公开(公告)号：US09666906B2

公开(公告)日：2017-05-30

申请号：US14709525

申请日：2015-05-12

申请人： Nano and Advanced Materials Institute Limited

发明人： Kam Piu Ho ,  Kwok Keung Paul Ho ,  Ranshi Wang ,  Yeming Xu ,  Wai Chun Luk ,  Mei Mei Hsu

IPC分类号： H01M10/0569 ,  H01M10/0567 ,  H01M10/0525

CPC分类号： H01M10/0569 ,  H01M10/0525 ,  H01M10/0567 ,  H01M2300/0037

摘要： The present application discloses a high voltage electrolyte including an electrolyte solvent which includes a mixture of a dinitrile solvent and a nitrile solvent and is stable at voltage of about 5 V or above. The dinitrile solvent may include at least one selected from the group consisting of malononitrile, succinonitrile, glutaronitrile, adiponitrile, pimelonitrile, suberonitrile, azelanitrile and sebaconitrile. The nitrile solvent may include at least one selected from the group consisting of acetonitrile, propionitrile, butyronitrile, pivalonitrile and capronitrile. The present application also discloses a lithium ion battery including the above high voltage electrolyte. The lithium ion battery exhibits a cyclic performance of greater than about 300 cycles and with a capacity retention of greater than about 80%.

公开(公告)号：US09243340B2

公开(公告)日：2016-01-26

申请号：US14178308

申请日：2014-02-12

申请人： Nano and Advanced Materials Institute Limited

发明人： Kam Piu Ho ,  Paul Kwok Keung Ho ,  Man Wah Liu ,  Ranshi Wang ,  Wai Chun Luk ,  Wing Ho Choi ,  Fulin Zheng ,  Kwong Chau Kwok ,  Mei Mei Hsu ,  Ivan Ka Yu Lau

IPC分类号： C25D3/54 ,  C25D3/56 ,  H01L31/18 ,  C25D3/30 ,  H01L31/032 ,  C25D3/22 ,  C25D3/38 ,  C25D3/58 ,  C25D3/60 ,  C25D5/10 ,  C25D5/50

CPC分类号： C25D3/30 ,  C25D3/22 ,  C25D3/38 ,  C25D3/54 ,  C25D3/565 ,  C25D3/58 ,  C25D3/60 ,  C25D5/10 ,  C25D5/50 ,  C25D5/505 ,  H01L31/0326 ,  Y02E10/50

摘要： The present invention describes a method of producing a p-type light-absorbing semiconductor copper zinc tin selenide/sulfide (Cu2(ZnxSn2-x)(SySe1-y)4) (abbreviated CZTS) with electrochemical deposition. It can be used in the production of solar cell when combined with an n-type inorganic or an organic semiconductor layer. The present method comprises a one-step or a sequence of depositions using electroplating to fabricate a low-cost and large-area CZTS solar cell, without using expensive and complicated deposition techniques or highly toxic and flammable chemicals in the production process. The present method significantly reduces the cost and energy requirement for production of solar cell.

摘要翻译： 本发明描述了一种用电化学沉积法生产p型光吸收半导体铜锌锡硒化物/硫化物（Cu2（ZnSSn2-x）（SySe1-y）4）（简称CZTS）的方法。 当与n型无机或有机半导体层组合时，可以用于制造太阳能电池。 本方法包括使用电镀制造低成本和大面积CZTS太阳能电池的一步或一系列沉积，而不需要在生产过程中使用昂贵且复杂的沉积技术或高毒性和易燃的化学品。 本方法大大降低了太阳能电池生产的成本和能源需求。

公开(公告)号：US20150333373A1

公开(公告)日：2015-11-19

申请号：US14709525

申请日：2015-05-12

申请人： Nano and Advanced Materials Institute Limited

发明人： Kam Piu Ho ,  Kwok Keung Paul Ho ,  Ranshi Wang ,  Yeming Xu ,  Wai Chun Luk ,  Mei Mei Hsu

IPC分类号： H01M10/0569 ,  H01M10/0525 ,  H01M10/0567

CPC分类号： H01M10/0569 ,  H01M10/0525 ,  H01M10/0567 ,  H01M2300/0037

摘要： The present application discloses a high voltage electrolyte including an electrolyte solvent which includes a mixture of a dinitrile solvent and a nitrile solvent and is stable at voltage of about 5 V or above. The dinitrile solvent may include at least one selected from the group consisting of malononitrile, succinonitrile, glutaronitrile, adiponitrile, pimelonitrile, suberonitrile, azelanitrile and sebaconitrile. The nitrile solvent may include at least one selected from the group consisting of acetonitrile, propionitrile, butyronitrile, pivalonitrile and capronitrile. The present application also discloses a lithium ion battery including the above high voltage electrolyte. The lithium ion battery exhibits a cyclic performance of greater than about 300 cycles and with a capacity retention of greater than about 80%.

摘要翻译： 本申请公开了一种包括电解质溶剂的高压电解质，其包括二腈溶剂和腈溶剂的混合物，并且在约5V或更高的电压下是稳定的。 二腈溶剂可以包括选自丙二腈，丁二腈，戊二腈，己二腈，庚二腈，辛二腈，壬烯腈和癸二腈中的至少一种。 腈溶剂可以包括选自乙腈，丙腈，丁腈，新戊腈和癸腈中的至少一种。 本申请还公开了包括上述高电压电解质的锂离子电池。 锂离子电池显示大于约300个循环的循环性能，其容量保持率大于约80％。