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1.发明授权Poly (arylene ether sulfone) having sulfoalkoxy group, process of producing the same, and polymer electrolyte membrane comprising the same 有权具有磺基烷氧基的聚（亚芳基醚砜），其制造方法和包含该聚合物的聚合物电解质膜公开(公告)号：US06986960B2
公开(公告)日：2006-01-17
申请号：US10298936
申请日：2002-11-19
申请人： Motohiro Oguri , Ryuji Ikeda , Fumio Okisaki
发明人： Motohiro Oguri , Ryuji Ikeda , Fumio Okisaki
CPC分类号： C08L81/06 , C08G2650/02 , H01M8/1027 , H01M8/1032
摘要： A novel poly(arylene ether sulfone) having a sulfoalkoxy group, which has both of heat resistance and electroconductivity, is suitable as polymer electrolyte membranes used for high performance polymer electrolyte fuel cells, and does not use fluorine so that loads to the environment are small in the synthesis or disposal, a process of producing the same, and a polymer electrolyte membrane comprising the same. The poly(arylene ether sulfone) having a sulfoalkoxy group has a structural unit represented by the formula (1) mentioned hereinabove, and is produced by reacting a poly(arylene ether sulfone) having a hydroxyl group with a specific alkali metal compound and/or an organic base compound, followed by reacting with a specific sulfonating agent and then with a specific acid. A polymer electrolyte membrane is produced by film formation of the polymer.
摘要翻译： 具有耐硫性和导电性两者的具有磺基烷氧基的新型聚（亚芳基醚砜）适合作为用于高性能聚合物电解质燃料电池的聚合物电解质膜，并且不使用氟，因此对环境的负荷小 在合成或处理中，其制备方法和包含该方法的聚合物电解质膜。 具有磺基烷氧基的聚（亚芳基醚砜）具有由上述式（1）表示的结构单元，其通过使具有羟基的聚（亚芳基醚砜）与特定的碱金属化合物和/或 有机碱化合物，然后与特定的磺化剂反应，然后与特定的酸反应。 聚合物电解质膜通过聚合物的膜形成来制造。
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2.发明授权
公开(公告)号：US5994435A
公开(公告)日：1999-11-30
申请号：US898602
申请日：1997-07-22
申请人： Kimitaka Kuma , Kenji Koyama , Nobuhiro Fujita , Takumi Kagawa , Fumio Okisaki , Keiji Itabashi
发明人： Kimitaka Kuma , Kenji Koyama , Nobuhiro Fujita , Takumi Kagawa , Fumio Okisaki , Keiji Itabashi
摘要： The subject of the invention is to provide a new high-performance flame retardant having excellent flame resistant effect and smoke-suppressing effect and generating no hazardous gas, and a new flame retardant resin-composition used it. As a means for solution, a flame retardant comprising ethylenediamine-containing zinc phosphate and other phosphorus-containing compound is formulated in amounts of 10 to 200 parts by weight to 100 parts by weight of resin.
摘要翻译： 本发明的目的是提供一种具有优异的阻燃效果和烟雾抑制效果并且不产生有害气体的新的高性能阻燃剂，并且使用它的新的阻燃树脂组合物。 作为溶液的方法，含有乙二胺的磷酸锌和其它含磷化合物的阻燃剂配制成相对于100重量份树脂为10〜200重量份。
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公开(公告)号：US6017987A
公开(公告)日：2000-01-25
申请号：US17241
申请日：1998-02-02
申请人： Fumio Okisaki , Akinori Hamada , Shunichi Endo , Genichiro Ochiai
发明人： Fumio Okisaki , Akinori Hamada , Shunichi Endo , Genichiro Ochiai
摘要： A novel fire-retardant polymer composition is provided which comprises 100 parts by weight of a polymer such as polyolefins and polystyrenes, 1-30 parts by weight of an oxide or a complex oxide of metals such as antimony, boron, and molybdenum, and 1-30 parts by weight of heat-expandable graphite. The fire-retardant polymer composition emits less amounts of smoke and corrosive gas on burning with the characteristics of the polymer material kept unimpaired.
摘要翻译： 提供了一种新型阻燃聚合物组合物，其包含100重量份聚合物如聚烯烃和聚苯乙烯，1-30重量份的氧化物或金属如锑，硼和钼的复合氧化物和1 -30重量份的热膨胀性石墨。 阻燃聚合物组合物在燃烧时发射较少量的烟雾和腐蚀性气体，同时保持不受损害的聚合物材料的特性。
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公开(公告)号：US5015526A
公开(公告)日：1991-05-14
申请号：US412087
申请日：1989-09-25
CPC分类号： C08K5/06 , C08K3/0091 , C08K5/03 , H01B3/30 , Y10T428/2938 , Y10T428/294 , Y10T428/2958 , Y10T428/296 , Y10T428/3154 , Y10T428/31544 , Y10T428/31699
摘要： A radiation-resistant high molecular composition is disclosed, charqacterized in that, to the high molecular polymer, a halogenated acenaphtylene and/or condensates thereof represented by a following general formula [I] ##STR1## (wherein, X indicates a chlorine or bromine atom, a indicates 0 to 2, b indicates 1 to 6 and n indicates an integer not less than 1) and a diphenyl ether derivative represented by a following general formula [II] ##STR2## (wherein, R.sub.1 and R.sub.2 indicate any ones of hydrogen atom, alkyl, alkoxy, phenyl phenoxy, diphenyloxy and terphenyloxy group) and/or basic lead compound are formulated.
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公开(公告)号：US4900766A
公开(公告)日：1990-02-13
申请号：US98883
申请日：1987-09-21
CPC分类号： C08K5/06 , C08K3/0091 , C08K5/03 , H01B3/30 , Y10T428/2938 , Y10T428/294 , Y10T428/2958 , Y10T428/296 , Y10T428/3154 , Y10T428/31544 , Y10T428/31699
摘要： A radiation-resistant high molecular composition is disclosed, characterized in that, to the high molecular polymer, a halogenated acenaphtylene and/or condensates thereof represented by a following general formula [I] ##STR1## (wherein, X indicates a chlorine or bromine atom, a indicates 0 to 2, b indicates 1 to 6 and n indicates an integer not less than 1) and a diphenyl ether derivative represented by a following general formula [II] ##STR2## (wherein, R.sub.1 and R.sub.2 indicate any ones of hydrogen atom, alkyl, alkoxy, phenyl phenoxy, diphenyloxy and terphenyloxy group) and/or basic lead compound are formulated.
摘要翻译： 公开了耐辐射高分子组合物，其特征在于，对于高分子聚合物，由以下通式[I]表示的卤化亚萘基和/或缩合物：其中X表示氯 或溴原子，a表示0〜2，b表示1〜6，n表示1以上的整数）和由以下通式[II]表示的二苯醚衍生物[II]（其中，R1和 R2表示任何氢原子，烷基，烷氧基，苯氧基，二苯氧基和三苯氧基）和/或碱性铅化合物。
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公开(公告)号：US5942561A
公开(公告)日：1999-08-24
申请号：US610134
申请日：1996-02-29
申请人： Fumio Okisaki , Akinori Hamada , Shunichi Endo , Genichiro Ochiai
发明人： Fumio Okisaki , Akinori Hamada , Shunichi Endo , Genichiro Ochiai
摘要： A fire-retardant polymer composition is provided which comprises 100 parts by weight of a polymer such as polystyrene, 1 to 30 parts by weight of heat-expandable graphite, and 1 to 30 parts by weight of a phosphorus compound. The polymer composition is fire-retardant, and emits less smoke and less corrosive gas on burning.
摘要翻译： 提供了一种阻燃聚合物组合物，其包含100重量份聚合物如聚苯乙烯，1〜30重量份的热膨胀性石墨和1〜30重量份的磷化合物。 聚合物组合物是阻燃剂，并且在燃烧时排出较少的烟雾和较少的腐蚀性气体。
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公开(公告)号：US4935562A
公开(公告)日：1990-06-19
申请号：US281037
申请日：1988-12-07
申请人： Fumio Okisaki , Masashige Kubo , Satoshi Fujii , Kiyotaka Oyama
发明人： Fumio Okisaki , Masashige Kubo , Satoshi Fujii , Kiyotaka Oyama
IPC分类号： C07B61/00 , B01J21/06 , B01J23/06 , B01J23/14 , B01J23/18 , B01J27/10 , B01J27/135 , C07C17/00 , C07C17/12 , C07C25/18 , C07C67/00
CPC分类号： C07C17/12
摘要： A method for producing 4,4'-dibromobiphenyl, which comprises reacting biphenyl and from 2 to 3 mol times, relative to biphenyl, of bromine in a halogenated hydrocarbon solvent in the presence of a catalyst which is a simple substance of an element selected from the group consisting of antimony, titanium, tin and zinc, or a compound of the element.
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公开(公告)号：US5810914A
公开(公告)日：1998-09-22
申请号：US813206
申请日：1997-03-07
申请人： Fumio Okisaki , Akinori Hamada , Masahiro Obasa
发明人： Fumio Okisaki , Akinori Hamada , Masahiro Obasa
CPC分类号： C08K3/04 , C08K3/32 , C08L71/12 , C08L77/00 , Y10S428/92 , Y10S428/921
摘要： A flame-retardant engineering plastic composition comprising (A) 100 parts by weight of an engineering plastic, (B) from 1 to 30 parts by weight of a heat-expandable graphite, and (C) from 1 to 30 parts by weight of red phosphorus and/or (D) from 1 to 30 parts by weight of a phosphorus compound.
摘要翻译： 一种阻燃工程塑料组合物，其包含（A）100重量份的工程塑料，（B）1至30重量份的热膨胀性石墨，和（C）1至30重量份的红 磷和/或（D）1〜30重量份的磷化合物。
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公开(公告)号：US5760115A
公开(公告)日：1998-06-02
申请号：US609902
申请日：1996-02-29
申请人： Fumio Okisaki , Akinori Hamada , Shunichi Endo , Genichiro Ochiai
发明人： Fumio Okisaki , Akinori Hamada , Shunichi Endo , Genichiro Ochiai
摘要： A novel fire-retardant polymer composition is provided which comprises 100 parts by weight of a polymer such as polyolefins and polystyrenes, 1-30 parts by weight of an oxide or a complex oxide of metals such as antimony, boron, and molybdenum, and 1-30 parts by weight of heat-expandable graphite. The fire-retardant polymer composition emits less amounts of smoke and corrosive gas on burning with the characteristics of the polymer material kept unimpaired.
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公开(公告)号：US4822931A
公开(公告)日：1989-04-18
申请号：US123533
申请日：1987-11-18
申请人： Fumio Okisaki , Masashige Kubo , Hideo Sakka
发明人： Fumio Okisaki , Masashige Kubo , Hideo Sakka
CPC分类号： C07C17/12
摘要： A method for preparing Con-BAN, in which Con-AN is reacted with bromine in the presence of an iron Lewis acid catalyst and in which the solution of Con-AN and bromine are supplied simultaneously at a given rate into a reactor already containing a halogenated hydrocarbon and an iron catalyst.
摘要翻译： 一种制备Con-BAN的方法，其中Con-AN在铁路易斯酸催化剂存在下与溴反应，其中Con-AN和溴的溶液以给定的速率同时供给到已经含有 卤代烃和铁催化剂。
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