at least a portion of the liquid hydrocarbons employed as extraction liquid.
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3.发明授权Feedstock preparation and reactor system for conversion to oxygenates to olefins 失效原料制备和用于转化为含氧化合物至烯烃的反应器系统
公开(公告)号：US5028400A
公开(公告)日：1991-07-02
申请号：US198264
申请日：1988-05-25
申请人： Mohsen N. Harandi , Hartley Owen , Sean C. Smyth
发明人： Mohsen N. Harandi , Hartley Owen , Sean C. Smyth
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/40
摘要： An improved system for converting crude aqueous methanol feedstock or the like to olefinic hydrocarbons in contact with a medium pore shape selective crystalline acid zeolite catalyst, wherein the improvement comprises feedstock preparation means contacting the aqueous methanol feedstock with a liquid propane-rich hydrocarbon extractant under liquid extraction conditions, means for recovering an aqueous phase containing the major amount of water introduced with the feedstock, means for recovering an organic extract phase comprising the hydrocarbon extractant and a portion of methanol introduced in the feedstock, and reactor means for converting the extracted methanol at elevated temperature under catalytic reaction conditions to produce predominantly olefinic hydrocarbons.
摘要翻译： 一种改进的系统，用于将粗的含水甲醇原料等转化为与中等孔隙形状的选择性结晶酸沸石催化剂接触的烯烃，其中改进包括原料制备方法，使甲醇水溶液与液体丙烷富含烃萃取剂在液体 萃取条件，用于回收含有用原料引入的大量水的水相的装置，用于回收包含烃萃取剂和引入原料的部分甲醇的有机萃取相的装置，以及用于将提取的甲醇转化为 在催化反应条件下升高温度，主要产生烯烃。
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公开(公告)号：US5599439A
公开(公告)日：1997-02-04
申请号：US322466
申请日：1994-10-14
CPC分类号： C10G69/08
摘要： A low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by octane enhancing treatment in a fluidized bed catalytic process, in the presence of an aromatics-rich feedstream. The process converts the hydrodesulfurized intermediate and the aromatics-rich feedstream to a gasoline boiling range fraction of high octane number. The fluidized bed catalytic process is carried out over zeolite catalyst particles in a turbulent reactor bed at a temperature of about 600.degree. to 800.degree. F. (316.degree. to 427.degree. C.) and pressure of about 100 to 250 psig (790 to 825 kPa. The catalyst has an apparent particle density of about 0.9 to 1.6 g/cm.sup.3 and a size range of about 1 to 150 microns, and average catalyst particle size of about 20 to 100 microns containing about 10 to 25 weight percent of fine particles having a particle size less than 32 microns. The feed vapor is passed upwardly through the fluidized catalyst bed under turbulent flow conditions; turbulent fluidized bed conditions are maintained through the reactor bed between transition velocity and transport velocity at a superficial fluid velocity of about 0.3 to 2 meters per second. Treatment in the fluidized bed catalytic process restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha.
摘要翻译： 通过加氢脱硫，然后在富含芳烃的进料流存在下，在流化床催化方法中进行辛烷值增强处理，由催化裂解的含硫石脑油产生相对高辛烷值的低硫汽油。 该方法将加氢脱硫中间体和富含芳烃的进料流转化为高辛烷值的汽油沸程。 流化床催化过程在湍流反应器床中在沸点催化剂颗粒上进行，温度为约600至800°F（316至427℃），压力为约100至250psig（790至825 催化剂具有约0.9至1.6g / cm 3的表观颗粒密度和约1至150微米的尺寸范围，并且约20至100微米的平均催化剂颗粒尺寸含有约10至25重量％的具有 进料蒸气在湍流条件下向上通过流化催化剂床;湍流流化床条件通过反应器床保持在过渡速度和输送速度之间，表面流体速度约为0.3至2 流化床催化过程中的处理恢复了由于氢化处理而发生的辛烷值损失，导致低硫汽油产物与 辛烷值与进料石脑油相当。
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公开(公告)号：US5401387A
公开(公告)日：1995-03-28
申请号：US101810
申请日：1993-08-03
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
IPC分类号： C10G51/02
CPC分类号： C10G51/026
摘要： A process for multi-stage catalytic cracking is disclosed. A first stage cracks a first feed at atmospheric to 100 psig over a shape selective zeolite to convert from 10 to 90%, by volume, to lighter products rich in iso-compounds which may be used to make ethers. A second feed, which may include 700.degree. F.+ liquid from the selective cracking reaction, is cracked in a catalytic cracking (FCC) unit. Preferably all or some of the products from the shape selective cracking reactor are fractionated in the FCC main column.
摘要翻译： 公开了一种多级催化裂化方法。 第一阶段在形状选择性沸石上将大气压下的第一次进料裂解至100psig，将体积的10至90％转化成可用于制备醚的富含异构体的较轻质产物。 来自选择性裂解反应的可能包括700°F +液体的第二进料在催化裂化（FCC）单元中裂化。 优选地，来自形状选择性裂化反应器的所有或一些产物在FCC主塔中分馏。
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公开(公告)号：US5348707A
公开(公告)日：1994-09-20
申请号：US644141
申请日：1991-01-22
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
摘要： A multistage catalytic reactor system for preparing ethers such as methyl t-butyl (MTBE) and t-amyl methyl ether (TAME) from iso-olefin and methanol, comprising a first reactor for contacting the iso-olefin and alcohol with a solid regenerable catalyst, such as medium-pore zeolite conversion catalyst for partial conversion of the iso-olefin and methanol to an unsymmetrical ether, operatively connected for feeding effluent from the first reactor to a second etherification reaction zone containing sensitive catalyst, such as macroreticular polystyrenesulfonic acid resin. In a preferred embodiment, the second reaction zone comprises an inlet means for receiving withdrawn intermediate product, a catalytic distillation column containing solid acid resin etherification catalyst in a plurality of fixed bed catalysis-distillation zones, and outlet means for withdrawing a final etherification product.
摘要翻译： 一种用于从异烯烃和甲醇制备醚如甲基叔丁基（MTBE）和叔戊基甲基醚（TAME）的多级催化反应器系统，包括用于使异烯烃和醇与固体可再生催化剂接触的第一反应器 ，例如用于将异烯烃和甲醇部分转化成不对称醚的中孔沸石转化催化剂，其可操作地连接用于将来自第一反应器的流出物供给到包含敏感催化剂的大孔聚苯乙烯磺酸树脂的第二醚化反应区。 在优选的实施方案中，第二反应区包括用于接收取出的中间产物的入口装置，在多个固定床催化蒸馏区中含有固体酸树脂醚化催化剂的催化蒸馏塔和用于取出最终醚化产物的出口装置。
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7.发明授权Upgrading C4 mixed hydrocarbons by transhydrogenation and isobutene etherification 失效通过转氢和异丁烯醚化来升级C4混合烃
公开(公告)号：US5176719A
公开(公告)日：1993-01-05
申请号：US614479
申请日：1990-11-16
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
摘要： A technique for converting olefinic light hydrocarbons rich in butenes and butanes to ether-rich liquid fuels including etherification and transhydrogenation operations. The preferred process includes: reacting a mixed C4 hydrocarbon stream containing isobutene and n-butenes with lower aliphatic alcohol in an etherification zone in contact with an acidic etherification catalyst under etherification conditions whereby an effluent stream containing C5+ tertiary-alkyl ether is produced; separating the etherification effluent stream to provide a liquid stream comprising C5+ ether and an olefinic stream comprising unreacted C4 hydrocarbons; contacting at least the n-butenes from the C.sub.4 olefinic hydrocarbon stream with isobutane under transhydrogenation conditions in the presence of transhydrogenation catalyst whereby isobutane is converted to isobutene; separating transhydrogenation effluent to recover a C4 olefinic intermediate stream containing isobutene; and passing at least a portion of the isobutene-containing intermediate stream to the etherification zone for conversion to tertiary-alkyl ether.
摘要翻译： 将富含丁烯和丁烷的烯烃轻质烃转化为富含醚的液体燃料的技术，包括醚化和转氢操作。 优选的方法包括：在醚化条件下使含有异丁烯和正丁烯的混合C 4烃流与醚化区中的酸性醚化催化剂接触的低级脂族醇反应，从而产生含有C5 +叔烷基醚的流出物流; 分离醚化流出物流以提供包含C5 +醚和包含未反应的C 4烃的烯烃流的液体流; 在转氢催化剂的存在下，在转氢氢化条件下，使来自C4烯烃的至少一种烃与异丁烷接触，由此将异丁烷转化为异丁烯; 分离反氢化流出液以回收含有异丁烯的C 4烯烃中间体流; 并将至少一部分含异丁烯的中间物流送至醚化区转化为叔烷基醚。
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公开(公告)号：US5144085A
公开(公告)日：1992-09-01
申请号：US500356
申请日：1990-03-28
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
CPC分类号： C07C41/06 , Y02P20/582
摘要： Improved process techniques and equipment for reacting crude aqueous ethanol feedstock with iso-olefinic hydrocarbons to produce C.sub.6.sup.+ ethyl t-alkyl ethers, which comprises: distilling the aqueous ethanol feedstock; contacting ethanol rich distillate overhead containing a minor amount of water with a liquid hydrocarbon extractant rich in C.sub.4.sup.+ isoalkene under liquid extraction conditions; recovering an aqueous phase containing water introduced from the overhead; recovering an organic extract phase comprising the hydrocarbon extractant and a major amount of ethanol introduced in the feedstock; and reacting the extracted ethanol and C.sub.4.sup.+ isoalkene in contact with an acid etherification catalyst under catalytic reaction conditions to produce ether product.
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公开(公告)号：US5041690A
公开(公告)日：1991-08-20
申请号：US563731
申请日：1990-08-03
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
CPC分类号： C10G3/49 , C07C41/01 , C07C41/06 , C10L1/023 , C10G2400/02 , C10G2400/20 , Y02P20/125 , Y02P30/20
摘要： Methanol or other alcohol is converted to high octane gasoline components by an integrated process wherein crude aqueous alcohol feedstock is extracted with a liquid extractant stream containing C.sub.4 +iso-olefin and reacted to form tertiary-alkyl ethers, such as MTBE. The aqueous raffinate is converted to olefinic hydrocarbons in a MTO catalytic reactor. Propene from the MTO reaction is reacted with water to produce di-isopropyl ether, which may be blended with MTBE and C.sub.6 +MTO hydrocarbons to produce high octane gasoline. Isobutylene and isoamylenes from the MTO reaction can be recovered and recycled as a liquid extractant stream.
摘要翻译： 通过一体化方法将甲醇或其它醇转化成高辛烷值的汽油成分，其中用含有C4 +异烯烃的液体萃取剂流提取粗制的含水醇原料，并反应形成叔烷基醚，如MTBE。 在MTO催化反应器中将含水残液转化为烯烃。 与MTO反应的丙烯与水反应产生二异丙醚，可与MTBE和C6 + MTO烃混合生产高辛烷值汽油。 来自MTO反应的异丁烯和异戊烯可以作为液体萃取剂流回收和再循环。
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公开(公告)号：US4981574A
公开(公告)日：1991-01-01
申请号：US322880
申请日：1989-03-14
申请人： Mohsen N. Harandi , Hartley Owen
发明人： Mohsen N. Harandi , Hartley Owen
IPC分类号： C10G45/64
CPC分类号： C10G45/64
摘要： A process is disclosed for dewaxing a waxy hydrocarbon feedstock and for upgrading the olefinic interstage by-product to a high-octane gasoline blending stream. Waxy hydrocarbon feedstock is catalytically dewaxed until the catalyst is deactivated. Hydrogen-rich gas or, optionally, oxygen-containing gas, is then circulated to at least partially reactivate the catalyst. The interstage by-product, stored during the dewaxing run, is then upgraded in the reaction zone to a high-octane gasoline blending component.
摘要翻译： 公开了一种用于将蜡质烃原料脱蜡并将烯烃级副产物升级为高辛烷值汽油混合物流的方法。 将蜡质烃原料催化脱蜡，直到催化剂失活。 然后将富氢气体或任选的含氧气体循环至少部分地使催化剂再活化。 然后在脱蜡运行期间储存的级间副产物在反应区中升级成高辛烷值汽油调和组分。
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