摘要:
The invention relates to a heterogenous enzymatic catalyst that takes the form of a cellular monolith consisting of a silica or organically modified silica matrix, said monolith including macropores, mesopores, and micropores, said pores being interconnected, and wherein the inner surface of the macropores is functionalized by a coupling agent selected from among silanes, said inner surface moreover having an unpurified enzyme attached thereon by means of a covalent or electrostatic bond. The invention also relates to the method for preparing said catalyst, said method comprising: a first step for preparing a solid silica impression that takes the form of a cellular monolith such as defined above; a second step for functionalizing the inner surface of the macropores via a coupling agent, selected from among silanes, by vacuum-soaking the cellular monolith by dissolving the coupling agent in an organic solvent; and a third step for vacuum-soaking the thus-functionalized monolith by means of an aqueous solution or aqueous dispersion of at least one unpurified enzyme. Finally, the invention relates to the use of such catalyst to carry out catalyzed chemical reactions.
摘要:
A method is provided for storing hydrogen in a macroporous monolithic material by the heterogeneous nucleation of a metal hydride. A composite material is provided for storing hydrogen directly obtained by the method. A method is also provided for employing the material for the production of dihydrogen, as well as a method for producing dihydrogen using such a composite material.
摘要:
A method is provided for storing hydrogen in a macroporous monolithic material by the heterogeneous nucleation of a metal hydride. A composite material is provided for storing hydrogen directly obtained by the method. A method is also provided for employing the material for the production of dihydrogen, as well as a method for producing dihydrogen using such a composite material.
摘要:
A carbon or ceramic monolithic materials with an M2 (macroporous/microporous) hierarchised porous structure is provided as well as method for preparing said materials using a macro/meso/microporous silica cavity. Such materials may be used, in particular for the production of hydrogen purifiers, supercapacitors or electrodes, or else for carrying out catalysed chemical reactions in a heterogeneous phase.
摘要:
A carbon or ceramic monolithic materials with an M2 (macroporous/microporous) hierarchised porous structure is provided as well as method for preparing said materials using a macro/meso/microporous silica cavity. Such materials may be used, in particular for the production of hydrogen purifiers, supercapacitors or electrodes, or else for carrying out catalysed chemical reactions in a heterogeneous phase.
摘要:
A porous electrochemical electrode is made up of a solid cellular material provided in the form of a semi-graphitized carbon monolith comprising a hierarchized porous network free of mesopores and including macropores with a mean dimension dA of 1 μm to 100 μm, and micropores with a mean dimension dI of 0.5 nm to 2 nm, said macropores and micropores being interconnected. In said electrode, the macropores contain at least one electroactive species in direct contact with the semi-graphitized carbon that makes up the surface of the macropores. The invention also relates to a method for preparing such an electrode as well as to the use thereof as a biosensor or for manufacturing a biopile.
摘要:
A porous electrochemical electrode is made up of a solid cellular material provided in the form of a semi-graphitised carbon monolith comprising a hierarchised porous network free of mesopores and including macropores with a mean dimension dA of 1 μm to 100 μm, and micropores with a mean dimension dI of 0.5 nm to 2 nm, said macropores and micropores being interconnected. In said electrode, the macropores contain at least one electroactive species in direct contact with the semi-graphitised carbon that makes up the surface of the macropores. The invention also relates to a method for preparing such an electrode as well as to the use thereof as a biosensor or for manufacturing a biopile.
摘要:
An original representation of an original set of data in a data source can be provided, and an updated representation of an updated set of data in the data source can be received. A change notification set that includes change notifications can be generated by comparing the updated representation with the original representation. The change notification set can represent a possible set of changes that yield the updated representation when starting with the original representation. The change notification set can be sent to a client of the data source. One or more requests from the client for data from the data source may be processed while obtaining the updated representation of the updated set of data. This processing can include adding one or more placeholders and matching the placeholder(s) with one or more items in the updated set of data.
摘要:
A data representation that represents source data at a data source can be maintained. A request to perform an edit can be received from a client, and a request to make the edit to the source data can be sent to the data source. The edit can be optimistically applied to the data representation. Additionally, a change notification can be sent to the client. The change notification can indicate one or more changes to the data representation, where the change(s) resulted from the application of the edit to the data representation. A notification can be received from the data source after applying the edit to the data representation and after sending the change notification. The notification from the data source can indicate whether the edit to the source data succeeded.
摘要:
Techniques and implementations for providing enhanced functionality for handling data in Internet browsers or other applications used for accessing data over a network, including providing thumbnail image displays of the current appearance of webpages referenced by URLs returned in a set of search results, providing thumbnail image displays of the webpages referenced by a list of favorite or bookmarked websites, providing thumbnail image displays of webpages which have been blocked from appearing on a user's screen, and providing thumbnail image displays of images which have been extracted from webpages and stored for potential future use.