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公开(公告)号:US20070253772A1
公开(公告)日:2007-11-01
申请号:US11822518
申请日:2007-07-06
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
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公开(公告)号:US20060128891A1
公开(公告)日:2006-06-15
申请号:US11345286
申请日:2006-02-02
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
摘要翻译: 一种二阶改性嵌段共聚物,其可以通过使一级改性嵌段共聚物与二级改性剂反应而得到,其中一级改性嵌段共聚物包含与碱结合的碱嵌段共聚物和含官能团的一级改性基团 嵌段共聚物,其中所述碱嵌段共聚物包含至少一种主要由乙烯基芳族烃单体单元和至少一个主要由共轭二烯单体单元组成的聚合物嵌段的聚合物嵌段,并且其中所述二级改性剂具有特定官能团, 与一级改性嵌段共聚物的一级改性基团的官能团反应。 含有二级改性嵌段共聚物的聚合物组合物的二阶改性嵌段共聚物以及热塑性树脂和/或橡胶状聚合物。
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公开(公告)号:US07256238B2
公开(公告)日:2007-08-14
申请号:US10479754
申请日:2002-07-18
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
IPC分类号: C08L53/02
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
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公开(公告)号:US07642318B2
公开(公告)日:2010-01-05
申请号:US11822518
申请日:2007-07-06
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
IPC分类号: C08L53/02
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
摘要翻译: 二级改性嵌段共聚物,其可以通过使一级改性嵌段共聚物与二级改性剂反应得到,其中一级改性嵌段共聚物包括碱嵌段共聚物和含官能团的一级改性剂 基团嵌段共聚物包含至少一个主要由乙烯基芳族烃单体单元组成的聚合物嵌段和至少一个主要由共轭二烯单体单元组成的聚合物嵌段,其中二级改性剂具有 与一级改性嵌段共聚物的一级改性剂基团的官能团反应的官能团。 包含二级改性嵌段共聚物的二阶改性嵌段共聚物聚合物组合物以及热塑性树脂和/或橡胶状聚合物。
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公开(公告)号:US07414093B2
公开(公告)日:2008-08-19
申请号:US11345286
申请日:2006-02-02
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
IPC分类号: C08L53/02
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
摘要翻译: 一种二阶改性嵌段共聚物,其可以通过使一级改性嵌段共聚物与二级改性剂反应而得到,其中一级改性嵌段共聚物包含与碱结合的碱嵌段共聚物和含官能团的一级改性基团 嵌段共聚物,其中所述碱嵌段共聚物包含至少一种主要由乙烯基芳族烃单体单元和至少一个主要由共轭二烯单体单元组成的聚合物嵌段的聚合物嵌段,并且其中所述二级改性剂具有特定官能团, 与一级改性嵌段共聚物的一级改性基团的官能团反应。 含有二级改性嵌段共聚物的聚合物组合物的二阶改性嵌段共聚物以及热塑性树脂和/或橡胶状聚合物。
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公开(公告)号:US07122594B2
公开(公告)日:2006-10-17
申请号:US10480201
申请日:2002-04-24
IPC分类号: B60C3/04 , C08K5/5415
CPC分类号: C08K3/22 , C08F8/04 , C08F8/30 , C08F2800/20 , C08K3/01 , C08K3/36 , C08L53/005 , C08L53/025 , C08L53/02 , C08L2666/06 , C08F297/04 , C08F8/42
摘要: A modified block copolymer composition comprising (1) 100 parts by weight of a modified block copolymer consisting of vinyl aromatic hydrocarbons and conjugated dienes, containing a functional group having at least one group selected from the group consisting of a hydroxide group, an epoxy group, an amino group, a silanol group and an alkoxysilane group, or a hydrogenation product of the copolymer, and (2) 0.5 to 50 parts by weight at least one of fillers selected from the group consisting of silica-based inorganic fillers, metal oxides and metal hydroxides is disclosed. This modified block copolymer composition is excellent in heat resistance, mechanical strength, transparency, abrasion resistance, and processability.
摘要翻译: 一种改性嵌段共聚物组合物,其包含(1)100重量份由乙烯基芳烃和共轭二烯构成的改性嵌段共聚物,其含有具有至少一个选自氢氧基,环氧基, 氨基,硅烷醇基和烷氧基硅烷基,或该共聚物的氢化产物,和(2)0.5至50重量份的至少一种选自二氧化硅基无机填料,金属氧化物和 公开了金属氢氧化物。 该改性嵌段共聚物组合物的耐热性,机械强度,透明性,耐磨性和加工性优异。
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公开(公告)号:US07642317B2
公开(公告)日:2010-01-05
申请号:US11822507
申请日:2007-07-06
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
IPC分类号: C08L53/02
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
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公开(公告)号:US20070258760A1
公开(公告)日:2007-11-08
申请号:US11822507
申请日:2007-07-06
申请人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
发明人: Nobuaki Kubo , Yasuhiro Kusanose , Shigeo Nakajima , Takaaki Matsuda , Shigeki Takayama , Toshinori Shiraki
IPC分类号: C08F12/06
CPC分类号: C08F8/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L95/00 , C08L2666/02 , C09J7/22 , C09J7/38 , C09J7/387 , C09J153/02 , C09J153/025 , C09J2453/00 , C08L2666/24
摘要: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
摘要翻译: 二级改性嵌段共聚物,其可以通过使一级改性嵌段共聚物与二级改性剂反应得到,其中一级改性嵌段共聚物包括碱嵌段共聚物和含官能团的一级改性剂 基团嵌段共聚物包含至少一个主要由乙烯基芳族烃单体单元组成的聚合物嵌段和至少一个主要由共轭二烯单体单元组成的聚合物嵌段,其中二级改性剂具有 与一级改性嵌段共聚物的一级改性剂基团的官能团反应的官能团。 包含二级改性嵌段共聚物的二阶改性嵌段共聚物聚合物组合物以及热塑性树脂和/或橡胶状聚合物。
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公开(公告)号:US07498387B2
公开(公告)日:2009-03-03
申请号:US10510571
申请日:2003-04-10
CPC分类号: C09J151/04 , C08C19/02 , C08F8/04 , C08F297/04 , C08L51/04 , C08L53/025 , C08L2666/02 , C09J153/025 , C08L2666/24
摘要: A first-order modified, hydrogenated polymer comprising (1) a hydrogenated polymer obtained by hydrogenating at least one unhydrogenated polymer selected from the group consisting of a polymer comprising conjugated diene monomer units and a copolymer comprising conjugated diene monomer units and vinyl aromatic hydrocarbon monomer units, and (2) a functional group-containing first-order modifier group bonded to the hydrogenated polymer (1), wherein the content of the vinyl aromatic hydrocarbon monomer units, vinyl aromatic hydrocarbon block ratio, weight average molecular weight, and hydrogenation ratio (as measured with respect to the double bonds in the conjugated diene monomer units) of the first-order modified, hydrogenated polymer are, respectively, within specific ranges. A second-order modified polymer obtained by reacting a second-order modifier with a first-order modified polymer comprising (β) a base polymer and (γ) a functional group-containing first-order modifier group bonded to the base polymer (β). A composition comprising the above-mentioned first-order modified, hydrogenated polymer or second-order modified polymer and at least one functional component other than the modified polymer.
摘要翻译: 一种一级改性氢化聚合物,其包含(1)氢化聚合物,其通过氢化至少一种选自包含共轭二烯单体单元的聚合物的非氢化聚合物和包含共轭二烯单体单元和乙烯基芳烃单体单元的共聚物而获得 ,和(2)与氢化聚合物(1)键合的含官能团的一级改性基团,其中乙烯基芳烃单体单元的含量,乙烯基芳烃嵌段比,重均分子量和氢化比( 相对于共轭二烯单体单元中的双键测定的一级改性氢化聚合物分别在特定范围内。 通过使二级改性剂与包含(β)基础聚合物和(γ)与基础聚合物(β)键合的含官能团的一级改性基团的一级改性聚合物反应而获得的二级改性聚合物, 。 包含上述一级改性氢化聚合物或二级改性聚合物和除改性聚合物以外的至少一种官能组分的组合物。
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公开(公告)号:US08071676B2
公开(公告)日:2011-12-06
申请号:US12318135
申请日:2008-12-22
CPC分类号: C09J151/04 , C08C19/02 , C08F8/04 , C08F297/04 , C08L51/04 , C08L53/025 , C08L2666/02 , C09J153/025 , C08L2666/24
摘要: A primary modified polymer composed of (1) a hydrogenated polymer obtained by hydrogenating at least one non-hydrogenated polymer selected from the group consisting of polymers comprising conjugated diene monomer units and copolymers comprising conjugated diene monomer units and vinyl aromatic monomer units and (2) groups of a primary modifier having a functional group which are bonded to the polymer (1), which has a specific vinyl aromatic monomer unit content, a specific vinyl aromatic polymer block content, a specific weight-average molecular weight, and a specific degree of hydrogenation of the double bonds of conjugated diene monomer units; a secondary modified polymer obtained by reacting a primary modified polymer composed of (β) a base polymer and (γ) groups of a primary modifier having a functional group which are bonded to the polymer (β) with a secondary modifier; and compositions comprising the primary or secondary modified polymer and at least one other component.
摘要翻译: 一种主要改性聚合物,其由(1)氢化聚合物组成,所述氢化聚合物通过氢化至少一种选自包含共轭二烯单体单元的聚合物和包含共轭二烯单体单元和乙烯基芳族单体单元的共聚物的非氢化聚合物和(2) 具有与聚合物(1)结合的官能团的基团,其具有特定的乙烯基芳族单体单元含量,特定的乙烯基芳族聚合物嵌段含量,比重重均分子量和具体的 共轭二烯单体单元的双键氢化; 由(&bgr)基础聚合物构成的一级改性聚合物和具有与该聚合物(&bgr)键合的官能团的一级改性剂的(γ))与二级改性剂反应得到的二次改性聚合物; 和包含伯或仲改性聚合物和至少一种其它组分的组合物。
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