公开(公告)号：US20210408583A1

公开(公告)日：2021-12-30

申请号：US17447305

申请日：2021-09-10

申请人： NAGOYA INSTITUTE OF TECHNOLOGY ,  NGK INSULATORS, LTD.

发明人： Reona MIYAZAKI ,  Harunobu ONISHI ,  Satoshi OZAKI ,  Toshihiro YOSHIDA ,  Yuji KATSUDA ,  Yosuke SATO ,  En YAGI

IPC分类号： H01M10/0562 ,  H01G11/56 ,  H01G11/84

摘要： Provided is a solid electrolyte which is identified as 3LiOH.Li2SO4 by diffractometry. The solid electrolyte further contains boron.

公开(公告)号：US20230420734A1

公开(公告)日：2023-12-28

申请号：US18461757

申请日：2023-09-06

申请人： NGK INSULATORS, LTD. ,  NAGOYA INSTITUTE OF TECHNOLOGY

发明人： Yosuke SATO ,  En YAGI ,  Satoshi OZAKI ,  Toshihiro YOSHIDA ,  Yuji KATSUDA ,  Mizuki HIROSE ,  Reona MIYAZAKI

IPC分类号： H01M10/0562

CPC分类号： H01M10/0562 ,  H01M2300/0068

摘要： A solid electrolyte is composed primarily of a component expressed by a composition formula of Lia+dMbXcAeOf by using values a to f that are greater than 0, where M is an element serving as a trivalent cation, X is a halogen element, and A is a sulfur element or a phosphorus element, wherein 0.8c≤(a+3b)≤1.2c and 1.6f≤(d+n×e)≤2.4f are satisfied, where when A is a sulfur element, n is 4 or 6, and when A is a phosphorus element, n is 5.

公开(公告)号：US20200343585A1

公开(公告)日：2020-10-29

申请号：US16923808

申请日：2020-07-08

申请人： NAGOYA INSTITUTE OF TECHNOLOGY ,  NGK INSULATORS, LTD.

发明人： Reona MIYAZAKI ,  Toshihiro YOSHIDA ,  Satoshi OZAKI ,  Yosuke SATO ,  Yuji KATSUDA

IPC分类号： H01M10/0562 ,  C01D15/06 ,  C01D15/02

摘要： Provided is a solid electrolyte which contains a composition expressed by 3LiOH.Li2SO4. The solid electrolyte has a lithium ion conductivity of 0.1x10−6 S/cm or more at 25° C. and an activation energy of 0.6 eV or more.

公开(公告)号：US20210408584A1

公开(公告)日：2021-12-30

申请号：US17447313

申请日：2021-09-10

申请人： NGK INSULATORS, LTD.

发明人： Harunobu ONISHI ,  Satoshi OZAKI ,  Toshihiro YOSHIDA ,  Yuji KATSUDA ,  Yosuke SATO ,  En YAGI

IPC分类号： H01M10/0562 ,  H01M4/131 ,  H01M10/0525

摘要： Provided is an all-solid-state secondary battery including a solid electrolyte which is identified as 3LiOH.Li2SO4 by X-ray diffraction. The solid electrolyte further contains boron.

公开(公告)号：US20200266494A1

公开(公告)日：2020-08-20

申请号：US16865462

申请日：2020-05-04

申请人： NGK INSULATORS, LTD.

发明人： Yukihisa TAKEUCHI ,  Iwao OWADA ,  Yukinobu YURA ,  Yosuke SATO ,  Toshihiro YOSHIDA ,  Yuji KATSUDA

IPC分类号： H01M10/0585 ,  H01M4/485 ,  H01M10/0562 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

摘要： Provided is a secondary battery including: a positive electrode plate composed of an inorganic material containing a positive electrode active material in an oxide form and having a thickness of 25 μm or more; a negative electrode plate composed of an inorganic material containing a negative electrode active material in an oxide form and having a thickness of 25 μm or more; and an inorganic solid electrolyte, the secondary battery being charged and discharged at a temperature of 100° C. or higher.

公开(公告)号：US20140290863A1

公开(公告)日：2014-10-02

申请号：US14246639

申请日：2014-04-07

申请人： NGK Insulators, Ltd.

发明人： Morimichi WATANABE ,  Asumi JINDO ,  Yuji KATSUDA ,  Yosuke SATO ,  Yoshinori ISODA ,  Atsushi WATANABE

IPC分类号： H01L21/683

CPC分类号： H01L21/6831 ,  C04B35/053 ,  C04B35/58 ,  C04B2235/3217 ,  C04B2235/3222 ,  C04B2235/3865 ,  C04B2235/6586 ,  C04B2235/76 ,  C04B2235/77 ,  C04B2235/80 ,  C04B2235/9607 ,  H01L21/6833

摘要： A ceramic member 30 according to the present invention includes a ceramic base 32, which contains a solid solution Mg(Al)O(N) in which Al and N components are dissolved in magnesium oxide as the main phase, and an electrode 34 disposed on a portion of the ceramic base 32 and containing at least one of nitrides, carbides, carbonitrides, and metals as an electrode component. The ceramic base 32 may have an XRD peak of a (111), (200), or (220) plane of Mg(Al)O(N) measured using a CiKα ray at 2θ=36.9 to 39, 42.9 to 44.8, or 62.3 to 65.2 degrees, respectively, between a magnesium oxide cubic crystal peak and an aluminum nitride cubic crystal peak.

摘要翻译： 根据本发明的陶瓷构件30包括陶瓷基底32，其包含其中Al和N成分溶解在作为主相的氧化镁中的固溶体Mg（Al）O（N）和设置在 陶瓷基体32的一部分并且包含氮化物，碳化物，碳氮化物和金属中的至少一种作为电极组分。 陶瓷基底32可以具有使用2θ时的CiKα射线测量的（111），（200）或（220）面的Mg（Al）O（N）的XRD峰; = 36.9〜39,42.9〜44.8， 或分别为氧化镁立方晶体晶体和氮化铝立方晶体晶体之间的62.3〜65.2度。

公开(公告)号：US20210009434A1

公开(公告)日：2021-01-14

申请号：US17022532

申请日：2020-09-16

申请人： NGK INSULATORS, LTD.

发明人： Miyuki KOJIMA ,  Keita MIYANISHI ,  Yosuke SATO ,  Yuji KATSUDA

IPC分类号： C01D15/04 ,  H01M10/0562 ,  H01M10/0525 ,  H01M4/1315 ,  H01M4/136

摘要： A lithium ion conductive material has a composition formula of Lia(OH)bFcBr, where 1.8≤a≤2.3, b=a−c−1, 0.01≤c≤0.11, and includes an antiperovskite-type crystal phase. Preferably, the lithium ion conductive material further includes a layered antiperovskite-type crystal phase. More preferably, 0≤B/(A+B)≤0.2 is satisfied, where A is the peak intensity in the vicinity of 2θ=31.2° in the X-ray diffractometry using Cu-Kα ray and B is the peak intensity in the vicinity of 2θ=30.2°.

公开(公告)号：US20200280047A1

公开(公告)日：2020-09-03

申请号：US16876513

申请日：2020-05-18

申请人： NGK INSULATORS, LTD.

发明人： Kei TANAKA ,  Miyuki KOJIMA ,  Keita MIYANISHI ,  Yosuke SATO ,  Yuji KATSUDA ,  Yukihisa TAKEUCHI

IPC分类号： H01M4/131 ,  H01M4/1391 ,  H01M4/525 ,  H01M4/485 ,  H01M10/0562 ,  H01M10/0585 ,  H01M10/0525 ,  H01M4/62 ,  H01M4/04

摘要： There is provided an all-solid-state lithium battery including: a positive-electrode plate composed of a lithium complex oxide sintered body having a layered rock-salt structure; a solid electrolyte layer composed of a lithium-ion-conductive antiperovskite material; a negative-electrode plate containing Ti and permitting intercalation and deintercalation of lithium ions at 0.4 (vs. Li/Li+) V or more; a positive-electrode current collecting layer provided on a face, remote from the solid electrolyte layer, of the positive-electrode plate; a negative-electrode current collecting layer provided on a face, remote from the solid electrolyte layer, of the negative-electrode plate; a positive-electrode covering metal membrane provided at an interface between the positive-electrode plate and the solid electrolyte layer; and a negative-electrode covering metal membrane provided at an interface between the negative-electrode plate and the solid electrolyte layer.

公开(公告)号：US20200259217A1

公开(公告)日：2020-08-13

申请号：US16864550

申请日：2020-05-01

申请人： NGK INSULATORS, LTD.

发明人： Yukinobu YURA ,  Yukihisa TAKEUCHI ,  Yosuke SATO ,  Toshihiro YOSHIDA ,  Yuji KATSUDA

IPC分类号： H01M10/0585 ,  H01M10/0525 ,  H01M10/0562 ,  H01M2/16 ,  H01M4/485

摘要： Provided is an all-solid lithium battery including: a low-angle oriented positive electrode plate that is a lithium complex oxide sintered plate having a porosity of 10 to 50%; a negative electrode plate containing Ti and capable of intercalating and deintercalating lithium ions at 0.4 V or higher (vs. Li/Li+); and a solid electrolyte having a melting point lower than the melting point or pyrolytic temperature of the oriented positive electrode plate or the negative electrode plate, wherein at least 30% of pores in the oriented positive electrode plate is filled with the solid electrolyte in an observation of a cross-section perpendicular to a main face of the oriented positive electrode plate.

公开(公告)号：US20150225297A1

公开(公告)日：2015-08-13

申请号：US14692922

申请日：2015-04-22

申请人： NGK Insulators, Ltd.

发明人： Yosuke SATO ,  Yoshinori ISODA ,  Yuji KATSUDA

IPC分类号： C04B35/04 ,  C23C14/34

CPC分类号： C04B35/04 ,  C04B35/053 ,  C04B2235/3203 ,  C04B2235/3286 ,  C04B2235/76 ,  C04B2235/77 ,  C23C14/08 ,  C23C14/3414 ,  G11B5/3909 ,  H01L21/02175 ,  H01L21/02194 ,  H01L21/02266 ,  H01L43/10 ,  H01L43/12

摘要： The present invention provides a ceramic material comprising magnesium, gallium, lithium, and oxygen as main components, wherein a crystal phase of a solid solution attained by dissolving gallium oxide and lithium oxide in magnesium oxide is a main phase. An XRD peak of a (200) plane of the solid solution with CuKα rays preferably appears at 2θ=42.91° or more which is larger than an angle at which a peak of a Cubic crystal of magnesium oxide appears, more preferably appears at 2θ=42.91° to 43.28°, and further preferably appears at 2θ=42.91° to 43.02°. In the ceramic material, a molar ratio Li/Ga of Li to Ga is preferably 0.80 or more and 1.20 or less.

摘要翻译： 本发明提供一种以镁，镓，锂和氧为主要成分的陶瓷材料，其中通过将氧化镓和氧化锂溶解在氧化镁中而获得的固溶体的结晶相是主相。 具有CuKα射线的固溶体（200）平面的XRD峰优选出现在2θ= 42.91°以上，其大于出现氧化镁立方晶体的峰的角度，更优选出现在2θ ; = 42.91°至43.28°，进一步优选出现在2θ= 42.91°至43.02°。 在陶瓷材料中，Li与Ga的Li / Ga摩尔比优选为0.80以上且1.20以下。