摘要:
Cationic copolymerization of trioxane and trimethylolpropane (TMP) formal or its ester derivatives yields acetal copolymers having pendant functional groups. The TMP formal or ester derivatives of TMP formal may therefore include functional groups selected from hydroxyl or ester moieties which are protected and thus survive the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.
摘要:
Novel oxymethylene graft polymers are obtained by grafting a functional compound (i.e., a polymer or compound having one or two hydroxyl, carboxyl, or amine functional groups) onto an oxymethylene backbone having pendant hydroxyl groups which serve as reactive sites for the graft reaction with diisocyanate coupling agents.
摘要:
Novel oxymethylene graft polymers are obtained by grafting, via Michael addition, an amine functional polymer onto an oxymethylene backbone having pendant acrylate or substituted acrylate ester groups serving as reactive sites for the graft reaction.
摘要:
Cationic copolymerization of trioxane and 1,2,6-hexanetriol formal (HTF) or its ester derivatives yields acetal copolymers having pendant functional groups. The HTF formal or ester derivatives of HTF may therefore include functional groups selected from hydroxyl or ester moieties which are protected, and thus survive, the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.
摘要:
An oxymethylene polymer composition which exhibits improved thermal stability is provided by utilizing as a stabilizer a major amount of superpolyamide and a minor amount of a transition metal salt.
摘要:
An oxymethylene polymer composition which exhibits a reduced tendency to form mold deposits upon molding, reduced tendency to discolor under thermal stress and low extractable formaldehyde levels is provided by utilizing as a stabilizer a major amount of superpolyamide and a minor amount of a cyclic amidine compound of the formula: ##STR1## wherein R is phenyl, polynuclear aromatic, heterocyclic, cycloaliphatic and aliphatic containing at least 6 carbon atoms, as well as substituted derivatives of the listed substituents.
摘要:
A thermoplastic polyketone polymer composition having thermoset properties, processes for its production, and articles made thereof are disclosed. This composition also having improved continuous use temperature and thermal stability properties can be produced by crosslinking, at elevated temperatures, a thermoplastic polyketone resin with a suitable basic material. Optionally, suitable lubricants or fillers can also be added to further improve the properties of the resulting composition.
摘要:
Cellulose is activated by penetration of the cellulose with a polar medium and mixed at a temperature at which no significant degradation occurs with an amide selected from the group consisting of dimethylacetamide, 1-methyl-2-pyrrolidinone and mixtures thereof and from 3 to 15% by weight of lithium chloride. The cellulose is then dissolved in the amide and lithium chloride in the substantial absence of any polar medium other than the amide. Shaped cellulosic products may be formed by reconstituting the cellulose in fiber, sheet or other form.
摘要:
The tendency of cellulose acetate solutions, containing methylolated polymers of melamine or guanamine, to prepolymerize or gel is reduced by the addition to the solutions of an amine oxide. The amine oxide also acts to reduce the viscosity of the cellulose acetate solutions.
摘要:
The present invention relates to an impact resistant polymeric composition comprising a polyarylene sulfide and a thermally stable modified selectively hydrogenated high 1,2 content block copolymer wherein at least one graftable functional molecule is grafted to the block copolymer in the vinylarene block.