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公开(公告)号：US10125414B2
公开(公告)日：2018-11-13
申请号：US15606254
申请日：2017-05-26
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Atsuo Shimizu , Masanori Matsuno , Masaya Yamamoto , Hirofumi Taketsu
IPC: C23C2/06 , C23C2/26 , C23C22/62 , C23C18/48 , C23C2/40 , B32B15/01 , C23F11/06 , C22C18/00 , C22C18/04 , C23C22/36 , C23C22/78 , C22C21/10 , C23C2/12 , C23C2/28
Abstract: A method of producing a hot-dip Zn alloy-plated steel sheet includes: dipping a base steel sheet in a hot-dip Zn alloy plating bath to form a hot-dip Zn alloy plating layer on a surface of the base steel sheet; and contacting an aqueous solution containing a water-soluble corrosion inhibitor with a surface of the hot-dip Zn alloy plating layer to cool the base steel sheet and the hot-dip Zn alloy plating layer having a raised temperature through formation of the hot-dip Zn alloy plating layer. A temperature of the surface of the hot-dip Zn alloy plating layer when the aqueous solution is to be contacted with the surface of the hot-dip Zn alloy plating layer is equal to or more than 100° C. and equal to or less than a solidifying point of the plating layer. The aqueous solution containing the water-soluble corrosion inhibitor satisfies the Equation [{(Z0−Z1)/Z0}100≥20].
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公开(公告)号：US10202676B2
公开(公告)日：2019-02-12
申请号：US14748279
申请日：2015-06-24
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Atsuo Shimizu , Masanori Matsuno , Masaya Yamamoto , Hirofumi Taketsu
IPC: B05D1/00 , D06B19/00 , C23C2/40 , C23C2/06 , C22C18/00 , C22C18/04 , C23C22/68 , C23C2/28 , B32B15/01 , C23C2/26 , C23C22/24 , C23C22/36 , C23C22/42 , C23C22/78
Abstract: A hot-dip Zn alloy plating layer is formed on a surface of a base steel sheet by immersing the base steel sheet in a hot-dip Zn alloy plating bath containing Al and Mg. An aqueous solution containing a polyatomic ion including Si4+ and/or a polyatomic ion including Cr6+ is then contacted with a surface of the hot-dip Zn alloy plating layer. All of the aqueous solution coating the surface of the hot-dip Zn alloy plating layer is removed with a squeeze roller. The aqueous solution contains the polyatomic ion in a concentration of 0.01 g/L or more in terms of atom of Si and Cr. A surface temperature of the hot-dip Zn alloy plating layer when the aqueous solution is contacted with the surface of the hot-dip Zn alloy plating layer is 100° C. or above and equal to or less than a solidifying point of the plating layer.
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公开(公告)号：US09598759B2
公开(公告)日：2017-03-21
申请号：US14396192
申请日：2013-04-23
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Tadashi Nakano , Masaya Yamamoto , Hirofumi Taketsu
IPC: C23C8/10 , C23C22/53 , C23C8/02 , C23C8/16 , C23C2/06 , C22C18/00 , C22C18/04 , C23C28/00 , C23C2/26 , C23C8/18 , B32B15/01 , C22C38/00 , C22C1/02 , C23C2/12 , C23C8/80 , C23C28/02
CPC classification number: C23C8/16 , B32B15/013 , C22C1/02 , C22C18/00 , C22C18/04 , C22C38/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C8/02 , C23C8/18 , C23C8/80 , C23C22/42 , C23C28/00 , C23C28/02 , C23C28/321 , C23C28/3225 , C23C28/34 , C23C28/345
Abstract: The present invention pertains to a method for producing a black-plated steel sheet capable of being blackened in a short amount of time, and exhibiting an excellent ability to maintain a black appearance after processing. As an original sheet, the sheet used is a Zn-plating steel sheet which contains molten Al and Mg and has a Zn-plating layer containing molten Al and Mg, containing Al in the amount of 0.1-22.0 mass %, inclusive, and containing Mg in the amount of 0.1-1.5 mass %, inclusive. The plating layer is blackened by causing the molten-plating steel sheet to contact water vapor inside a tightly sealed container. When doing so, the concentration of oxygen inside the tightly sealed container is 13% or less.
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公开(公告)号：US09890461B2
公开(公告)日：2018-02-13
申请号：US14922341
申请日：2015-10-26
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Masanori Matsuno , Koichiro Ueda , Masaya Yamamoto , Hirofumi Taketsu
IPC: B05D1/02 , B05D1/04 , B05D1/06 , B05D1/08 , B05D1/12 , B05D3/00 , B05D7/02 , B05D7/24 , C23C28/00 , C23C22/36 , B32B15/01 , C09D5/08 , C23C22/34 , C23C22/44 , C23C22/78
CPC classification number: C23C28/00 , B32B15/01 , C09D5/082 , C23C22/34 , C23C22/36 , C23C22/361 , C23C22/364 , C23C22/44 , C23C22/78 , C23C2222/20
Abstract: The present disclosure relates to a chemically treated zinc-based plated steel sheet that is superior in weather resistance, water resistance, blackening resistance and film adhesion. A chemical conversion film having a thickness 0.5-10 μm is formed by coating and drying a chemical treatment solution on a surface of an aluminum-containing zinc-based alloy plated steel sheet. The chemical treatment solution contains a fluororesin containing 0.05-5% by weight of a hydrophilic functional group selected from the group consisting of a carboxyl group and a sulfonic acid group and 7-20% by weight of a fluorine atom, the fluororesin in which a number-average molecular weight is 1,000-2,000,000, and an oxoate, a fluoride, a hydroxide, an organic salt, a carbonate or a peroxygenated salt of a group 4A metal.
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公开(公告)号：US09598773B2
公开(公告)日：2017-03-21
申请号：US14396210
申请日：2013-04-23
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Tadashi Nakano , Masaya Yamamoto , Hirofumi Taketsu
IPC: C23C8/10 , C23C22/53 , C23C8/02 , C23C22/05 , C23C2/06 , C22C18/00 , C22C18/04 , C23C28/00 , C23C2/26 , C23C8/18 , B32B15/01 , C22C38/00 , C23C22/73 , C23C22/82 , C22C1/02 , C23C2/12
CPC classification number: C23C22/05 , B32B15/013 , C22C1/02 , C22C18/00 , C22C18/04 , C22C38/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C8/02 , C23C8/18 , C23C22/73 , C23C22/82 , C23C28/00 , C23C28/321 , C23C28/3225 , C23C28/34 , C23C28/345 , C23C2222/00
Abstract: The present invention pertains to a method for producing a black-plated steel sheet capable of being blackened in a short amount of time, and exhibiting an excellent ability to maintain a black appearance after processing. As an original sheet, the sheet used is a Zn-plating steel sheet which contains molten Al and Mg and has a Zn-plating layer containing molten Al and Mg, containing Al in the amount of 1.0-22.0 mass %, inclusive, and containing Mg in the amount of 1.5-10.0 mass %, inclusive. The plating layer is blackened by causing the molten-plating steel sheet to contact water vapor inside a tightly sealed container. When doing so, the concentration of oxygen inside the tightly sealed container is 13% or less.
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Patent Agency Ranking
6.发明申请公开(公告)号：US20150083276A1
公开(公告)日：2015-03-26
申请号：US14396210
申请日：2013-04-23
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Tadashi Nakano , Masaya Yamamoto , Hirofumi Taketsu
CPC classification number: C23C22/05 , B32B15/013 , C22C1/02 , C22C18/00 , C22C18/04 , C22C38/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C8/02 , C23C8/18 , C23C22/73 , C23C22/82 , C23C28/00 , C23C28/321 , C23C28/3225 , C23C28/34 , C23C28/345 , C23C2222/00
Abstract: The present invention pertains to a method for producing a black-plated steel sheet capable of being blackened in a short amount of time, and exhibiting an excellent ability to maintain a black appearance after processing. As an original sheet, the sheet used is a Zn-plating steel sheet which contains molten Al and Mg and has a Zn-plating layer containing molten Al and Mg, containing Al in the amount of 1.0-22.0 mass %, inclusive, and containing Mg in the amount of 1.5-10.0 mass %, inclusive. The plating layer is blackened by causing the molten-plating steel sheet to contact water vapor inside a tightly sealed container. When doing so, the concentration of oxygen inside the tightly sealed container is 13% or less.
Abstract translation: 本发明涉及一种能够在短时间内变黑的镀黑钢板的制造方法，并且在加工后表现出良好的保持黑色外观的能力。 作为原始片材，所使用的片材是含有熔融的Al和Mg的Zn镀层钢板，并且具有含有熔融Al和Mg的Zn镀层，其含有量为1.0〜22.0质量％的Al，含有 含量为1.5-10.0质量％的Mg。 使镀层钢板与紧密密封的容器内的水蒸气接触，使镀层变黑。 这样做时，密闭容器内的氧浓度为13％以下。
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公开(公告)号：US10167542B2
公开(公告)日：2019-01-01
申请号：US14349334
申请日：2013-03-04
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Atsuo Shimizu , Masanori Matsuno , Masaya Yamamoto , Hirofumi Taketsu
IPC: B05D1/00 , D06B19/00 , C23C2/40 , C23C2/06 , C22C18/00 , C22C18/04 , C23C22/68 , C23C2/28 , B32B15/01 , C23C2/26 , C23C22/24 , C23C22/36 , C23C22/42 , C23C22/78
Abstract: A hot-dip Zn alloy plating layer is formed on a surface of a base steel sheet by immersing the base steel sheet in a hot-dip Zn alloy plating bath containing Al and Mg. An aqueous solution containing one of or two or more of polyatomic ions selected from the group consisting of a polyatomic ion including V5+, a polyatomic ion including Si4+, and a polyatomic ion including Cr6+ is then contacted with a surface of the hot-dip Zn alloy plating layer. The aqueous solution contains the polyatomic ion in a concentration of 0.01 g/L or more in terms of one of or two or more of atoms selected from the group consisting of V, Si, and Cr.
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公开(公告)号：US20150259776A1
公开(公告)日：2015-09-17
申请号：US14349334
申请日：2013-03-04
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Atsuo Shimizu , Masanori Matsuno , Masaya Yamamoto , Hirofumi Taketsu
CPC classification number: C23C2/40 , B32B15/013 , C22C18/00 , C22C18/04 , C23C2/06 , C23C2/26 , C23C2/28 , C23C22/24 , C23C22/36 , C23C22/42 , C23C22/68 , C23C22/78
Abstract: A hot-dip Zn alloy plating layer is formed on a surface of a base steel sheet by immersing the base steel sheet in a hot-dip Zn alloy plating bath containing Al and Mg. An aqueous solution containing one of or two or more of polyatomic ions selected from the group consisting of a polyatomic ion including V5+, a polyatomic ion including Si4+, and a polyatomic ion including Cr6+ is then contacted with a surface of the hot-dip Zn alloy plating layer. The aqueous solution contains the polyatomic ion in a concentration of 0.01 g/L or more in terms of one of or two or more of atoms selected from the group consisting of V, Si, and Cr.
Abstract translation: 通过将基体钢板浸渍在含有Al和Mg的热浸Zn合金电镀浴中，在基体钢板的表面上形成热浸镀锌合金镀层。 含有选自包括V5 +的多原子离子，包括Si4 +的多原子离子和包含Cr6 +的多原子离子的多原子离子中的一种或两种以上的水溶液然后与热浸Zn合金的表面接触 电镀层。 所述水溶液含有选自由V，Si和Cr组成的组中的一种或两种以上的原子浓度为0.01g / L以上的多原子离子。
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公开(公告)号：US10161047B2
公开(公告)日：2018-12-25
申请号：US15039512
申请日：2014-11-28
Inventor： Yusuke Miura , Shintaro Nakamura , Tadashi Nakano , Masaya Yamamoto , Hirofumi Taketsu
Abstract: Provided is a method for obtaining a chemical conversion coating-treated zinc-aluminum-magnesium alloy-plated steel sheet having extremely excellent in corrosion resistance and adhesiveness to a resin coating film. The method is for treating the surface of a zinc-aluminum-magnesium alloy-plated steel sheet with a metal surface treatment agent, in which the metal surface treatment agent contains a compound (A) having a zirconyl ([Zr═O]2+) structure, a vanadium compound (B), a titanium fluorocomplex compound (C), an organic phosphorus compound (Da) containing a phosphoric acid group and/or a phosphonic acid group, an inorganic phosphorus compound (Db), a specific aqueous acrylic resin (E), and an oxazoline group-containing polymer (F) as a curing agent, each in a predetermined amount, and the pH of the metal surface treatment agent is 3 to 6.
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10.发明申请公开(公告)号：US20150107722A1
公开(公告)日：2015-04-23
申请号：US14396192
申请日：2013-04-23
Applicant: NISSHIN STEEL CO., LTD.
Inventor： Tadashi Nakano , Masaya Yamamoto , Hirofumi Taketsu
CPC classification number: C23C8/16 , B32B15/013 , C22C1/02 , C22C18/00 , C22C18/04 , C22C38/00 , C23C2/06 , C23C2/12 , C23C2/26 , C23C8/02 , C23C8/18 , C23C8/80 , C23C22/42 , C23C28/00 , C23C28/02 , C23C28/321 , C23C28/3225 , C23C28/34 , C23C28/345
Abstract: The present invention pertains to a method for producing a black-plated steel sheet capable of being blackened in a short amount of time, and exhibiting an excellent ability to maintain a black appearance after processing. As an original sheet, the sheet used is a Zn-plating steel sheet which contains molten Al and Mg and has a Zn-plating layer containing molten Al and Mg, containing Al in the amount of 0.1-22.0 mass %, inclusive, and containing Mg in the amount of 0.1-1.5 mass %, inclusive. The plating layer is blackened by causing the molten-plating steel sheet to contact water vapor inside a tightly sealed container. When doing so, the concentration of oxygen inside the tightly sealed container is 13% or less.
Abstract translation: 本发明涉及一种能够在短时间内变黑的镀黑钢板的制造方法，在加工后表现出良好的保持黑色外观的能力。 作为原始片材，使用的片材是含有熔融的Al和Mg的Zn镀层钢板，并且具有含有熔融Al和Mg的Zn镀层，其含有量为0.1〜22.0质量％的Al，含有 含量为0.1〜1.5质量％的Mg。 使镀层钢板与紧密密封的容器内的水蒸气接触，使镀层变黑。 这样做时，密闭容器内的氧浓度为13％以下。
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