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公开(公告)号：US4207213A
公开(公告)日：1980-06-10
申请号：US10459
申请日：1979-02-08
申请人： Jan G. Noltes , Gerard van Koten , Murray S. Cohen
发明人： Jan G. Noltes , Gerard van Koten , Murray S. Cohen
IPC分类号： B01J23/48 , B01J23/72 , B01J31/22 , B01J37/02 , B01J37/03 , B01J37/08 , C07C5/03 , C07C5/08 , C07C5/10 , B01J23/58
CPC分类号： B01J31/2295 , B01J23/48 , B01J23/72 , B01J31/2291 , B01J37/0215 , B01J37/031 , B01J37/086 , C07C5/03 , C07C5/08 , C07C5/10 , B01J2231/645 , B01J2231/646 , B01J2531/822 , B01J31/122 , C07C2523/46 , C07C2523/52 , C07C2523/72 , C07C2523/89
摘要： A process for the preparation of novel zero-valent rhodium catalysts. The catalysts are prepared by the reaction of a hydrocarbyl-lithium compound with a hydrocarbon-soluble complex of a rhodium halide and a ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. It is effective to catalyze the hydrogenation of organic compounds such as benzene, styrene and the like.
摘要翻译： 一种制备新型零价铑催化剂的方法。 催化剂通过烃基锂化合物与卤化铑和配体的烃溶性络合物的反应制备。 如果需要，催化剂可以沉积在载体如氧化铝或二氧化硅上。 催化苯，苯乙烯等有机化合物的氢化是有效的。
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公开(公告)号：US4152303A
公开(公告)日：1979-05-01
申请号：US827278
申请日：1977-08-24
申请人： Murray S. Cohen , Jan G. Noltes , Gerard VAN Koten
发明人： Murray S. Cohen , Jan G. Noltes , Gerard VAN Koten
IPC分类号： C07C5/02 , B01J23/48 , B01J23/72 , B01J31/22 , B01J37/02 , B01J37/03 , B01J37/08 , C07B61/00 , C07C1/00 , C07C5/03 , C07C5/08 , C07C5/10 , C07C13/18 , C07C67/00 , B01J23/58 , B01J23/52
CPC分类号： C07C5/10 , B01J23/48 , B01J23/72 , B01J31/2295 , B01J37/0215 , B01J37/031 , B01J37/086 , C07C5/03 , C07C5/08 , B01J2231/645 , B01J2231/646 , B01J2531/10 , B01J2531/11 , B01J2531/16 , B01J2531/18 , B01J2531/80 , B01J2531/822 , B01J31/1616 , C07C2101/12 , C07C2523/46 , C07C2523/52 , C07C2523/72 , C07C2523/89
摘要： A process for the preparation of novel zero-valent metal catalysts. The catalysts are prepared by the reaction of an organic metal cluster compound wherein one of the metals is lithium with a complex of a metal halide and a ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. It is effective to catalyze the hydrogenation of organic compounds such as benzene, styrene and the like.
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公开(公告)号：US4243824A
公开(公告)日：1981-01-06
申请号：US88242
申请日：1979-10-25
申请人： Jan G. Noltes , Gerard van Koten , Murray S. Cohen
发明人： Jan G. Noltes , Gerard van Koten , Murray S. Cohen
CPC分类号： C07C5/10 , B01J31/2291 , B01J31/2295 , C07C5/03 , C07C5/08 , B01J2231/645 , B01J2231/646 , B01J2531/822 , C07C2531/22
摘要： A process for the preparation of novel zero-valent rhodium catalysts. The catalysts are prepared by the reaction of a hydrocarbyl-lithium compound with a hydrocarbon-soluble complex of a rhodium halide and a ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. It is effective to catalyze the hydrogenation of organic compounds such as benzene, styrene and the like.
摘要翻译： 一种制备新型零价铑催化剂的方法。 催化剂通过烃基锂化合物与卤化铑和配体的烃溶性络合物的反应制备。 如果需要，催化剂可以沉积在载体如氧化铝或二氧化硅上。 催化苯，苯乙烯等有机化合物的氢化是有效的。
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公开(公告)号：US4205191A
公开(公告)日：1980-05-27
申请号：US962268
申请日：1978-11-20
申请人： Murray S. Cohen , Jan G. Noltes , Gerard van Koten
发明人： Murray S. Cohen , Jan G. Noltes , Gerard van Koten
IPC分类号： C07C5/02 , B01J23/48 , B01J23/72 , B01J31/22 , B01J37/02 , B01J37/03 , B01J37/08 , C07B61/00 , C07C1/00 , C07C5/03 , C07C5/08 , C07C5/10 , C07C13/18 , C07C67/00 , C07C5/04 , C07C5/06
CPC分类号： C07C5/10 , B01J23/48 , B01J23/72 , B01J31/2295 , B01J37/0215 , B01J37/031 , B01J37/086 , C07C5/03 , C07C5/08 , B01J2231/645 , B01J2231/646 , B01J2531/10 , B01J2531/11 , B01J2531/16 , B01J2531/18 , B01J2531/80 , B01J2531/822 , B01J31/1616 , C07C2101/12 , C07C2523/46 , C07C2523/52 , C07C2523/72 , C07C2523/89
摘要： A process for the preparation of novel zero-valent metal catalysts. The catalysts are prepared by the reaction of an organic metal cluster compound wherein one of the metals is lithium with a complex of a metal halide and a ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. It is effective to catalyze the hydrogenation of organic compounds such as benzene, styrene and the like.
摘要翻译： 一种新型零价金属催化剂的制备方法。 催化剂通过有机金属簇化合物的反应制备，其中金属之一是锂与金属卤化物和配体的络合物。 如果需要，催化剂可以沉积在载体如氧化铝或二氧化硅上。 催化苯，苯乙烯等有机化合物的氢化是有效的。
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公开(公告)号：US4243604A
公开(公告)日：1981-01-06
申请号：US18373
申请日：1979-03-07
CPC分类号： C07F1/00
摘要： A process for the preparation of novel aliphatic metal cluster compounds. The cluster compounds are prepared by reacting an alkyllithium such as n-butyllithium with a Group Ib metal halide or Group Ib metal halide complex such as gold chloride.triphenyl-phosphine. The resulting cluster compound is relatively stable.
摘要翻译： 一种制备新型脂族金属簇化合物的方法。 簇化合物通过使正丁基锂等烷基锂与Ib族金属卤化物或Ib族金属卤化物络合物例如氯化金三苯基膦反应来制备。 所得到的簇化合物相对稳定。
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公开(公告)号：US4222898A
公开(公告)日：1980-09-16
申请号：US18372
申请日：1979-03-07
摘要： A process for the preparation of novel zero-valent mixed catalysts. The catalysts are prepared by the reaction of an organic metal cluster compound wherein one of the metals is lithium with a complex of a rhodium halide and an olefinic hydrocarbon ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. It is effective to catalyze the hydrogenation of organic compounds such as benzene, styrene and the like.
摘要翻译： 一种新型零价混合催化剂的制备方法。 催化剂通过有机金属簇化合物的反应制备，其中一种金属是锂，与卤化铑和烯烃配体的络合物。 如果需要，催化剂可以沉积在载体如氧化铝或二氧化硅上。 催化苯，苯乙烯等有机化合物的氢化是有效的。
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公开(公告)号：US4228312A
公开(公告)日：1980-10-14
申请号：US18374
申请日：1979-03-07
摘要： A process for the hydrogenation of certain aromatic, olefinic and acetylenic compounds. The process is catalyzed by a zero-valent mixed metal catalyst which is in turn prepared by the reaction of an organic metal cluster compound wherein one of the metals is lithium with a complex of rhodium halide and an olefinic hydrocarbon ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. The hydrogenation process can, in many instances, be carried out under ordinary conditions, i.e., at room temperature and atmospheric pressure.
摘要翻译： 某些芳族，烯属和炔属化合物氢化的方法。 该方法由零价混合金属催化剂催化，其又通过有机金属簇化合物的反应制备，其中金属之一为锂，卤化铱和烯烃配体的络合物。 如果需要，催化剂可以沉积在载体如氧化铝或二氧化硅上。 在许多情况下，氢化方法可以在常规条件下，即在室温和大气压下进行。
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