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公开(公告)号：US20120108770A1
公开(公告)日：2012-05-03
申请号：US12300857
申请日：2007-04-24
申请人： Nermeen W. Aboelella , Robert D. Froese , David D. Graf , Wayde V. Konze , Pulikkottil J. Thomas
发明人： Nermeen W. Aboelella , Robert D. Froese , David D. Graf , Wayde V. Konze , Pulikkottil J. Thomas
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08L7/00 , Y10S526/905 , C08F4/64193 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F4/659 , C08F2500/01 , C08F2500/08 , C08F2500/09 , C08F2/06
摘要： Metal complexes of polyvalent aryloxyethers appropriately substituted with sterically bulky substituents possess enhanced solubility in aliphatic and cycloaliphatic hydrocarbons and/or when employed as catalyst components for the polymerization of ethylene/α-olefin copolymers, produce products having reduced I10/I2 values.
摘要翻译： 由空间庞大的取代基适当取代的多价芳氧基醚的金属络合物具有增强的在脂族和脂环族烃中的溶解性和/或当用作乙烯/α-烯烃共聚物聚合的催化剂组分时，产生具有降低的I10 / I2值的产物。
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公开(公告)号：US08450438B2
公开(公告)日：2013-05-28
申请号：US12300857
申请日：2007-04-24
申请人： Nermeen W. Aboelella , Robert D. Froese , David D. Graf , Wayde V. Konze , Pulikkottil J. Thomas
发明人： Nermeen W. Aboelella , Robert D. Froese , David D. Graf , Wayde V. Konze , Pulikkottil J. Thomas
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08L7/00 , Y10S526/905 , C08F4/64193 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F4/659 , C08F2500/01 , C08F2500/08 , C08F2500/09 , C08F2/06
摘要： Metal complexes of polyvalent aryloxyethers appropriately substituted with sterically bulky substituents possess enhanced solubility in aliphatic and cycloaliphatic hydrocarbons and/or when employed as catalyst components for the polymerization of ethylene/α-olefin copolymers, produce products having reduced I10/I2 values.
摘要翻译： 由空间庞大的取代基适当取代的多价芳氧基醚的金属配合物具有增强的在脂族和脂环族烃中的溶解性和/或当用作乙烯/α-烯烃共聚物聚合的催化剂成分时，产生具有降低的I10 / I2值的产物。
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公开(公告)号：US09029487B2
公开(公告)日：2015-05-12
申请号：US13814634
申请日：2011-08-24
申请人： Jerzy Klosin , Pulikkottil J. Thomas , Carl N. Iverson , Nermeen W. Aboelella , Kevin A. Frazier
发明人： Jerzy Klosin , Pulikkottil J. Thomas , Carl N. Iverson , Nermeen W. Aboelella , Kevin A. Frazier
IPC分类号： C08F4/76 , C08F4/659 , C07D209/82 , C07F7/00 , C08F210/16 , C08F210/18
CPC分类号： C08F4/65912 , C07D209/82 , C07F7/00 , C08F4/659 , C08F210/16 , C08F210/18 , C08F210/14 , C08F2500/03 , C08F210/08 , C08F210/06 , C08F236/06 , C08F4/64189 , C08F4/64193
摘要： The present invention generally relates to a process that copolymerizes two or more polymerizable olefins, and to cataclyst comprising a metal-ligand complex (precatalyst). The present invention also generally relates to ligands useful for preparing the metal-ligand complex.
摘要翻译： 本发明一般涉及使两种或更多种可聚合烯烃共聚的方法和包含金属 - 配体络合物（预催化剂）的崩解剂。 本发明还通常涉及可用于制备金属 - 配体络合物的配体。
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公开(公告)号：US20130144018A1
公开(公告)日：2013-06-06
申请号：US13814634
申请日：2011-08-24
申请人： Jerzy Klosin , Pulikkottil J. Thomas , Carl N. Iverson , Nermeen W. Aboelella , Kevin A. Frazier
发明人： Jerzy Klosin , Pulikkottil J. Thomas , Carl N. Iverson , Nermeen W. Aboelella , Kevin A. Frazier
IPC分类号： C08F4/659
CPC分类号： C08F4/65912 , C07D209/82 , C07F7/00 , C08F4/659 , C08F210/16 , C08F210/18 , C08F210/14 , C08F2500/03 , C08F210/08 , C08F210/06 , C08F236/06 , C08F4/64189 , C08F4/64193
摘要： The present invention generally relates to a process that copolymerizes two or more polymerizable olefins, and to cataclyst comprising a metal-ligand complex (precatalyst). The present invention also generally relates to ligands useful for preparing the metal-ligand complex.
摘要翻译： 本发明一般涉及使两种或更多种可聚合烯烃共聚的方法和包含金属 - 配体络合物（预催化剂）的崩解剂。 本发明还通常涉及可用于制备金属 - 配体络合物的配体。
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公开(公告)号：US08609794B2
公开(公告)日：2013-12-17
申请号：US13105018
申请日：2011-05-11
CPC分类号： C08F4/64193 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/14 , C08F210/16 , C08F2500/03
摘要： The present invention generally relates to a process that selectively polymerizes ethylene in the presence of an alpha-olefin, and to a metal-ligand complex (precatalyst) and catalyst useful in such processes, and to related compositions. The present invention also generally relates to ligands and intermediates useful for preparing the metal-ligand complex and to processes of their preparation.
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公开(公告)号：US20110282018A1
公开(公告)日：2011-11-17
申请号：US13105018
申请日：2011-05-11
IPC分类号： C08F4/76 , C07D403/12 , B01J31/22 , C08F10/14 , C07F7/00
CPC分类号： C08F4/64193 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/14 , C08F210/16 , C08F2500/03
摘要： The present invention generally relates to a process that selectively polymerizes ethylene in the presence of an alpha-olefin, and to a metal-ligand complex (precatalyst) and catalyst useful in such processes, and to related compositions. The present invention also generally relates to ligands and intermediates useful for preparing the metal-ligand complex and to processes of their preparation.
摘要翻译： 本发明一般涉及一种在α-烯烃存在下选择性聚合乙烯的方法，以及可用于这些方法的金属 - 配体络合物（预催化剂）和催化剂以及相关组合物。 本发明还通常涉及可用于制备金属 - 配体络合物的配体和中间体及其制备方法。
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公开(公告)号：US08124812B2
公开(公告)日：2012-02-28
申请号：US12565446
申请日：2009-09-23
申请人： Zenon Lysenko , Donald L. Morrison , David A. Babb , Donald L. Bunning , Christopher W. Derstine , James H. Gilchrist , H. Ray Jouett , Jeffrey S. Kanel , Kurt D. Olson , Wei-Jun Peng , Joe D. Phillips , Brian M. Roesch , Aaron W. Sanders , Alan K. Schrock , Pulikkottil J. Thomas
发明人： Zenon Lysenko , Donald L. Morrison , David A. Babb , Donald L. Bunning , Christopher W. Derstine , James H. Gilchrist , H. Ray Jouett , Jeffrey S. Kanel , Kurt D. Olson , Wei-Jun Peng , Joe D. Phillips , Brian M. Roesch , Aaron W. Sanders , Alan K. Schrock , Pulikkottil J. Thomas
IPC分类号： C07C47/02 , C07C45/50 , C07C29/14 , C07C59/147
CPC分类号： C08G18/4891 , C07C67/31 , C07C67/347 , C07C69/675 , C07C69/716 , C07C69/732 , C07C69/738 , C08G18/4072 , C08G18/4804 , C08G18/4841 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.
摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。
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公开(公告)号：US07615658B2
公开(公告)日：2009-11-10
申请号：US10551854
申请日：2004-04-22
申请人： Zenon Lysenko , Donald L. Morrison , David A. Babb , Donald L. Bunning , Christopher W. Derstine , James H. Gilchrist , H. Ray Jouett , Jeffrey S. Kanel , Kurt D. Olson , Wei-Jun Peng , Joe D. Phillips , Brian M. Roesch , Aaron W. Sanders , Alan K. Schrock , Pulikkottil J. Thomas
发明人： Zenon Lysenko , Donald L. Morrison , David A. Babb , Donald L. Bunning , Christopher W. Derstine , James H. Gilchrist , H. Ray Jouett , Jeffrey S. Kanel , Kurt D. Olson , Wei-Jun Peng , Joe D. Phillips , Brian M. Roesch , Aaron W. Sanders , Alan K. Schrock , Pulikkottil J. Thomas
IPC分类号： C07C51/367 , C07C27/00
CPC分类号： C08G18/4891 , C07C67/31 , C07C67/347 , C07C69/675 , C07C69/716 , C07C69/732 , C07C69/738 , C08G18/4072 , C08G18/4804 , C08G18/4841 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxymethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foam.
摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或具有以下重量组成的脂肪酸酯的混合物：大于约10至小于约95％的一元醇（单（羟甲基）}， 大于约1至小于约65％的二醇{二（羟甲基）}，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯; 优选大于约3至小于约35％的饱和物; 并且优选小于约10％的不饱和物。 醇组合物可以转化为用于制造聚氨酯板坯柔性泡沫的低聚多元醇。
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公开(公告)号：US20100298610A1
公开(公告)日：2010-11-25
申请号：US12565446
申请日：2009-09-23
申请人： Zenon Lysenko , Donald L. Morrison , David A. Babb , Donald L. Bunning , Christopher W. Derstine , James H. Gilchrist , H. Ray Jouett , Kurt D. Olson , Wei-Jun Peng , Joe D. Phillips , Brian M. Roesch , Aaron W. Sanders , Alan K. Schrock , Pulikkottil J. Thomas , Jeffrey S. Kanel
发明人： Zenon Lysenko , Donald L. Morrison , David A. Babb , Donald L. Bunning , Christopher W. Derstine , James H. Gilchrist , H. Ray Jouett , Kurt D. Olson , Wei-Jun Peng , Joe D. Phillips , Brian M. Roesch , Aaron W. Sanders , Alan K. Schrock , Pulikkottil J. Thomas , Jeffrey S. Kanel
IPC分类号： C07C47/02
CPC分类号： C08G18/4891 , C07C67/31 , C07C67/347 , C07C69/675 , C07C69/716 , C07C69/732 , C07C69/738 , C08G18/4072 , C08G18/4804 , C08G18/4841 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.
摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。
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公开(公告)号：US5227536A
公开(公告)日：1993-07-13
申请号：US922651
申请日：1992-07-30
IPC分类号： C07B61/00 , C07C37/02 , C07C37/055 , C07C39/23
CPC分类号： C07C37/02 , C07C2102/06
摘要： A process for preparing a 3- or 4-hydroxybenzocyclobutene comprises reacting a 3- or 4-halogenzocyclobutene reactant with an alkali metal hydroxide by heating in an aqueous alcohol medium at a temperature from about 50.degree. C. to a temperature at which dimerization or oligomerization of a benzocyclobutene reactant or product is a significant side reaction, in the presence of a metal-containing catalyst, for a time sufficient to convert the halobenzocyclobutene reactant to the hydroxybenzocyclobutene product.
摘要翻译： 制备3-或4-羟基苯并环丁烯的方法包括使3-或4-卤代环丁烯反应物与碱金属氢氧化物在约50℃的温度下在含水醇介质中加热至二聚或低聚 苯并环丁烯反应物或产物是在含金属的催化剂存在下足够将卤代苯并环丁烯反应物转化为羟基苯并环丁烯产物的时间的显着副反应。
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