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    Hydrogenated Block Copolymers and Crosslinking Compositions Containing the Same
    2.
    发明申请
    Hydrogenated Block Copolymers and Crosslinking Compositions Containing the Same 有权
    氢化嵌段共聚物和含有它的交联组合物

    公开(公告)号：US20100087559A1

    公开(公告)日：2010-04-08

    申请号：US12375672

    申请日：2007-08-07

    申请人： Yasuhiro Kusanose ,  Masahiro Fujiwara ,  Daisuke Shimizu

    发明人： Yasuhiro Kusanose ,  Masahiro Fujiwara ,  Daisuke Shimizu

    IPC分类号： C08F136/04 ,  C08F8/04 ,  C08L53/02

    CPC分类号： C08F8/04 ,  C08F297/04 ,  C08L51/006 ,  C08L53/025 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

    摘要： A hydrogenated block copolymer obtained by selective hydrogenation of a block copolymer comprising at least two polymer blocks (A) which each comprise vinyl aromatic monomer units as the main component and may be the same or different from each other, at least two polymer blocks (B) which each comprise monomer units derived from a conjugated diene of 5 or more carbon atoms as the main component and may be the same or different from each other, and one or more polymer blocks (C) which each comprise monomer units derived from a conjugated diene of 4 or more carbon atoms as the main component and may be the same or different from each other and/or one or more random copolymer blocks (D) which each comprise monomer units (d-1) derived from a conjugated diene of 4 or more carbon atoms and vinyl aromatic monomer units (d-2) as the main components, wherein the degree of hydrogenation of olefinically unsaturated double bonds of the blocks (B) is 50% or below; the degrees of hydrogenation of olefinically unsaturated double bonds of the blocks (C) and (D) are 80% or above; the content of vinyl aromatic monomer units in the block copolymer is 10 to 85% by weight; the contents of A, B, C and D in the block copolymer are 10 to 70% by weight, 1 to 15% by weight, 0 to 85% by weight and 0 to 85% by weight respectively with the proviso that the sum of C and D is 25 to 85% by weight and the sum total of A, B, C and D is 100% by weight; and the weight-average molecular weight (M) of A satisfies the relationship: M≧20000/[l+{content (%) of (d-2)}/20].

    摘要翻译： 通过选择性氢化包含至少两个聚合物嵌段（A）的嵌段共聚物获得的氢化嵌段共聚物，它们各自包含乙烯基芳族单体单元作为主要组分，并且可以彼此相同或不同，至少两个聚合物嵌段（B ），其各自包含衍生自5个或更多个碳原子的共轭二烯作为主要成分的单体单元，并且可以彼此相同或不同，并且一个或多个聚合物嵌段（C）各自包含衍生自共轭 具有4个或更多个碳原子的二烯作为主要组分，并且可以彼此相同或不同，和/或一种或多种无规共聚物嵌段（D），其各自包含衍生自共轭二烯的单体单元（d-1）4 或更多的碳原子和乙烯基芳族单体单元（d-2）作为主要成分，其中嵌段（B）的烯属不饱和双键的氢化度为50％以下; 嵌段（C）和（D）的烯属不饱和双键的氢化度为80％以上; 嵌段共聚物中乙烯基芳族单体单元的含量为10〜85重量％ 嵌段共聚物中A，B，C和D的含量分别为10〜70重量％，1〜15重量％，0〜85重量％，0〜85重量％，条件是 C和D为25〜85重量％，A，B，C和D的总和为100重量％ 并且A的重均分子量（M）满足关系：M≥20000/ [1 + {（d-2）的含量（％）} / 20]。

    Modified block copolymer
    6.
    发明申请
    Modified block copolymer 有权
    改性嵌段共聚物

    公开(公告)号：US20060128891A1

    公开(公告)日：2006-06-15

    申请号：US11345286

    申请日：2006-02-02

    申请人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    发明人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    IPC分类号： C08L53/00 ,  C08F8/30

    CPC分类号： C08F8/00 ,  C08F297/04 ,  C08L53/02 ,  C08L53/025 ,  C08L95/00 ,  C08L2666/02 ,  C09J7/22 ,  C09J7/38 ,  C09J7/387 ,  C09J153/02 ,  C09J153/025 ,  C09J2453/00 ,  C08L2666/24

    摘要： A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.

    摘要翻译： 一种二阶改性嵌段共聚物，其可以通过使一级改性嵌段共聚物与二级改性剂反应而得到，其中一级改性嵌段共聚物包含与碱结合的碱嵌段共聚物和含官能团的一级改性基团 嵌段共聚物，其中所述碱嵌段共聚物包含至少一种主要由乙烯基芳族烃单体单元和至少一个主要由共轭二烯单体单元组成的聚合物嵌段的聚合物嵌段，并且其中所述二级改性剂具有特定官能团， 与一级改性嵌段共聚物的一级改性基团的官能团反应。 含有二级改性嵌段共聚物的聚合物组合物的二阶改性嵌段共聚物以及热塑性树脂和/或橡胶状聚合物。

    Modified block copolymer
    7.
    发明授权
    Modified block copolymer 有权
    改性嵌段共聚物

    公开(公告)号：US07642318B2

    公开(公告)日：2010-01-05

    申请号：US11822518

    申请日：2007-07-06

    申请人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    发明人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    IPC分类号： C08L53/02

    CPC分类号： C08F8/00 ,  C08F297/04 ,  C08L53/02 ,  C08L53/025 ,  C08L95/00 ,  C08L2666/02 ,  C09J7/22 ,  C09J7/38 ,  C09J7/387 ,  C09J153/02 ,  C09J153/025 ,  C09J2453/00 ,  C08L2666/24

    摘要： A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.

    摘要翻译： 二级改性嵌段共聚物，其可以通过使一级改性嵌段共聚物与二级改性剂反应得到，其中一级改性嵌段共聚物包括碱嵌段共聚物和含官能团的一级改性剂 基团嵌段共聚物包含至少一个主要由乙烯基芳族烃单体单元组成的聚合物嵌段和至少一个主要由共轭二烯单体单元组成的聚合物嵌段，其中二级改性剂具有 与一级改性嵌段共聚物的一级改性剂基团的官能团反应的官能团。 包含二级改性嵌段共聚物的二阶改性嵌段共聚物聚合物组合物以及热塑性树脂和/或橡胶状聚合物。

    Modified polymers and compositions containing the same
    8.
    发明授权
    Modified polymers and compositions containing the same 有权
    改性聚合物和含有它们的组合物

    公开(公告)号：US07498387B2

    公开(公告)日：2009-03-03

    申请号：US10510571

    申请日：2003-04-10

    申请人： Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki ,  Shigeo Nakajima ,  Yasuhiro Kusanose

    发明人： Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki ,  Shigeo Nakajima ,  Yasuhiro Kusanose

    IPC分类号： C08C19/02 ,  C08C19/22 ,  C08C19/25 ,  C08C19/28 ,  C08C19/30 ,  C08L95/00 ,  C08F36/04

    CPC分类号： C09J151/04 ,  C08C19/02 ,  C08F8/04 ,  C08F297/04 ,  C08L51/04 ,  C08L53/025 ,  C08L2666/02 ,  C09J153/025 ,  C08L2666/24

    摘要： A first-order modified, hydrogenated polymer comprising (1) a hydrogenated polymer obtained by hydrogenating at least one unhydrogenated polymer selected from the group consisting of a polymer comprising conjugated diene monomer units and a copolymer comprising conjugated diene monomer units and vinyl aromatic hydrocarbon monomer units, and (2) a functional group-containing first-order modifier group bonded to the hydrogenated polymer (1), wherein the content of the vinyl aromatic hydrocarbon monomer units, vinyl aromatic hydrocarbon block ratio, weight average molecular weight, and hydrogenation ratio (as measured with respect to the double bonds in the conjugated diene monomer units) of the first-order modified, hydrogenated polymer are, respectively, within specific ranges. A second-order modified polymer obtained by reacting a second-order modifier with a first-order modified polymer comprising (β) a base polymer and (γ) a functional group-containing first-order modifier group bonded to the base polymer (β). A composition comprising the above-mentioned first-order modified, hydrogenated polymer or second-order modified polymer and at least one functional component other than the modified polymer.

    摘要翻译： 一种一级改性氢化聚合物，其包含（1）氢化聚合物，其通过氢化至少一种选自包含共轭二烯单体单元的聚合物的非氢化聚合物和包含共轭二烯单体单元和乙烯基芳烃单体单元的共聚物而获得 ，和（2）与氢化聚合物（1）键合的含官能团的一级改性基团，其中乙烯基芳烃单体单元的含量，乙烯基芳烃嵌段比，重均分子量和氢化比（ 相对于共轭二烯单体单元中的双键测定的一级改性氢化聚合物分别在特定范围内。 通过使二级改性剂与包含（β）基础聚合物和（γ）与基础聚合物（β）键合的含官能团的一级改性基团的一级改性聚合物反应而获得的二级改性聚合物， 。 包含上述一级改性氢化聚合物或二级改性聚合物和除改性聚合物以外的至少一种官能组分的组合物。

    Modified block copolymer
    9.
    发明授权
    Modified block copolymer 有权
    改性嵌段共聚物

    公开(公告)号：US07414093B2

    公开(公告)日：2008-08-19

    申请号：US11345286

    申请日：2006-02-02

    申请人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    发明人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    IPC分类号： C08L53/02

    CPC分类号： C08F8/00 ,  C08F297/04 ,  C08L53/02 ,  C08L53/025 ,  C08L95/00 ,  C08L2666/02 ,  C09J7/22 ,  C09J7/38 ,  C09J7/387 ,  C09J153/02 ,  C09J153/025 ,  C09J2453/00 ,  C08L2666/24

    摘要： A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.

    摘要翻译： 一种二阶改性嵌段共聚物，其可以通过使一级改性嵌段共聚物与二级改性剂反应而得到，其中一级改性嵌段共聚物包含与碱结合的碱嵌段共聚物和含官能团的一级改性基团 嵌段共聚物，其中所述碱嵌段共聚物包含至少一种主要由乙烯基芳族烃单体单元和至少一个主要由共轭二烯单体单元组成的聚合物嵌段的聚合物嵌段，并且其中所述二级改性剂具有特定官能团， 与一级改性嵌段共聚物的一级改性基团的官能团反应。 含有二级改性嵌段共聚物的聚合物组合物的二阶改性嵌段共聚物以及热塑性树脂和/或橡胶状聚合物。

    Modified block copolymer composition
    10.
    发明授权
    Modified block copolymer composition 有权
    改性嵌段共聚物组成

    公开(公告)号：US07122594B2

    公开(公告)日：2006-10-17

    申请号：US10480201

    申请日：2002-04-24

    申请人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeki Takayama ,  Toshinori Shiraki

    发明人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeki Takayama ,  Toshinori Shiraki

    IPC分类号： B60C3/04 ,  C08K5/5415

    CPC分类号： C08K3/22 ,  C08F8/04 ,  C08F8/30 ,  C08F2800/20 ,  C08K3/01 ,  C08K3/36 ,  C08L53/005 ,  C08L53/025 ,  C08L53/02 ,  C08L2666/06 ,  C08F297/04 ,  C08F8/42

    摘要： A modified block copolymer composition comprising (1) 100 parts by weight of a modified block copolymer consisting of vinyl aromatic hydrocarbons and conjugated dienes, containing a functional group having at least one group selected from the group consisting of a hydroxide group, an epoxy group, an amino group, a silanol group and an alkoxysilane group, or a hydrogenation product of the copolymer, and (2) 0.5 to 50 parts by weight at least one of fillers selected from the group consisting of silica-based inorganic fillers, metal oxides and metal hydroxides is disclosed. This modified block copolymer composition is excellent in heat resistance, mechanical strength, transparency, abrasion resistance, and processability.

    摘要翻译： 一种改性嵌段共聚物组合物，其包含（1）100重量份由乙烯基芳烃和共轭二烯构成的改性嵌段共聚物，其含有具有至少一个选自氢氧基，环氧基， 氨基，硅烷醇基和烷氧基硅烷基，或该共聚物的氢化产物，和（2）0.5至50重量份的至少一种选自二氧化硅基无机填料，金属氧化物和 公开了金属氢氧化物。 该改性嵌段共聚物组合物的耐热性，机械强度，透明性，耐磨性和加工性优异。