公开(公告)号：US20100298610A1

公开(公告)日：2010-11-25

申请号：US12565446

申请日：2009-09-23

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas ,  Jeffrey S. Kanel

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas ,  Jeffrey S. Kanel

IPC分类号： C07C47/02

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。

公开(公告)号：US08124812B2

公开(公告)日：2012-02-28

申请号：US12565446

申请日：2009-09-23

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C47/02 ,  C07C45/50 ,  C07C29/14 ,  C07C59/147

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。

公开(公告)号：US07615658B2

公开(公告)日：2009-11-10

申请号：US10551854

申请日：2004-04-22

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C51/367 ,  C07C27/00

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxymethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foam.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或具有以下重量组成的脂肪酸酯的混合物：大于约10至小于约95％的一元醇（单（羟甲基）}， 大于约1至小于约65％的二醇{二（羟甲基）}，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯; 优选大于约3至小于约35％的饱和物; 并且优选小于约10％的不饱和物。 醇组合物可以转化为用于制造聚氨酯板坯柔性泡沫的低聚多元醇。

公开(公告)号：US20100048753A1

公开(公告)日：2010-02-25

申请号：US12518432

申请日：2007-12-03

申请人： Wei-Jun Peng ,  David A. Babb ,  Aaron W. Sanders ,  Christopher W. Derstine ,  Jorge Jimenez ,  Zenon Lysenko ,  Kurt D. Olson ,  Joe D. Phillips ,  Brian M. Roesch ,  Alan K. Schrock

发明人： Wei-Jun Peng ,  David A. Babb ,  Aaron W. Sanders ,  Christopher W. Derstine ,  Jorge Jimenez ,  Zenon Lysenko ,  Kurt D. Olson ,  Joe D. Phillips ,  Brian M. Roesch ,  Alan K. Schrock

IPC分类号： C08G18/00 ,  C07C53/00 ,  C07C69/34

CPC分类号： C08G18/36 ,  C08G2190/00

摘要： An aldehyde composition containing a mixture of mono-formyl-, diformyl-, and triformyl-substituted fatty acids and/or fatty acid esters having a di-aldehyde/tri-aldehyde weight ratio of less than 5/1 and an average functionality number from greater than 0.96 to less than 1.26. A monomer alcohol composition containing a mixture of mono-hydroxymethyl-, dihydroxymethyl-, and trihydroxymethyl-substituted fatty acids and/or fatty acid esters having a diol/triol weight ratio of less than 5/1 and an average functionality number from greater than 0.90 to less than 1.20. The monomer alcohol can be converted into an oligomeric polyol for use in the manufacture of polyurethane flexible foams.

摘要翻译： 含有单甲酰基，二甲酰基和三甲酰基取代的脂肪酸和/或二醛/三醛重量比小于5/1的​​平均官能度数和/或脂肪酸酯的混合物的醛组合物， 大于0.96小于1.26。 含有单羟甲基 - ，二羟甲基 - 和三羟甲基取代的脂肪酸和/或二醇/三醇重量比小于5/1并且平均官能度数大于0.90的脂肪酸酯的混合物的单体醇组合物 小于1.20。 单体醇可以转化为用于制备聚氨酯柔性泡沫的低聚多元醇。

公开(公告)号：US20090312450A1

公开(公告)日：2009-12-17

申请号：US11996505

申请日：2006-07-26

申请人： Charles A. Martin ,  Aaron W. Sanders ,  Jimmy D. Earls ,  Kurt D. Olson ,  John R. Briggs ,  Alan K. Schrock ,  Zenon Lysenko ,  David A. Babb

发明人： Charles A. Martin ,  Aaron W. Sanders ,  Jimmy D. Earls ,  Kurt D. Olson ,  John R. Briggs ,  Alan K. Schrock ,  Zenon Lysenko ,  David A. Babb

IPC分类号： C08G18/34 ,  C08G18/32 ,  C07C229/02

CPC分类号： C08G18/3825 ,  C07C235/08 ,  C08G18/36 ,  C08G2101/0025 ,  C08G2101/005

摘要： Polyurethanes, and rigid polyurethane foams in particular, are made using certain amides of modified fatty acids. The fatty acid groups are substituted hydroxymethyl, N-hydroxyalkyl aminoalkyl or hydroxy-substituted ester groups. The amide portion of the molecule contains hydroxyalkyl or other hydroxyl-substituted organic groups bonded to the amide nitrogen.

摘要翻译： 聚氨酯和硬质聚氨酯泡沫特别是使用某些改性脂肪酸酰胺制成的。 脂肪酸基团是取代的羟甲基，N-羟基烷基氨基烷基或羟基取代的酯基。 分子的酰胺部分含有与酰胺氮键合的羟基烷基或其它羟基取代的有机基团。

公开(公告)号：US20090118548A1

公开(公告)日：2009-05-07

申请号：US12299853

申请日：2007-04-17

申请人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

发明人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

IPC分类号： C07C45/50

CPC分类号： C07C45/80 ,  C07C45/50 ,  C07C67/347 ,  Y02P20/584 ,  C07C69/738 ,  C07C69/716 ,  C07C47/02

摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.

摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。

公开(公告)号：US07663002B2

公开(公告)日：2010-02-16

申请号：US12299853

申请日：2007-04-17

申请人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

发明人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

IPC分类号： C07C45/50

CPC分类号： C07C45/80 ,  C07C45/50 ,  C07C67/347 ,  Y02P20/584 ,  C07C69/738 ,  C07C69/716 ,  C07C47/02

摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.

摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。

公开(公告)号：US20080221363A1

公开(公告)日：2008-09-11

申请号：US12064064

申请日：2006-09-14

申请人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

发明人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

IPC分类号： C07F9/54

CPC分类号： C07F9/5022 ,  C07F9/5442 ,  C07F9/5449

摘要： A method of preparing an aromatic phosphine monosulfonate in zwitterionic form, such as dicyclohexylphenylphosphine monosulfonate zwitterion, involving contacting an aromatic phosphine with a sulfonating agent to provide a reaction mixture containing aromatic phosphine monosulfonate in acid form and unconverted sulfonating agent; quenching or removing substantially all of the unconverted sulfonating agent; partially neutralizing the aromatic phosphine monosulfonate in acid form to phase separate aromatic phosphine monosulfonate in zwitterionic form as a solid or neat liquid layer; and collecting the zwitterion as a solid or neat liquid. The zwitterion may be neutralized to form the corresponding aromatic phosphine monosulfonate metal salt, which is useful in preparing catalysts for hydroformylation processes.

摘要翻译： 一种以两性离子形式制备芳族膦单磺酸盐如二环己基苯基膦单磺酸盐两性离子的方法，包括使芳族膦与磺化剂接触以提供含有酸形式的芳族膦单磺酸盐和未转化的磺化剂的反应混合物; 淬火或去除基本上所有未转化的磺化剂; 部分中和酸形式的芳族膦单磺酸盐作为固体或纯液体层以两性离子形式相分离芳香族膦单磺酸盐; 并收集两性离子作为固体或纯净液体。 两性离子可以被中和形成相应的芳族膦单磺酸盐金属盐，其可用于制备用于加氢甲酰化方法的催化剂。

公开(公告)号：US07754924B2

公开(公告)日：2010-07-13

申请号：US12064064

申请日：2006-09-14

申请人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

发明人： Donald L. Morrison ,  Kurt D. Olson ,  Walter C. Reed ,  Anthony G. Abatjoglou

IPC分类号： C07F5/02

CPC分类号： C07F9/5022 ,  C07F9/5442 ,  C07F9/5449

摘要： A method of preparing an aromatic phosphine monosulfonate in zwitterionic form, such as dicyclohexylphenylphosphine monosulfonate zwitterion, involving contacting an aromatic phosphine with a sulfonating agent to provide a reaction mixture containing aromatic phosphine monosulfonate in acid form and unconverted sulfonating agent; quenching or removing substantially all of the unconverted sulfonating agent; partially neutralizing the aromatic phosphine monosulfonate in acid form to phase separate aromatic phosphine monosulfonate in zwitterionic form as a solid or neat liquid layer; and collecting the zwitterion as a solid or neat liquid. The zwitterion may be neutralized to form the corresponding aromatic phosphine monosulfonate metal salt, which is useful in preparing catalysts for hydroformylation processes.

摘要翻译： 一种以两性离子形式制备芳族膦单磺酸盐如二环己基苯基膦单磺酸盐两性离子的方法，包括使芳族膦与磺化剂接触以提供含有酸形式的芳族膦单磺酸盐和未转化的磺化剂的反应混合物; 淬火或去除基本上所有未转化的磺化剂; 部分中和酸形式的芳族膦单磺酸盐作为固体或纯液体层以两性离子形式相分离芳香族膦单磺酸盐; 并收集两性离子作为固体或纯净液体。 两性离子可以被中和形成相应的芳族膦单磺酸盐金属盐，其可用于制备用于加氢甲酰化方法的催化剂。

公开(公告)号：US5164497A

公开(公告)日：1992-11-17

申请号：US585556

申请日：1990-09-20

申请人： Stephen W. King ,  Kurt D. Olson ,  Bernard C. Ream

发明人： Stephen W. King ,  Kurt D. Olson ,  Bernard C. Ream

IPC分类号： B01J21/02 ,  B01J21/10 ,  B01J23/00 ,  C07B37/06 ,  C07B41/04 ,  C07B61/00 ,  C07C41/01 ,  C07C41/16 ,  C07C43/04 ,  C07C43/11 ,  C07C43/184 ,  C07C68/06 ,  C07C69/96 ,  C07C213/00 ,  C07C213/08 ,  C07C217/08 ,  C07D295/02 ,  C07D295/023 ,  C07D295/088 ,  C07D305/06

CPC分类号： C07D295/023 ,  B01J21/02 ,  B01J21/10 ,  B01J23/00 ,  C07B37/06 ,  C07C213/08 ,  C07C41/01 ,  C07C41/16 ,  C07D295/088 ,  C07D305/06 ,  Y02P20/582

摘要： A decarboxylation process which comprises contacting a carboxylated compound with a metal oxide catalyst under conditions effective to decarboxylate the carboxylated compound.