公开(公告)号：US20230420734A1

公开(公告)日：2023-12-28

申请号：US18461757

申请日：2023-09-06

Applicant: NGK INSULATORS, LTD. ,  NAGOYA INSTITUTE OF TECHNOLOGY

Inventor： Yosuke SATO ,  En YAGI ,  Satoshi OZAKI ,  Toshihiro YOSHIDA ,  Yuji KATSUDA ,  Mizuki HIROSE ,  Reona MIYAZAKI

IPC: H01M10/0562

CPC classification number: H01M10/0562 ,  H01M2300/0068

Abstract: A solid electrolyte is composed primarily of a component expressed by a composition formula of Lia+dMbXcAeOf by using values a to f that are greater than 0, where M is an element serving as a trivalent cation, X is a halogen element, and A is a sulfur element or a phosphorus element, wherein 0.8c≤(a+3b)≤1.2c and 1.6f≤(d+n×e)≤2.4f are satisfied, where when A is a sulfur element, n is 4 or 6, and when A is a phosphorus element, n is 5.

公开(公告)号：US20210009434A1

公开(公告)日：2021-01-14

申请号：US17022532

申请日：2020-09-16

Applicant: NGK INSULATORS, LTD.

Inventor： Miyuki KOJIMA ,  Keita MIYANISHI ,  Yosuke SATO ,  Yuji KATSUDA

IPC: C01D15/04 ,  H01M10/0562 ,  H01M10/0525 ,  H01M4/1315 ,  H01M4/136

Abstract: A lithium ion conductive material has a composition formula of Lia(OH)bFcBr, where 1.8≤a≤2.3, b=a−c−1, 0.01≤c≤0.11, and includes an antiperovskite-type crystal phase. Preferably, the lithium ion conductive material further includes a layered antiperovskite-type crystal phase. More preferably, 0≤B/(A+B)≤0.2 is satisfied, where A is the peak intensity in the vicinity of 2θ=31.2° in the X-ray diffractometry using Cu-Kα ray and B is the peak intensity in the vicinity of 2θ=30.2°.

公开(公告)号：US20200343585A1

公开(公告)日：2020-10-29

申请号：US16923808

申请日：2020-07-08

Applicant: NAGOYA INSTITUTE OF TECHNOLOGY ,  NGK INSULATORS, LTD.

Inventor： Reona MIYAZAKI ,  Toshihiro YOSHIDA ,  Satoshi OZAKI ,  Yosuke SATO ,  Yuji KATSUDA

IPC: H01M10/0562 ,  C01D15/06 ,  C01D15/02

Abstract: Provided is a solid electrolyte which contains a composition expressed by 3LiOH.Li2SO4. The solid electrolyte has a lithium ion conductivity of 0.1x10−6 S/cm or more at 25° C. and an activation energy of 0.6 eV or more.

公开(公告)号：US20200280047A1

公开(公告)日：2020-09-03

申请号：US16876513

申请日：2020-05-18

Applicant: NGK INSULATORS, LTD.

Inventor： Kei TANAKA ,  Miyuki KOJIMA ,  Keita MIYANISHI ,  Yosuke SATO ,  Yuji KATSUDA ,  Yukihisa TAKEUCHI

IPC: H01M4/131 ,  H01M4/1391 ,  H01M4/525 ,  H01M4/485 ,  H01M10/0562 ,  H01M10/0585 ,  H01M10/0525 ,  H01M4/62 ,  H01M4/04

Abstract: There is provided an all-solid-state lithium battery including: a positive-electrode plate composed of a lithium complex oxide sintered body having a layered rock-salt structure; a solid electrolyte layer composed of a lithium-ion-conductive antiperovskite material; a negative-electrode plate containing Ti and permitting intercalation and deintercalation of lithium ions at 0.4 (vs. Li/Li+) V or more; a positive-electrode current collecting layer provided on a face, remote from the solid electrolyte layer, of the positive-electrode plate; a negative-electrode current collecting layer provided on a face, remote from the solid electrolyte layer, of the negative-electrode plate; a positive-electrode covering metal membrane provided at an interface between the positive-electrode plate and the solid electrolyte layer; and a negative-electrode covering metal membrane provided at an interface between the negative-electrode plate and the solid electrolyte layer.

公开(公告)号：US20200259217A1

公开(公告)日：2020-08-13

申请号：US16864550

申请日：2020-05-01

Applicant: NGK INSULATORS, LTD.

Inventor： Yukinobu YURA ,  Yukihisa TAKEUCHI ,  Yosuke SATO ,  Toshihiro YOSHIDA ,  Yuji KATSUDA

IPC: H01M10/0585 ,  H01M10/0525 ,  H01M10/0562 ,  H01M2/16 ,  H01M4/485

Abstract: Provided is an all-solid lithium battery including: a low-angle oriented positive electrode plate that is a lithium complex oxide sintered plate having a porosity of 10 to 50%; a negative electrode plate containing Ti and capable of intercalating and deintercalating lithium ions at 0.4 V or higher (vs. Li/Li+); and a solid electrolyte having a melting point lower than the melting point or pyrolytic temperature of the oriented positive electrode plate or the negative electrode plate, wherein at least 30% of pores in the oriented positive electrode plate is filled with the solid electrolyte in an observation of a cross-section perpendicular to a main face of the oriented positive electrode plate.

公开(公告)号：US20150225297A1

公开(公告)日：2015-08-13

申请号：US14692922

申请日：2015-04-22

Applicant: NGK Insulators, Ltd.

Inventor： Yosuke SATO ,  Yoshinori ISODA ,  Yuji KATSUDA

IPC: C04B35/04 ,  C23C14/34

CPC classification number: C04B35/04 ,  C04B35/053 ,  C04B2235/3203 ,  C04B2235/3286 ,  C04B2235/76 ,  C04B2235/77 ,  C23C14/08 ,  C23C14/3414 ,  G11B5/3909 ,  H01L21/02175 ,  H01L21/02194 ,  H01L21/02266 ,  H01L43/10 ,  H01L43/12

Abstract: The present invention provides a ceramic material comprising magnesium, gallium, lithium, and oxygen as main components, wherein a crystal phase of a solid solution attained by dissolving gallium oxide and lithium oxide in magnesium oxide is a main phase. An XRD peak of a (200) plane of the solid solution with CuKα rays preferably appears at 2θ=42.91° or more which is larger than an angle at which a peak of a Cubic crystal of magnesium oxide appears, more preferably appears at 2θ=42.91° to 43.28°, and further preferably appears at 2θ=42.91° to 43.02°. In the ceramic material, a molar ratio Li/Ga of Li to Ga is preferably 0.80 or more and 1.20 or less.

Abstract translation: 本发明提供一种以镁，镓，锂和氧为主要成分的陶瓷材料，其中通过将氧化镓和氧化锂溶解在氧化镁中而获得的固溶体的结晶相是主相。 具有CuKα射线的固溶体（200）平面的XRD峰优选出现在2θ= 42.91°以上，其大于出现氧化镁立方晶体的峰的角度，更优选出现在2θ ; = 42.91°至43.28°，进一步优选出现在2θ= 42.91°至43.02°。 在陶瓷材料中，Li与Ga的Li / Ga摩尔比优选为0.80以上且1.20以下。

公开(公告)号：US20150184030A1

公开(公告)日：2015-07-02

申请号：US14561449

申请日：2014-12-05

Applicant: NGK Insulators, Ltd.

Inventor： Masashi GOTO ,  Noboru NISHIMURA ,  Yuji KATSUDA

IPC: C09J1/00 ,  C09J5/06

CPC classification number: B32B18/00 ,  B32B7/12 ,  B32B2250/02 ,  B32B2255/20 ,  B32B2307/704 ,  C04B37/005 ,  C04B2237/08 ,  C04B2237/366 ,  C04B2237/60 ,  C09J1/00 ,  C09J5/06 ,  C09J2400/123 ,  Y10T428/31536

Abstract: A first bonding material composition according to the present invention is a bonding material composition used when aluminum nitride sintered bodies containing a rare-earth metal oxide are bonded to each other, in which the bonding immaterial composition contains, in addition, to an O element-containing aluminum nitride raw material, (a) as a fluorine compound, at least one of a fluorine compound of an alkaline-earth metal and a fluorine compound of a rare-earth metal, or (b) as a fluorine compound, at least one of a fluorine compound of an alkaline-earth metal and a fluorine compound of a rare-earth metal, and a rare-earth metal oxide.

Abstract translation: 根据本发明的第一粘合材料组合物是当含有稀土金属氧化物的氮化铝烧结体彼此结合时使用的粘结材料组合物，其中所述粘合非材料组合物另外含有O元素 - 含有氮化铝原料的（a）作为氟化合物，至少一种碱土金属的氟化合物和稀土金属的氟化合物，或（b）作为氟化合物的至少一种，至少一种 的碱土金属的氟化合物和稀土金属的氟化合物和稀土金属氧化物。

公开(公告)号：US20130235507A1

公开(公告)日：2013-09-12

申请号：US13869285

申请日：2013-04-24

Applicant: NGK INSULATORS, LTD.

Inventor： Kenichiro AIKAWA ,  Morimichi WATANABE ,  Asumi JINDO ,  Yuji KATSUDA ,  Yosuke SATO ,  Yoshinori ISODA

IPC: H01L21/683

CPC classification number: H01L21/6833 ,  C04B35/58 ,  C04B35/581 ,  C04B35/6261 ,  C04B35/62655 ,  C04B35/645 ,  C04B2235/3206 ,  C04B2235/3217 ,  C04B2235/3222 ,  C04B2235/3865 ,  C04B2235/3869 ,  C04B2235/5445 ,  C04B2235/762 ,  C04B2235/77 ,  C04B2235/80 ,  C04B2235/96 ,  C04B2235/9669 ,  C23C14/3414

Abstract: Electrostatic chucks (1A to 1F) are provided with: susceptors (11A to 11F) having an attracting surface (11a) that attracts and holds semiconductors; and electrostatic chuck electrodes (4) that are embedded in the susceptors. The susceptors are provided with plate-shape bodies (3) and surface corrosion-resistant layers (2) that face the attracting surface. The surface corrosion-resistant layer (2) is made from a ceramic material having magnesium, aluminum, oxygen and nitrogen as main components, the ceramic material having, as a main phase, an MgO—AlN solid solution crystal phase obtained by dissolving aluminum nitride in magnesium oxide.

Abstract translation: 静电吸盘（1A〜1F）设有：具有吸引并保持半导体的吸附面（11a）的感受体（11A〜11F） 和静电吸盘电极（4）。 基座设有板状体（3）和面向吸引面的表面耐腐蚀层（2）。 表面耐腐蚀层（2）由具有镁，铝，氧和氮的陶瓷材料作为主要成分，陶瓷材料以MgO-AlN固溶体结晶相为主要成分，所述MgO-AlN固溶体结晶相通过将氮化铝 在氧化镁中。

公开(公告)号：US20230299285A1

公开(公告)日：2023-09-21

申请号：US18323608

申请日：2023-05-25

Applicant: NGK INSULATORS, LTD.

Inventor： Tsutomu NISHIZAKI ,  Mizuki HIROSE ,  Yoshimasa KOBAYASHI ,  Yuji KATSUDA

IPC: H01M4/525 ,  H01M10/0525 ,  H01M4/505 ,  H01M10/0562 ,  H01M4/58

CPC classification number: H01M4/525 ,  H01M4/505 ,  H01M4/5825 ,  H01M10/0525 ,  H01M10/0562 ,  H01M2004/028

Abstract: There is provided a positive electrode active material containing a lithium composite oxide having a layered rock salt structure containing Li, Ni, Co and Mn, and further containing at least one additive selected from Li3BO3, Li3PO4 and Li2SO4.

公开(公告)号：US20200350196A1

公开(公告)日：2020-11-05

申请号：US16934222

申请日：2020-07-21

Applicant: NGK INSULATORS, LTD.

Inventor： Asumi NAGAI ,  Katsuhiro INOUE ,  Yuji KATSUDA

IPC: H01L21/683 ,  B28B1/00 ,  C04B35/117 ,  C04B35/565

Abstract: A method of manufacturing a composite sintered body includes a step (Step S11) of molding mixed powder in which Al2O3, SiC, and MgO are mixed, into a green body having a predetermined shape and a step (Step S12) of generating a composite sintered body by sintering the green body. Then, in Step S11, the ratio of SiC to the mixed powder is not lower than 4.0 weight percentage and not higher than 13.0 weight percentage. Further, the purity of Al2O3 in Step S11 is not lower than 99.9%. It is thereby possible to suppress the abnormal grain growth of Al2O3 and suitably manufacture a composite sintered body having high relative dielectric constant and withstand voltage, and low tan δ.