公开(公告)号：US20090253876A1

公开(公告)日：2009-10-08

申请号：US11920767

申请日：2006-05-24

申请人： Munehito Funaya ,  Koji Endo ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

发明人： Munehito Funaya ,  Koji Endo ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

IPC分类号： C08F2/00 ,  C07F7/02 ,  B01J31/12 ,  C08F4/42 ,  C07F7/00 ,  C07C25/24

CPC分类号： C07C13/567 ,  C07F7/081 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/15 ,  C08F210/06 ,  C08F210/14

摘要： Provided is a novel fluorene derivative which is useful as a catalyst component for olefin polymerization, a transition metal compound containing the fluorene derivative as a part of ligand, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing olefin polymer. The fluorene derivative is characterized by being represented by the following general formula [I]: wherein R1, R2, R3, R5, R6, R7, R8, R9, R10, R11, R12, and R14 are each selected from hydrogen, a hydrocarbon group, and a silicon-containing group, and may be the same as or different from each other, R4 and R13 are each selected from hydrogen, a hydrocarbon group, a silicon-containing group, a sulfur-containing group, an oxygen-containing group, a nitrogen-containing group, and a halogen-containing group, and may be the same as or different from each other, and adjacent substituents of R1 to R14 may be bonded to each other to form a ring, except that the case where R4 and R5, and R12 and R13 are each bonded to each other to form a vinylene group. Also provided is a bridged metallocene compound having both of the skeleton and a cyclopentadiene skeleton.

摘要翻译： 提供了可用作烯烃聚合的催化剂组分的新型芴衍生物，含有芴衍生物作为配体的一部分的过渡金属化合物，含有过渡金属化合物的烯烃聚合用催化剂和烯烃聚合物的制造方法。 芴衍生物的特征在于由以下通式[I]表示：其中R1，R2，R3，R5，R6，R7，R8，R9，R10，R11，R12和R14各自选自氢，烃 基团和含硅基团，并且可以彼此相同或不同，R4和R13各自选自氢，烃基，含硅基团，含硫基团，含氧基团 基团，含氮基团和含卤素基团，可以相同或不同，R1〜R14的相邻取代基可以相互键合形成环，除了以下情况 R4和R5以及R12和R13各自彼此键合形成亚乙烯基。 还提供了具有骨架和环戊二烯骨架两者的桥连金属茂化合物。

公开(公告)号：US20090043057A1

公开(公告)日：2009-02-12

申请号：US11920779

申请日：2006-05-24

申请人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

发明人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

IPC分类号： C08F4/78 ,  C07F7/08 ,  C07F11/00 ,  C08F2/00 ,  B01J31/12

CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/15 ,  C08F2500/03 ,  C08F210/06 ,  C08F2500/17 ,  C08F4/65927

摘要： Provided is a transition metal compound novel and useful as a catalyst component for olefin polymerization, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing an olefin polymer using the catalyst for polymerization. The transition metal is characterized by being represented by the following general formula [I]: wherein, R3 is hydrogen, R2 is selected from a hydrocarbon group or a silicon-containing group, R1 and R4 are selected from a hydrocarbon group having 2 to 20 carbon atoms and a silicon-containing group, each of R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14, which is selected from hydrogen, a hydrocarbon group and a silicon-containing group, may be same or different from each other, and adjacent groups from R5 to R14 may be bonded to each other to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q may be selected from halogen, a hydrocarbon group, an anionic ligand and a neutral ligand capable of coordinating with a lone electron pair, which may be selected in the same combination or different combination, and j is an integer of 1 to 4.

摘要翻译： 提供了一种新颖可用作烯烃聚合催化剂组分的过渡金属化合物，含有过渡金属化合物的烯烃聚合催化剂，以及使用聚合催化剂生产烯烃聚合物的方法。 过渡金属的特征在于由以下通式[I]表示：其中，R3是氢，R2选自烃基或含硅基团，R1和R4选自具有2〜20个碳原子的烃基 碳原子和含硅基团，选自氢，烃基和含硅基团的R5，R6，R7，R8，R9，R10，R11，R12，R13和R14各自可以相同 或彼此不同，并且R 5至R 14的相邻基团可以彼此键合形成环。 M是第4族过渡金属，Y是碳原子，Q可以选自卤素，烃基，阴离子配体和能够与单个电子对配位的中性配体，其可以以相同的组合或 不同的组合，j为1〜4的整数。

公开(公告)号：US07834204B2

公开(公告)日：2010-11-16

申请号：US11920767

申请日：2006-05-24

申请人： Munehito Funaya ,  Koji Endo ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

发明人： Munehito Funaya ,  Koji Endo ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

IPC分类号： C07F17/00 ,  B01J31/22 ,  C08F4/6592

CPC分类号： C07C13/567 ,  C07F7/081 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/15 ,  C08F210/06 ,  C08F210/14

摘要： Provided is a transition metal compound represented by the general formula [III]: wherein R23, R24, R25, R26, R27, and R28 are each independently selected from hydrogen, a hydrocarbon group, a silicon-containing group, a sulfur-containing group, an oxygen-containing group, a nitrogen-containing group, and a halogen-containing group, adjacent substituents of R23 to R28 are optionally bonded to each other to form a ring, M is a Group 4 transition metal, Y is carbon atom, Q is selected from halogen, a hydrocarbon group, an anionic ligand and a neutral ligand capable of coordinating with a lone electron pair, which is selected in the same combination or different combination, j is an integer of 1 to 4, and Z is a fluorenylidene group comprising a fluorene derivative formula [I] or formula [II]

摘要翻译： 提供由通式[III]表示的过渡金属化合物：其中R 23，R 24，R 25，R 26，R 27和R 28各自独立地选自氢，烃基，含硅基团，含硫基团 ，含氧基团，含氮基团和含卤素基团，R 23〜R 28的相邻取代基可以相互键合形成环，M为4族过渡金属，Y为碳原子， Q选自卤素，烃基，阴离子配体和能够与单电子对配位的中性配体，其以相同的组合或不同的组合选择，j为1〜4的整数，Z为 包含芴衍生物式[I]或式[II]的亚芴基

公开(公告)号：US20100190941A1

公开(公告)日：2010-07-29

申请号：US12753647

申请日：2010-04-02

申请人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

发明人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

IPC分类号： C08F2/00

CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/15 ,  C08F2500/03 ,  C08F210/06 ,  C08F2500/17 ,  C08F4/65927

摘要： Provided is a transition metal compound novel and useful as a catalyst component for olefin polymerization, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing an olefin polymer using the catalyst for polymerization. The transition metal is characterized by being represented by the following general formula [I]: wherein, R3 is hydrogen, R2 is selected from a hydrocarbon group or a silicon-containing group, R1 and R4 are selected from a hydrocarbon group having 2 to 20 carbon atoms and a silicon-containing group, each of R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14, which is selected from hydrogen, a hydrocarbon group and a silicon-containing group, may be same or different from each other, and adjacent groups from R5 to R14 may be bonded to each other to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q may be selected from halogen, a hydrocarbon group, an anionic ligand and a neutral ligand capable of coordinating with a lone electron pair, which may be selected in the same combination or different combination, and j is an integer of 1 to 4.

摘要翻译： 提供了一种新颖可用作烯烃聚合催化剂组分的过渡金属化合物，含有过渡金属化合物的烯烃聚合催化剂，以及使用聚合催化剂生产烯烃聚合物的方法。 过渡金属的特征在于由以下通式[I]表示：其中，R3是氢，R2选自烃基或含硅基团，R1和R4选自具有2〜20个碳原子的烃基 碳原子和含硅基团，选自氢，烃基和含硅基团的R5，R6，R7，R8，R9，R10，R11，R12，R13和R14各自可以相同 或彼此不同，并且R 5至R 14的相邻基团可以彼此键合形成环。 M是第4族过渡金属，Y是碳原子，Q可以选自卤素，烃基，阴离子配体和能够与单个电子对配位的中性配体，其可以以相同的组合或 不同的组合，j为1〜4的整数。

公开(公告)号：US20080038498A1

公开(公告)日：2008-02-14

申请号：US11793719

申请日：2005-12-22

申请人： Keita Itakura ,  Munehito Funaya ,  Ayako Kadosaka ,  Naritoshi Hirota ,  Hiroshi Nishikawa ,  Yuichi Yamamura ,  Shuji Matsumura ,  Satoshi Hashizume ,  Yoshio Sasaki

发明人： Keita Itakura ,  Munehito Funaya ,  Ayako Kadosaka ,  Naritoshi Hirota ,  Hiroshi Nishikawa ,  Yuichi Yamamura ,  Shuji Matsumura ,  Satoshi Hashizume ,  Yoshio Sasaki

IPC分类号： C08L23/12

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F210/06 ,  C08F210/16 ,  C08F255/00 ,  C08F255/02 ,  C08F297/08 ,  C08F297/083 ,  C08L23/083 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L51/06 ,  C08L53/00 ,  C08L2314/06 ,  Y10T428/1352 ,  C08F4/6492 ,  C08F4/65927 ,  C08L2666/24 ,  C08L2666/06 ,  C08L2666/08 ,  C08L2666/02 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/18

摘要： A propylene polymer which is constituted of 10 to 40 wt % room-temperature n-decane soluble part (Dsol) and 60 to 90 wt % room-temperature n-decane insoluble part (Dinsol), comprises skeletons derived from propylene (MP) and at least one kind of olefin (MX) selected from ethylene and C4 or more α-olefins, and satisfies all of the following requirements [1] to [5]. The polymer is characterized by having a high melting point and a high molecular weight and is suitable for use in producing various moldings therefrom. [1] the molecular weight distribution (Mw/Mn) of both Dsol and Dinsol as determined by GPC is 4.0 or less; [2] the melting point (Tm) of Dinsol is 156° C. or more; [3] the sum of the 2,1-bond content and the 1,3-bond content in Dinsol is 0.05 mol % or less; [4] the intrinsic viscosity [η] (dl/g) of Dsol satisfies the relationship 2.2

摘要翻译： 丙烯聚合物由10〜40重量％的室温正癸烷可溶部分（D> sol）和60〜90重量％的室温正癸烷不溶部分（D＆lt; 包括衍生自丙烯（MP）的骨架和选自乙烯和C 4或更多α-烯烃的至少一种烯烃（MX），并且满足以下所有要求[1]至[5] 。 聚合物的特征在于具有高熔点和高分子量，并且适用于从其生产各种模制品。 [1]通过GPC测定的D＆amp; S＆gt;和D＆amp; S＆gt;两者的分子量分布（Mw / Mn）为4.0以下; [2] D 的熔点（Tm）为156℃以上; [3] D insol中的2,1-键含量和1,3-键含量的总和为0.05摩尔％以下; [4] D 的特性粘度η（dl / g）满足关系式2.2 <η<6.0; 和[5]衍生自D insol中的烯烃（MX）的骨架的浓度为3.0重量％以下。

公开(公告)号：US07879960B2

公开(公告)日：2011-02-01

申请号：US11661504

申请日：2005-08-29

申请人： Munehito Funaya ,  Naritoshi Hirota ,  Mayumi Hiwara ,  Yasushi Tohi ,  Koji Kawai ,  Ryoji Mori ,  Masahiko Okamoto ,  Shigenobu Ikenaga ,  Hiromasa Marubayashi

发明人： Munehito Funaya ,  Naritoshi Hirota ,  Mayumi Hiwara ,  Yasushi Tohi ,  Koji Kawai ,  Ryoji Mori ,  Masahiko Okamoto ,  Shigenobu Ikenaga ,  Hiromasa Marubayashi

IPC分类号： C08F4/6592 ,  C08F10/06 ,  B01J31/22

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2/02 ,  C08F2500/17 ,  C08F2500/03 ,  C08F210/16 ,  C08F210/08

摘要： A high molecular weight propylene polymer exhibiting high stereoregularity (isotactic) and high position selectivity can be effectively produced by polymerizing at least one monomer selected from propylene, α-olefins and polyenes in the presence of a catalyst for olefin polymerization comprising: (A) a bridged metallocene compound represented by the General Formula [I] given in claims (diphenylmethylene(3-tert-butyl-5-ethyl-cyclopentadienyl)(fluorenyl)zirconium dichloride, etc.); and (B) one or more compound(s) selected from (b-1) an organoaluminumoxy compound (b-2) a compound which reacts with the bridged metallocene compound (A) to form an ion pair, and (b-3) an organoaluminum compound.

摘要翻译： 通过在烯烃聚合催化剂的存在下聚合选自丙烯，α-烯烃和多烯中的至少一种单体，可以有效地制备显示出高立构规整性（全同立构）和高位置选择性的高分子量丙烯聚合物，其包括：（A） 由权利要求中给出的通式[I]表示的桥连金属茂化合物（二苯基亚甲基（3-叔丁基-5-乙基 - 环戊二烯基）（芴基）二氯化锆等）; 和（B）选自（b-1）有机铝氧化合物（b-2）的一种或多种化合物与桥连金属茂化合物（A）反应形成离子对的化合物，和（b-3） 有机铝化合物。

公开(公告)号：US20080306234A1

公开(公告)日：2008-12-11

申请号：US12185543

申请日：2008-08-04

申请人： Shigenobu Ikenaga ,  Keiji Okada ,  Hiroshi Takayasu ,  Norihide Inoue ,  Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara ,  Shinichi Kojoh ,  Norio Kashiwa ,  Ryoji Mori

发明人： Shigenobu Ikenaga ,  Keiji Okada ,  Hiroshi Takayasu ,  Norihide Inoue ,  Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara ,  Shinichi Kojoh ,  Norio Kashiwa ,  Ryoji Mori

IPC分类号： C08F210/06 ,  C08F210/08

CPC分类号： C08F210/06 ,  C08F4/65927 ,  C08L23/142 ,  Y10S428/91 ,  Y10S526/943 ,  Y10T428/1328 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08F210/08 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/26

摘要： A propylene elastomer (PBER) comprising (a) 50 to 85 mol % of units derived from propylene, (b) 5 to 25 mol % of units derived from 1-butene and (c) 10 to 25 mol % of units derived from ethylene, and having a molar ratio of propylene content to ethylene content of from 89/11 to 70/30, and a modulus in tension (YM), as measured in accordance with JIS 6301, of not more than 40 Mpa.

摘要翻译： 丙烯弹性体（PBER），其包含（a）50〜85摩尔％的来自丙烯的单元，（b）5〜25摩尔％的来自1-丁烯的单元和（c）10〜25摩尔％来自乙烯的单元 丙烯含量与乙烯含量的摩尔比为89/11〜70/30，按照JIS 6301测定的拉伸模量（YM）为40Mpa以下。

公开(公告)号：US07678934B2

公开(公告)日：2010-03-16

申请号：US12185555

申请日：2008-08-04

申请人： Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara

发明人： Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara

IPC分类号： C07F17/00 ,  C07F7/00

CPC分类号： C08F210/06 ,  C08F4/65927 ,  C08L23/142 ,  Y10S428/91 ,  Y10S526/943 ,  Y10T428/1328 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08F210/08 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/26

摘要： A transition metal compound represented by the following formula (2a):

摘要翻译： 由下式（2a）表示的过渡金属化合物：

公开(公告)号：US20090043050A1

公开(公告)日：2009-02-12

申请号：US12185547

申请日：2008-08-04

申请人： Shigenobu Ikenaga ,  Keiji Okada ,  Hiroshi Hoya ,  Norihide Inoue ,  Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara ,  Shinichi Kojoh ,  Norio Kashiwa ,  Ryoji Mori

发明人： Shigenobu Ikenaga ,  Keiji Okada ,  Hiroshi Hoya ,  Norihide Inoue ,  Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara ,  Shinichi Kojoh ,  Norio Kashiwa ,  Ryoji Mori

IPC分类号： C08L23/20

CPC分类号： C08F210/06 ,  C08F4/65927 ,  C08L23/142 ,  Y10S428/91 ,  Y10S526/943 ,  Y10T428/1328 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08F210/08 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/26

摘要： A polypropylene composition containing a propylene/1-butene random copolymer which contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point of from 40 to 75° C. and a crystallization rate at 45° C. of 10 minutes or less, and satisfying the following relation, 146 exp (−0.022M)≧Tm≧125 exp (−0.032M), and an olefin catalyst for preparation thereof.

摘要翻译： 一种含丙烯-1-丁烯无规共聚物的聚丙烯组合物，其含有60〜90摩尔％的丙烯单元和10〜40摩尔％的1-丁烯单元，三重态全同立构规整度为85％以上97.5％以下， ，分子量分布为1至3，特性粘度为0.1至12dl / g，熔点为40至75℃，结晶速率为45℃为10分钟以下，以及 满足以下关系：146exp（-0.022M）> = Tm> = 125exp（-0.032M），以及用于其制备的烯烃催化剂。

公开(公告)号：US20060276607A1

公开(公告)日：2006-12-07

申请号：US10550017

申请日：2003-12-26

申请人： Shigenobu Ikenaga ,  Keiji Okada ,  Hiroshi Takayasu ,  Norihide Inoue ,  Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara ,  Shinichi Kojoh ,  Norio Kashiwa ,  Ryoji Mori

发明人： Shigenobu Ikenaga ,  Keiji Okada ,  Hiroshi Takayasu ,  Norihide Inoue ,  Naritoshi Hirota ,  Hiromu Kaneyoshi ,  Munehito Funaya ,  Koji Kawai ,  Nobuo Kawahara ,  Shinichi Kojoh ,  Norio Kashiwa ,  Ryoji Mori

IPC分类号： C08F110/14 ,  C08F210/04

CPC分类号： C08F210/06 ,  C08F4/65927 ,  C08L23/142 ,  Y10S428/91 ,  Y10S526/943 ,  Y10T428/1328 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08F210/08 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/26

摘要： The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120° C., and satisfies the following relation 146 exp(−0.022M)≧Tm≧125 exp(−0.032M) wherein Tm represents a melting point and M (mol %) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R1 and R3 is hydrogen, R2 and R4 are selected from a hydrocarbon group and silicon-containing group, R5 to R13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R5 to R12 may be linked to form a ring. R14 is an aryl group, and R13 and R14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.