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    Conversion of residua to premium products via thermal treatment and coking
    2.
    发明授权
    Conversion of residua to premium products via thermal treatment and coking 失效
    通过热处理和焦化将残渣转化为优质产品

    公开(公告)号：US4443325A

    公开(公告)日：1984-04-17

    申请号：US452482

    申请日：1982-12-23

    申请人： Nai Y. Chen ,  Lillian A. Rankel

    发明人： Nai Y. Chen ,  Lillian A. Rankel

    IPC分类号： C10B55/00 ,  C10G51/04 ,  C10B55/10 ,  C10G65/18

    CPC分类号： C10B55/00 ,  C10G51/04

    摘要： A combined process for treating heavy hydrocarbon feedstocks, such as resids that minimizes coke production and maximizes naphtha production, comprising the steps of thermally treating the feedstocks, in the absence of an added catalyst and either with or without hydrogen and steam, at a temperature of at least about 750.degree. F. (399.degree. C.) and under a pressure greater than about 400 psig to create significant chemical transformations without causing phase separation and consequent formation of sludge or a coke deposit; topping the thermally treated product to produce a distillate fraction and a bottoms fraction; coking the bottom fraction to produce gas, liquid products, and coke; and finally catalytically cracking the combined distillate fraction and liquid products to recover gas, gasoline, and light distillate products.

    摘要翻译： 用于处理重烃原料的组合方法，例如使焦炭生产最小化并使石脑油生产最大化的残渣，包括以下步骤：在不存在加入的催化剂的情况下热处理原料，以及在有或没有氢气和蒸汽的情况下，在 至少约750°F（399℃），并且在大于约400psig的压力下产生显着的化学转化，而不引起相分离，从而形成污泥或焦炭沉积物; 顶部热处理产物以产生馏出物馏分和塔底馏分; 焦化底部馏分产生气体，液体产物和焦炭; 并最终催化裂化组合的馏出物馏分和液体产物以回收气体，汽油和轻馏分产物。

    Apparatus for FCC process with catalyst separation
    3.
    发明授权
    Apparatus for FCC process with catalyst separation 失效
    FCC催化分离装置

    公开(公告)号：US4971766A

    公开(公告)日：1990-11-20

    申请号：US437064

    申请日：1989-11-16

    申请人： Nai Y. Chen ,  Billy K. Huh ,  Thomas E. Degnan

    发明人： Nai Y. Chen ,  Billy K. Huh ,  Thomas E. Degnan

    IPC分类号： C10G11/18

    CPC分类号： C10G11/18

    摘要： An FCC or fluidized catalytic cracking process and apparatus for converting heavy metals laden crudes is disclosed. The heavy feed, conventional catalyst and an additive or vanadium getter contact the feed in a riser reactor. The additive is segregated from conventional FCC catalyst upstream of the conventional FCC regenerator. An elutriating, upflow riser reactor may be used with a coarse, rapidly settling getter. A fine, slowly settling getter may be used, with getter segregation achieved by using an elutriating cyclone on the riser outlet, an elutriating catalyst stripper, a sieve, or the like. The spent getter may be used once through, regenerated in a separate getter regenerator, or used as a source of fuel. Alumina and sponge coke are preferred getters.

    摘要翻译： 公开了一种FCC或流化催化裂化方法和用于转化重金属负载原油的装置。 重料，常规催化剂和添加剂或钒吸附剂在提升管反应器中接触进料。 该添加剂与常规FCC再生器上游的常规FCC催化剂分离。 淘汰式上升式提升管式反应器可与粗，快速沉降的吸气剂一起使用。 可以使用细的缓慢沉降的吸气剂，通过在提升管出口，淘洗催化剂汽提器，筛子等上使用淘洗旋风来实现吸气剂分离。 废吸气剂可以一次使用，在单独的吸气剂再生器中再生，或用作燃料来源。 氧化铝和海绵焦炭是优选的吸气剂。

    Catalyst for dewaxing hydrocarbon feedstock
    4.
    发明授权
    Catalyst for dewaxing hydrocarbon feedstock 失效
    用于脱蜡烃原料的催化剂

    公开(公告)号：US4877581A

    公开(公告)日：1989-10-31

    申请号：US239257

    申请日：1988-09-01

    申请人： Nai Y. Chen ,  Dennis E. Walsh

    发明人： Nai Y. Chen ,  Dennis E. Walsh

    IPC分类号： B01J29/44 ,  B01J29/74 ,  C10G45/64

    CPC分类号： C10G45/64 ,  B01J29/44

    摘要： A paraffin conversion process for hydroisomerizing a nitrogen and wax-containing hydrocarbon feedstock comprising contacting the feedstock with a catalyst including a ZSM-11 zeolite characterized by an alpha value from about 10 to 50, in combination with a Group VIII metal hydrogenation-dehydrogenation component of platinum or palladium at a temperature of about 400.degree. F. to about 850.degree. F. and at a pressure of from about 200 to about 2000 psig.

    摘要翻译： 一种用于使含氮和含蜡的烃原料加氢异构化的链烷烃转化方法，包括使原料与包含Z值为约10至50的α值的ZSM-11沸石的催化剂结合，与第VIII族金属加氢脱氢组分 铂或钯，温度为约400°F至约850°F，压力为约200至约2000psig。

    Crystalline silicate zeolite beta of improved stability
    6.
    发明授权
    Crystalline silicate zeolite beta of improved stability 失效
    结晶硅酸盐沸石β具有改善的稳定性

    公开(公告)号：US4789656A

    公开(公告)日：1988-12-06

    申请号：US070170

    申请日：1987-07-02

    申请人： Nai Y. Chen ,  Sharon B. McCullen

    发明人： Nai Y. Chen ,  Sharon B. McCullen

    IPC分类号： B01J29/74 ,  C10G45/64 ,  B01J29/32

    CPC分类号： C10G45/64 ,  B01J29/7415

    摘要： A process is described for preparing a binder-free Zeolite Beta containing catalyst which has a highly dispersed noble metal incorporated into the framework. The process comprises steaming Zeolite Beta, followed by noble metal incorporation and calcination. The present invention is also directed to an improved calcination process.

    摘要翻译： 描述了一种制备不含无粘结剂的含沸石沸石的催化剂的方法，该催化剂具有掺入框架中的高度分散的贵金属。 该方法包括蒸煮沸石β，然后进行贵金属掺入和煅烧。 本发明还涉及一种改进的煅烧方法。

    Hydroprocessing catalyst and process
    7.
    发明授权
    Hydroprocessing catalyst and process 失效
    加氢催化剂和工艺

    公开(公告)号：US4756822A

    公开(公告)日：1988-07-12

    申请号：US31807

    申请日：1987-03-30

    申请人： Nai Y. Chen ,  Tracy J. Huang

    发明人： Nai Y. Chen ,  Tracy J. Huang

    IPC分类号： B01J29/86 ,  C10G47/16

    CPC分类号： B01J29/86 ,  C10G47/16

    摘要： This invention provides a novel hydrocracking catalyst composition that contains Zeolite Beta having a framework boron content, a solid source of alumina, and a hydrogenation component. It further provides a low-pressure hydrocracking process that uses such composition.

    摘要翻译： 本发明提供一种新型加氢裂化催化剂组合物，其包含具有骨架硼含量的沸石β，氧化铝的固体源和氢化组分。 它还提供了使用这种组合物的低压加氢裂化方法。

    Lube dewaxing method for extension of cycle length
    8.
    发明授权
    Lube dewaxing method for extension of cycle length 失效
    润滑油脱蜡方法延长循环长度

    公开(公告)号：US4749467A

    公开(公告)日：1988-06-07

    申请号：US054115

    申请日：1987-05-22

    申请人： Nai Y. Chen ,  Bruce P. Pelrine

    发明人： Nai Y. Chen ,  Bruce P. Pelrine

    IPC分类号： C10G45/64 ,  C10G73/38

    CPC分类号： C10G45/64

    摘要： An improved method which provides for an extended cycle length in catalytic lube dewaxing of residual lube oil feedstocks and easier catalyst regeneration. The method may incorporate catalytically dewaxing a feedstock in a fixed bed reactor with or without product recycle, or a series of reactors with interreactor separation of vapors from liquids. Improved performance is achieved by operating the reactor at a temperature between about 490.degree. and about 620.degree. F., employing a high activity crystalline zeolite catalyst having an alpha value between about 50 and about 900 based on the zeolite and a space velocity sufficiently low to produce a dewaxed effluent of desired pour point and to maintain an average catalyst aging rate of less than about 2.degree. F. per day. This relatively low temperature operation allows catalyst performance to be restored by simple hydrogen reactivation.

    摘要翻译： 一种改进的方法，其提供了在残余润滑油原料的催化润滑油脱蜡中延长的循环长度并且更容易的催化剂再生。 该方法可以将原料催化脱蜡在具有或不具有产物再循环的固定床反应器中，或者一系列具有蒸发器与液体的反应器分离的反应器。 通过使用基于沸石的α值在约50至约900之间的高活性结晶沸石催化剂，在约490℃至约620℃的温度下操作反应器来实现改进的性能，空间速度足够低至 产生所需倾点的脱蜡流出物，并保持每天平均催化剂老化速率小于约2°F。 这种相对较低的温度操作允许通过简单的氢再活化来恢复催化剂性能。