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公开(公告)号：US06395341B1
公开(公告)日：2002-05-28
申请号：US09354152
申请日：1999-07-16
IPC分类号： B05D136
CPC分类号： C08G65/48 , C08F8/42 , C08G63/916 , C08G64/42 , C08G65/485 , C08G83/001 , C08J3/245
摘要： According to the present invention, organic-inorganic hybrid polymer materials with compositional gradient, and processes for preparing the same are provided. In the organic-inorganic hybrid polymer materials with compositional gradient, formation of cracks, removal of surface, or deformation such as warp and distortion, under heat shock or upon aging, hardly occurs. The organic-inorganic hybrid polymer materials with compositional gradient are comprised of an organic polymer component and a metal oxide component which are covalently bonded each other, characterized in that concentration of the organic polymer component, or of the metal oxide component is increased or decreased in the direction of thickness of the material.
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2.发明授权公开(公告)号：US06476098B1
公开(公告)日：2002-11-05
申请号：US09572497
申请日：2000-05-18
IPC分类号： C08K906
CPC分类号： C08G83/001 , C08K9/08 , Y10S977/753 , Y10S977/776 , Y10S977/778 , Y10S977/788
摘要： According to the present invention, there is provided an organic-inorganic composite material which shows high mechanical strength and high water resistance, requires low cost for preparation, and is preferred to be used as a high performance and a high functional plastic material. The present invention provides an organic-inorganic composite material which comprises a matrix of an organic polymer (E), metal oxide particles (C) dispersed uniformly in the organic polymer (E), and a surface modifier for allowing the metal oxide particles (C) to disperse uniformly in the organic polymer (E), wherein the surface modifier is another organic polymer (A) which has a functional group formable of a covalent bond to a surface of the metal oxide particles (C).
摘要翻译： 根据本发明，提供了一种机械强度高，耐水性高的有机 - 无机复合材料，制备成本低，优选用作高性能和高功能塑料材料。 本发明提供一种有机 - 无机复合材料，其包含有机聚合物（E）的基体，均匀分散在有机聚合物（E）中的金属氧化物颗粒（C））和表面改性剂，用于使金属氧化物颗粒（C ）分散在有机聚合物（E）中，其中表面改性剂是具有与金属氧化物颗粒（C）的表面形成共价键的官能团的另一种有机聚合物（A）。
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3.发明授权公开(公告)号：US06228796B1
公开(公告)日：2001-05-08
申请号：US09472975
申请日：1999-12-28
IPC分类号： B01J3100
CPC分类号： B01J21/066 , B01D53/86 , B01D2255/802 , B01J21/063 , B01J31/069 , B01J35/002 , B01J35/004 , B01J37/0209 , B01J37/0244 , B01J37/033 , Y10T428/252 , Y10T428/31663
摘要： The present invention is made to provide an organic-inorganic hybrid material, a surface of which is supplied with a layer having photo-catalysis, without photo-degradation of the substrate. The present invention provides an organic-inorganic hybrid material comprising a substrate, an intermediate layer and a photo-catalysis layer which are sequentially formed on a surface of the substrate wherein, the intermediate layer is composed of an organic-inorganic hybrid polymer material in which an organic polymer component and a metal oxide component are covalently bonded each other, which is obtained by hydrolyzing and polycondensing a solution or a wet gel which comprises an organic polymer having an alkoxymetal group as a functional group or an organic polymer having a functional group reactable with a metal alkoxide compound, and a metal alkoxide compound, and the photo-catalysis layer is composed of metal oxides having photo-catalysis.
摘要翻译： 本发明提供一种有机 - 无机混合材料，其表面被提供有光催化层，而不会使基板光降解。 本发明提供了一种有机 - 无机混合材料，其包含依次形成在基板的表面上的基板，中间层和光催化层，其中，中间层由有机 - 无机杂化聚合物材料构成，其中 有机聚合物组分和金属氧化物组分彼此共价键合，其通过水解和缩聚溶液或湿凝胶获得，所述溶液或湿凝胶包含具有烷氧基金属基团作为官能团的有机聚合物或具有可反应官能团的有机聚合物 与金属醇盐化合物和金属醇盐化合物反应，光催化层由具有光催化作用的金属氧化物构成。
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4.发明授权Organic-inorganic hybrid polymer material and process for preparing the same 有权有机 - 无机杂化聚合物材料及其制备方法
公开(公告)号：US6103854A
公开(公告)日：2000-08-15
申请号：US196787
申请日：1998-11-20
CPC分类号： C08G83/001 , C08G63/64 , C08G64/14 , C08G63/916 , C08G64/42
摘要： According to the present invention, the characteristics of an inorganic material are suitably supplied to an organic material, and the characteristics of an organic material are suitably supplied to an inorganic material. The organic-inorganic hybrid polymer is obtained by the process in which a polymer having a polycarbonate and/or a polyarylate moiety as a main frame and having a metal alkoxide group as a functional group, is hydrolyzed and polycondensed to form crosslinkages. Another process is that in which a polymer having a polycarbonate and/or a polyarylate moiety as a main frame and having a metal alkoxide group as a functional group, and a metal alkoxide compound are cohydrorized and copolycondensed to form crosslinkages.
摘要翻译： 根据本发明，无机材料的特性适当地供给到有机材料中，有机材料的特性适当地供给到无机材料中。 有机 - 无机杂化聚合物通过其中以聚碳酸酯和/或多芳基化合物部分为主体并具有金属醇盐基作为官能团的聚合物水解和缩聚以形成交联的方法获得。 另一方法是其中具有聚碳酸酯和/或多芳基化合物部分作为主要框架并具有金属醇盐基团作为官能团的聚合物和金属醇盐化合物被共沉淀并共缩聚以形成交联。
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5.发明授权Organic-inorganic hybrid polymer materials with compositional gradient, and processes for preparing the same 失效具有组成梯度的有机 - 无机杂化聚合物材料及其制备方法公开(公告)号：US06965001B2
公开(公告)日：2005-11-15
申请号：US10014512
申请日：2001-12-14
IPC分类号： C08K3/36 , C08F8/42 , C08G63/91 , C08G64/42 , C08G65/48 , C08G83/00 , C08J3/24 , C08L67/00 , C08L69/00 , C08L83/02 , C08L85/00 , C08L101/00 , C09D169/00 , C09D183/02 , C08F283/00 , C08G77/00
CPC分类号： C08G65/48 , C08F8/42 , C08G63/916 , C08G64/42 , C08G65/485 , C08G83/001 , C08J3/245
摘要： According to the present invention, organic-inorganic hybrid polymer materials with compositional gradient, and processes for preparing the same are provided. In the organic-inorganic hybrid polymer materials with compositional gradient, formation of cracks, removal of surface, or deformation such as warp and distortion, under heat shock or upon aging, hardly occurs. The organic-inorganic hybrid polymer materials with compositional gradient are comprised of an organic polymer component and a metal oxide component which are covalently bonded each other, characterized in that concentration of the organic polymer component, or of the metal oxide component is increased or decreased in the direction of thickness of the material.
摘要翻译： 根据本发明，提供了具有组成梯度的有机 - 无机杂化聚合物材料及其制备方法。 在具有组成梯度的有机 - 无机杂化聚合物材料中，几乎不发生在热冲击或老化时形成裂纹，去除表面或变形如翘曲和变形。 具有组成梯度的有机 - 无机杂化聚合物材料由共价键合的有机聚合物组分和金属氧化物组分组成，其特征在于有机聚合物组分或金属氧化物组分的浓度增加或降低 材料的厚度方向。
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公开(公告)号：US20050174880A1
公开(公告)日：2005-08-11
申请号：US10475772
申请日：2002-04-26
IPC分类号： C08G83/00 , C08J3/00 , C08L101/06 , B29B7/00 , C08L11/10 , C08G63/91 , B01F7/00 , B01F7/08 , B01F7/24
CPC分类号： C08J3/005 , B29C48/40 , C08G83/001 , C08L101/06 , C08L2666/02
摘要： Disclosed is a polymeric material obtained by melt-kneading, using a kneading machine, a resin composition which contains organic polymers having metal alkoxy groups. An organic-inorganic hybrid polymeric material which is suitable for use in high-performance and high-function polymeric materials, was provided.
摘要翻译： 公开了通过使用捏合机将含有具有金属烷氧基的有机聚合物的树脂组合物熔融捏合而获得的聚合物材料。 提供了适用于高性能和高功能聚合物材料的有机 - 无机杂化聚合材料。
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公开(公告)号：US06818736B2
公开(公告)日：2004-11-16
申请号：US10170568
申请日：2002-06-14
IPC分类号： C08F600
CPC分类号： C08K5/5415 , C08G83/001 , C08K5/057 , C08L33/06 , C08L67/00 , C08L69/00 , C08L77/00 , C08L81/06
摘要： Disclosed is a polymeric material obtained by melt-kneading, using a kneading apparatus, a resin composition containing an organic polymer having no metal alkoxy group and a metal alkoxide compound. The organic-inorganic hybrid polymeric material, a polymeric material containing this component, and a molded products obtained therefrom are suitable for high-performance and high-function plastic applications. Simple and practical processes for producing them at high productivity and at low cast are also disclosed.
摘要翻译： 公开了通过使用捏合装置将含有不含金属烷氧基的有机聚合物和金属醇盐化合物的树脂组合物熔融捏合而获得的聚合物材料。 有机 - 无机杂化聚合物材料，含该成分的聚合物材料和由其获得的模制产品适用于高性能和高功能塑料应用。 还公开了以高生产率和低铸造生产它们的简单实用的方法。
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8.发明授权Copolymer having reactive silicon-containing group and organic-inorganic hybrid polymeric material 失效具有反应性含硅基团和有机 - 无机杂化聚合物材料的共聚物公开(公告)号：US07326762B2
公开(公告)日：2008-02-05
申请号：US11313788
申请日：2005-12-22
IPC分类号： C08G77/20
CPC分类号： C08F293/00 , C08F290/06 , Y10S528/901
摘要： Disclosed is a copolymer comprising a polyethylene segment which is a main chain; a reactive silicon-containing group which is a side group of the polyethylene segment; and a polycondensation segment bonded to the polyethylene segment, which is a part of the main chain together with the polyethylene segment or a side chain with respect to the polyethylene segment. There are provided a condensation polymer having many reactive silicon-containing groups with respect to one molecule and an organic-inorganic hybrid polymeric material having superior properties such as strength, heat resistance, weather resistance and chemical resistance by using the polymer.
摘要翻译： 公开了包含作为主链的聚乙烯部分的共聚物; 作为聚乙烯部分的侧基的反应性含硅基团; 以及与聚乙烯部分结合的缩聚链段，该聚乙烯部分是与聚乙烯部分或侧链相对于聚乙烯部分一起的主链的一部分。 提供了相对于一个分子具有许多反应性含硅基团的缩合聚合物和通过使用该聚合物而具有优异性能如强度，耐热性，耐候性和耐化学性的有机 - 无机复合聚合材料。
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9.发明授权Copolymer having reactive silicon-containing group and organic-inorganic hybrid polymeric material 失效具有反应性含硅基团和有机 - 无机杂化聚合物材料的共聚物公开(公告)号：US07157542B2
公开(公告)日：2007-01-02
申请号：US10736708
申请日：2003-12-17
IPC分类号： C08G77/20
CPC分类号： C08F293/00 , C08F290/06 , Y10S528/901
摘要： Disclosed is a copolymer comprising a polyethylene segment which is a main chain; a reactive silicon-containing group which is a side group of the polyethylene segment; and a polycondensation segment bonded to the polyethylene segment, which is a part of the main chain together with the polyethylene segment or a side chain with respect to the polyethylene segment. There are provided a condensation polymer having many reactive silicon-containing groups with respect to one molecule and an organic-inorganic hybrid polymeric material having superior properties such as strength, heat resistance, weather resistance and chemical resistance by using the polymer.
摘要翻译： 公开了包含作为主链的聚乙烯部分的共聚物; 作为聚乙烯部分的侧基的反应性含硅基团; 以及与聚乙烯部分结合的缩聚链段，该聚乙烯部分是与聚乙烯部分或侧链相对于聚乙烯部分一起的主链的一部分。 提供了相对于一个分子具有许多反应性含硅基团的缩合聚合物和通过使用该聚合物而具有优异性能如强度，耐热性，耐候性和耐化学性的有机 - 无机复合聚合材料。
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10.发明申请Copolymer having reactive silicon-containing group and organic-inorganic hybrid polymeric material 失效具有反应性含硅基团和有机 - 无机杂化聚合物材料的共聚物公开(公告)号：US20060100405A1
公开(公告)日：2006-05-11
申请号：US11313788
申请日：2005-12-22
CPC分类号： C08F293/00 , C08F290/06 , Y10S528/901
摘要： Disclosed is a copolymer comprising a polyethylene segment which is a main chain; a reactive silicon-containing group which is a side group of the polyethylene segment; and a polycondensation segment bonded to the polyethylene segment, which is a part of the main chain together with the polyethylene segment or a side chain with respect to the polyethylene segment. There are provided a condensation polymer having many reactive silicon-containing groups with respect to one molecule and an organic-inorganic hybrid polymeric material having superior properties such as strength, heat resistance, weather resistance and chemical resistance by using the polymer.
摘要翻译： 公开了包含作为主链的聚乙烯部分的共聚物; 作为聚乙烯部分的侧基的反应性含硅基团; 以及与聚乙烯部分结合的缩聚链段，该聚乙烯部分是与聚乙烯部分或侧链相对于聚乙烯部分一起的主链的一部分。 提供了相对于一个分子具有许多反应性含硅基团的缩合聚合物和通过使用该聚合物而具有优异性能如强度，耐热性，耐候性和耐化学性的有机 - 无机复合聚合材料。
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