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公开(公告)号：US4906728A
公开(公告)日：1990-03-06
申请号：US181237
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
IPC分类号： C08G65/16 , C07D321/06 , C08G4/00 , G03F7/039
CPC分类号： G03F7/039 , C07D321/06 , C08G4/00
摘要： The invention concerns a method for producing an acetal copolymer containing backbone bromo-functional groups comprising copolymerizing trioxane with 5,6,-dibromo-1,3-dioxepene. The invention also concerns methods of modifying acetal copolymers containing bromo-functional groups and the copolymers produced by the methods of the invention.
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2.发明授权
公开(公告)号：US4900783A
公开(公告)日：1990-02-13
申请号：US181047
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce , Shian S. Wang
IPC分类号： C08G65/16 , C07D321/04 , C08F283/06 , C08G2/10 , C08G2/18 , C08G4/00 , C08G65/06 , C08G65/26
CPC分类号： C08G4/00 , C07D321/04 , C08G2/18
摘要： Acetal copolymers of trioxane and 1,3-dioxep-5-ene having a high degree of crystallinity and specific mole percent incorporations of 1,3-dioxep-5-ene are synthesized.The invention also provides a process for producing highly crystalline acetal copolymers by copolymerizing triozane and 1,3-dioxep-5-ene and precipitating the copolymer product from solution.The copolymers show much improved stability against halogen degradation.
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3.发明授权
公开(公告)号：US5071952A
公开(公告)日：1991-12-10
申请号：US181236
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Rose Pesce
IPC分类号： C07D321/06 , C07D498/04 , C08G2/24 , C08G2/26 , C08G4/00 , C08G65/22
CPC分类号： C07D321/06 , C08G4/00
摘要： Iodoisocyano, iodourea and oxazole modified 1,3 dioxep-5-ene ring monomers are synthesized and used in copolymerization reactions with trioxane to produce acetal copolymers with backbone functional groups. The invention also concerns processes for the production of acetal copolymers containing iodourea and oxazole functional groups from acetal copolymers with backbone double bonds.
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公开(公告)号：US5034499A
公开(公告)日：1991-07-23
申请号：US181233
申请日：1988-04-13
申请人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Yong C. Zheng , Shian S. Wang
发明人： Nan-Loh Yang , Andrew Auerbach , James L. Paul , Yong C. Zheng , Shian S. Wang
IPC分类号： C07D321/06 , C07D493/04 , C08G2/00 , C08G2/10 , C08G2/18 , C08G4/00 , C08G18/00 , C08G18/56 , C08G59/20 , C08G77/42
CPC分类号： C08G4/00 , C07D321/06 , C08G18/003 , C08G18/56 , C08G2/18 , C08G77/42
摘要： Acetal copolymers of trioxane with epoxy functional groups are obtained by copolymerizing trioxane with 5,6-epoxy-1,3-dioxepane. The epoxide group in the polymer chain provides a highly reacting functional group for further modification. Acetal copolymers with backbone epoxide groups exhibit toughness and thermal stability. The backbone epoxide groups can also be aminated in a one step hydrolysis-amination process.
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5.发明授权
公开(公告)号：US4983708A
公开(公告)日：1991-01-08
申请号：US350782
申请日：1989-05-12
申请人： Nan L. Yang , Andrew Auerbach , Rose. Pesce , Jerry A. Broussard , James L. Paul
发明人： Nan L. Yang , Andrew Auerbach , Rose. Pesce , Jerry A. Broussard , James L. Paul
CPC分类号： C08G2/22
摘要： Cationic copolymerization of trioxane with glycidyl ester derivatives, preferably glycidyl acrylate derivatives, produces thermally stable, usually cross-linked, acetal copolymer. The resulting acetal copolymer will exhibit side chain ester functionality, and particularly side chain vinyl functionality when glycidyl acrylate derivatives are employed, so as to permit its futher reaction with other chemical moieties to achieve an acetal copolymer of modified chemical and/or physical properties.
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6.发明授权Novel polyacetal terpolymers of trioxane and alpha, alpha- and alpha, beta-isomers of glycerol formal and functional derivatives thereof 失效丙三醇和其功能衍生物的三恶烷和α，α和α，β-异构体的新型聚缩醛三元共聚物
公开(公告)号：US4975519A
公开(公告)日：1990-12-04
申请号：US350781
申请日：1989-05-12
申请人： Nan L. Yang , Andrew Auerbach , Rose Pesce , Jerry A. Broussard , James L. Paul
发明人： Nan L. Yang , Andrew Auerbach , Rose Pesce , Jerry A. Broussard , James L. Paul
摘要： Cationic polymerization of trioxane and a mixture of ester derivatives of .alpha.,.alpha.- and .alpha.,.beta.-isomers of glycerol formal yields acetal terpolymers having pendant functional groups (i.e., ester groups, or hydroxyl groups obtained by hydrolyzing ester groups, pendent from the polymer's backbone). The glycerol formal monomers employed in this invention may include functional groups selected from ester moieties which are protected from, and thus survive, the polymerization process with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block polymers and/or to chemically bind modifiers to the acetal terpolymer backbone, for example.
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公开(公告)号：US08487139B2
公开(公告)日：2013-07-16
申请号：US12445356
申请日：2007-10-12
IPC分类号： C07C49/00
CPC分类号： C07C229/12 , A61K8/37 , A61K8/39 , A61K8/496 , A61K8/8147 , A61K2800/522 , A61K2800/56 , A61Q19/02 , C07C49/248 , C07C49/255 , C07C69/52 , C07C69/602 , C07C247/04 , C07D249/04
摘要： The invention relates to novel curcumin and tetrahydrocurcumin derivatives, which have been modified at one phenolic group to incorporate more-reactive groups. The curcumin and tetrahydrocurcumin derivatives are in the form of monomers, dimmers, and polymers.
摘要翻译： 本发明涉及新的姜黄素和四氢姜黄素衍生物，它们已经在一个酚基团被修饰以引入更多的反应性基团。 姜黄素和四氢姜黄素衍生物是单体，二聚体和聚合物的形式。
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公开(公告)号：US5300362A
公开(公告)日：1994-04-05
申请号：US960302
申请日：1992-10-13
申请人： Andrew Auerbach , Joseph Tajar , Marvin Wilson
发明人： Andrew Auerbach , Joseph Tajar , Marvin Wilson
CPC分类号： H01B3/308 , C08L81/02 , H01B3/301 , C08L53/02 , Y10T428/2933 , Y10T428/2938 , Y10T428/294 , Y10T428/2962
摘要： A coated wire is provided which comprises a wire coated with a blend of polyarylene sulfide and an ungrafted, hydrogenated conjugated diene/vinyl aromatic block copolymer which imparts improved elongation to polyarylene sulfide.
摘要翻译： 提供一种涂覆线，其包括涂覆有聚芳硫醚和未接枝的氢化共轭二烯/乙烯基芳族嵌段共聚物的共混物的线，其赋予聚芳硫醚的改进的伸长率。
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公开(公告)号：US5096951A
公开(公告)日：1992-03-17
申请号：US626789
申请日：1990-12-13
申请人： Andrew Auerbach
发明人： Andrew Auerbach
IPC分类号： C08K3/00 , C08J5/00 , C08K5/09 , C08K5/098 , C08K5/16 , C08K5/3475 , C08K5/3492 , C08K5/524 , C08K5/526 , C08L59/00 , C08L61/04
CPC分类号： C08K5/3492 , C08K5/098 , C08K5/526
摘要： A polyoxymethylene molding composition which exhibits improved ambient and heat aged color stability includes a metal deactivator and calcium hydroxystearate. One preferred composition of the invention includes: (a) greater than about 95 weight percent of polyoxymethylene, (b) between about 0.01 to about 0.1 weight percent of 3 salicyloyl-amido-1,2,4 triazole or tris-2-tert.butyl- 4-thio-(2'methyl-4'hydroxy-5'tert.butyl) phenyl-5-methyl phenyl phosphite, (c) between about 0.015 to about 0.4 weight percent of 2,4,6-triamino-sym-triazine, (d) between about 0.25 to about 1.0 weight percent of tetrakis(methylene-(3,5-di-tert-butyl- 4-hydroxyhydrocinnamate)) methane, (e) between about 0.05 to about 0.2 weight percent of calcium 12-hydroxystearate, and (f) between about 0.1 to about 0.3 weight percent of N-N'-ethylenebisstearamide. Due to their enhanced color stability, the compositions of this invention find particular utility as molded automobile components.
摘要翻译： 表现出改善的环境和热老化颜色稳定性的聚甲醛模塑组合物包括金属钝化剂和羟基硬脂酸钙。 本发明的一种优选组合物包括：（a）大于约95重量％的聚甲醛，（b）约0.01至约0.1重量％的磺酰基酰胺基-1,2,4-三唑或三-2-叔丁醇。 丁基-4-硫代 - （2'-甲基-4'-羟基-5'-叔丁基）苯基-5-甲基苯基亚磷酸酯，（c）约0.015至约0.4重量％的2,4,6-三氨基对 - 三嗪，（d）约0.25至约1.0重量％的四（亚甲基 - （3,5-二叔丁基-4-羟基氢化肉桂酸酯））甲烷，（e）约0.05至约0.2重量％的钙 12-羟基硬脂酸酯，和（f）约0.1至约0.3重量％的N-N'-亚乙基双硬脂酰胺。 由于其颜色稳定性的提高，本发明的组合物特别用作模制汽车部件。
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公开(公告)号：US5070127A
公开(公告)日：1991-12-03
申请号：US615859
申请日：1990-11-20
申请人： Andrew Auerbach
发明人： Andrew Auerbach
摘要： The present invention relates to an impact resistant polymeric composition comprising a polyarylene sulfide, a thermally stable modified selectively hydrogenated high 1,2 content block copolymer wherein at least one graftable functional molecule is grafted to the block copolymer in the vinylarene block and a silane.
摘要翻译： 本发明涉及耐冲击聚合物组合物，其包含聚芳硫醚，热稳定改性的选择性氢化的高含量嵌段共聚物，其中至少一个可接枝的官能分子被接枝到乙烯基芳烃嵌段中的嵌段共聚物和硅烷上。
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