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1.发明授权
公开(公告)号：US4983708A
公开(公告)日：1991-01-08
申请号：US350782
申请日：1989-05-12
申请人： Nan L. Yang , Andrew Auerbach , Rose. Pesce , Jerry A. Broussard , James L. Paul
发明人： Nan L. Yang , Andrew Auerbach , Rose. Pesce , Jerry A. Broussard , James L. Paul
CPC分类号： C08G2/22
摘要： Cationic copolymerization of trioxane with glycidyl ester derivatives, preferably glycidyl acrylate derivatives, produces thermally stable, usually cross-linked, acetal copolymer. The resulting acetal copolymer will exhibit side chain ester functionality, and particularly side chain vinyl functionality when glycidyl acrylate derivatives are employed, so as to permit its futher reaction with other chemical moieties to achieve an acetal copolymer of modified chemical and/or physical properties.
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2.发明授权Novel polyacetal terpolymers of trioxane and alpha, alpha- and alpha, beta-isomers of glycerol formal and functional derivatives thereof 失效丙三醇和其功能衍生物的三恶烷和α，α和α，β-异构体的新型聚缩醛三元共聚物
公开(公告)号：US4975519A
公开(公告)日：1990-12-04
申请号：US350781
申请日：1989-05-12
申请人： Nan L. Yang , Andrew Auerbach , Rose Pesce , Jerry A. Broussard , James L. Paul
发明人： Nan L. Yang , Andrew Auerbach , Rose Pesce , Jerry A. Broussard , James L. Paul
摘要： Cationic polymerization of trioxane and a mixture of ester derivatives of .alpha.,.alpha.- and .alpha.,.beta.-isomers of glycerol formal yields acetal terpolymers having pendant functional groups (i.e., ester groups, or hydroxyl groups obtained by hydrolyzing ester groups, pendent from the polymer's backbone). The glycerol formal monomers employed in this invention may include functional groups selected from ester moieties which are protected from, and thus survive, the polymerization process with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block polymers and/or to chemically bind modifiers to the acetal terpolymer backbone, for example.
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3.发明授权Novel polyacetal copolymers of trioxane and trimethylolpropane formal derivatives 失效三恶烷和三羟甲基丙烷正式衍生物的新型聚缩醛共聚物
公开(公告)号：US5004798A
公开(公告)日：1991-04-02
申请号：US350799
申请日：1989-05-12
申请人： Jerry A. Broussard , Andrew B. Auerbach , Nan L. Yang , James L. Paul , Yong C. Zheng , Chong L. Zhang
发明人： Jerry A. Broussard , Andrew B. Auerbach , Nan L. Yang , James L. Paul , Yong C. Zheng , Chong L. Zhang
CPC分类号： C08G2/24
摘要： Cationic copolymerization of trioxane and trimethylolpropane (TMP) formal or its ester derivatives yields acetal copolymers having pendant functional groups. The TMP formal or ester derivatives of TMP formal may therefore include functional groups selected from hydroxyl or ester moieties which are protected and thus survive the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.
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4.发明授权Grafting of amine functional polymers onto functionalized oxymethylene polymers and the resulting graft polymers thereof 失效将胺官能聚合物接枝到官能化甲醛聚合物上及其所得的接枝聚合物
公开(公告)号：US5206308A
公开(公告)日：1993-04-27
申请号：US664436
申请日：1991-03-04
IPC分类号： C08G81/00
CPC分类号： C08G81/00 , Y10S525/926 , Y10S525/927
摘要： Novel oxymethylene graft polymers are obtained by grafting, via Michael addition, an amine functional polymer onto an oxymethylene backbone having pendant acrylate or substituted acrylate ester groups serving as reactive sites for the graft reaction.
摘要翻译： 通过迈克尔加成将胺官能聚合物接枝到具有侧链丙烯酸酯或用作接枝反应的反应性位点的取代的丙烯酸酯基团的甲醛主链上获得新的甲醛接枝聚合物。
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5.发明授权Grafting of functional compounds onto functional oxymethylene polymer backbones, with diisocyanate coupling agents, and the graft polymers thereof 失效功能性化合物与功能性甲醛聚合物主链，二异氰酸酯偶联剂及其接枝聚合物接枝
公开(公告)号：US5043398A
公开(公告)日：1991-08-27
申请号：US350811
申请日：1989-05-12
CPC分类号： C08G18/8064 , C08G18/10 , C08G18/56 , C08G2/18
摘要： Novel oxymethylene graft polymers are obtained by grafting a functional compound (i.e., a polymer or compound having one or two hydroxyl, carboxyl, or amine functional groups) onto an oxymethylene backbone having pendant hydroxyl groups which serve as reactive sites for the graft reaction with diisocyanate coupling agents.
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公开(公告)号：US4906728A
公开(公告)日：1990-03-06
申请号：US181237
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
IPC分类号： C08G65/16 , C07D321/06 , C08G4/00 , G03F7/039
CPC分类号： G03F7/039 , C07D321/06 , C08G4/00
摘要： The invention concerns a method for producing an acetal copolymer containing backbone bromo-functional groups comprising copolymerizing trioxane with 5,6,-dibromo-1,3-dioxepene. The invention also concerns methods of modifying acetal copolymers containing bromo-functional groups and the copolymers produced by the methods of the invention.
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7.发明授权
公开(公告)号：US4900783A
公开(公告)日：1990-02-13
申请号：US181047
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
IPC分类号： C08G65/16 , C07D321/04 , C08F283/06 , C08G2/10 , C08G2/18 , C08G4/00 , C08G65/06 , C08G65/26
CPC分类号： C08G4/00 , C07D321/04 , C08G2/18
摘要： Acetal copolymers of trioxane and 1,3-dioxep-5-ene having a high degree of crystallinity and specific mole percent incorporations of 1,3-dioxep-5-ene are synthesized.The invention also provides a process for producing highly crystalline acetal copolymers by copolymerizing triozane and 1,3-dioxep-5-ene and precipitating the copolymer product from solution.The copolymers show much improved stability against halogen degradation.
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8.发明授权
公开(公告)号：US5071952A
公开(公告)日：1991-12-10
申请号：US181236
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce
IPC分类号： C07D321/06 , C07D498/04 , C08G2/24 , C08G2/26 , C08G4/00 , C08G65/22
CPC分类号： C07D321/06 , C08G4/00
摘要： Iodoisocyano, iodourea and oxazole modified 1,3 dioxep-5-ene ring monomers are synthesized and used in copolymerization reactions with trioxane to produce acetal copolymers with backbone functional groups. The invention also concerns processes for the production of acetal copolymers containing iodourea and oxazole functional groups from acetal copolymers with backbone double bonds.
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9.发明授权Novel polyacetal copolymers of trioxane and 1,2,6-hexanetriol formal derivatives 失效三恶烷和1,2,6-己三醇正式衍生物的新型聚缩醛共聚物
公开(公告)号：US4975518A
公开(公告)日：1990-12-04
申请号：US350791
申请日：1989-05-12
摘要： Cationic copolymerization of trioxane and 1,2,6-hexanetriol formal (HTF) or its ester derivatives yields acetal copolymers having pendant functional groups. The HTF formal or ester derivatives of HTF may therefore include functional groups selected from hydroxyl or ester moieties which are protected, and thus survive, the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.
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公开(公告)号：US5034499A
公开(公告)日：1991-07-23
申请号：US181233
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Yong C. Zheng , Shian S. Wang
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Yong C. Zheng , Shian S. Wang
IPC分类号： C07D321/06 , C07D493/04 , C08G2/00 , C08G2/10 , C08G2/18 , C08G4/00 , C08G18/00 , C08G18/56 , C08G59/20 , C08G77/42
CPC分类号： C08G4/00 , C07D321/06 , C08G18/003 , C08G18/56 , C08G2/18 , C08G77/42
摘要： Acetal copolymers of trioxane with epoxy functional groups are obtained by copolymerizing trioxane with 5,6-epoxy-1,3-dioxepane. The epoxide group in the polymer chain provides a highly reacting functional group for further modification. Acetal copolymers with backbone epoxide groups exhibit toughness and thermal stability. The backbone epoxide groups can also be aminated in a one step hydrolysis-amination process.
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