摘要:
A supported catalyst for fuel cell includes a conductive carrier and platinum supported on the conductive carrier. A 90% particle diameter D90 on a cumulative particle size curve obtained by determining a particle size distribution of the supported catalyst by a light scattering method is 28 μm or less.
摘要:
A method for producing a gold fine particle-supported carrier catalyst for a fuel cell, which reduces a gold ion in a liquid phase reaction system containing a carbon carrier by means of an action of a reducing agent, to reduce the gold ion, deposit, and support a gold fine particle on the carbon carrier, wherein a reduction rate of the gold ion is set within the range of 330 to 550 mV/h, and pH is set within the range of 4.0 to 6.0 to perform the reduction of the gold ion, deposition, and support of the gold fine particle.
摘要:
A method for producing a gold fine particle-supported carrier catalyst for a fuel cell, which reduces a gold ion in a liquid phase reaction system containing a carbon carrier by means of an action of a reducing agent, to reduce the gold ion, deposit, and support a gold fine particle on the carbon carrier, wherein a reduction rate of the gold ion is set within the range of 330 to 550 mV/h, and pH is set within the range of 4.0 to 6.0 to perform the reduction of the gold ion, deposition, and support of the gold fine particle.
摘要:
A fuel cell having an excellent life property is achieved. A supported catalyst for a fuel cell includes a catalytic particle made of an alloy of platinum and gold, and a conductive carrier supporting the catalytic particle. 50% or more of gold forms a solid solution with platinum.
摘要:
To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less.A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.
摘要:
To enhance the activation of a catalyst comprising an alloy of platinum and cobalt, thereby providing an electrode catalyst for fuel cell whose battery output and fuel efficiency are high, and thereby providing a production process of the same.An electrode catalyst according to the present invention for fuel cell is an electrode catalyst for fuel cell in which catalytic particles comprising platinum and cobalt are loaded on a conductive support, and is characterized in that a compositional (molar) ratio of said catalytic particles is platinum:cobalt=3:1-5:1: In the range of platinum:cobalt=3:1-5:1, a high battery voltage is obtainable. When the proportion of platinum is less than platinum: cobalt=3:1, the elution of cobalt from out of catalyst increases. On the contrarily, when the proportion of platinum is more than platinum: cobalt=5:1, the catalytic activities become low.
摘要:
To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less.A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.
摘要:
An object of the present invention is to provide a supported catalyst for a fuel cell having a high activity, a method of manufacturing thereof, and a fuel cell including the supported catalyst for a fuel cell. A supported catalyst for a fuel cell of the present invention includes a conductive carrier and catalyst particle supported on the conductive carrier and contains platinum. The ratio of the mass of oxygen to the mass of the catalyst particle measured by using an inert gas fusion-nondispersive infrared absorption method is 4 mass % or less.