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    Water and oil repellent composition
    3.
    发明申请
    Water and oil repellent composition 审中-公开
    防水防油组成

    公开(公告)号：US20050267241A1

    公开(公告)日：2005-12-01

    申请号：US11106641

    申请日：2005-04-15

    申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

    发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

    IPC分类号： C09K3/18 ,  C08F18/20

    CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

    摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

    摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。 作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为 至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

    Aqueous antifouling composition, process for its production and product treated therewith
    4.
    发明授权
    Aqueous antifouling composition, process for its production and product treated therewith 有权
    水性防污组合物，其生产方法和用其处理的产物

    公开(公告)号：US06271283B1

    公开(公告)日：2001-08-07

    申请号：US09383399

    申请日：1999-08-26

    申请人： Toyomichi Shimada ,  Yuichi Omori ,  Takashige Maekawa

    发明人： Toyomichi Shimada ,  Yuichi Omori ,  Takashige Maekawa

    IPC分类号： C08K556

    CPC分类号： C08F220/22 ,  D06M15/263 ,  D06M15/27 ,  D06M15/277 ,  Y10T428/31544

    摘要： An aqueous antifouling composition comprising fine particles of a copolymer which comprises the following polymer units (a), (b) and (c) and which has a glass transition temperature of at most 5° C., and an aqueous medium in which the fine particles are dispersed: (a) polymer units of a (meth)acrylate having a polyfluoroalkyl group, (b) polymer units of an alkyl acrylate wherein the carbon number of the alkyl group is from 2 to 12, and (c) polymer units of a (meth)acrylic monoester of a polyol.

    摘要翻译： 一种水性防污组合物，其包含共聚物的细颗粒，其包含以下聚合物单元（a），（b）和（c），并且其玻璃化转变温度为至多5℃，以及水性介质， 颗粒分散：（a）具有多氟烷基的（甲基）丙烯酸酯的聚合物单元，（b）丙烯酸烷基酯的聚合物单元，其中烷基的碳数为2至12，和（c）聚合物单元 多元醇的（甲基）丙烯酸单酯。

    Aqueous dispersion type antisoiling composition
    6.
    发明授权
    Aqueous dispersion type antisoiling composition 有权
    水分散型防污组合物

    公开(公告)号：US06251984B1

    公开(公告)日：2001-06-26

    申请号：US09433725

    申请日：1999-11-04

    申请人： Toyomichi Shimada ,  Takashige Maekawa

    发明人： Toyomichi Shimada ,  Takashige Maekawa

    IPC分类号： C08L7500

    CPC分类号： D06M15/576 ,  D06M13/428 ,  D06M15/277

    摘要： An aqueous dispersion type antisoiling composition comprising an aqueous medium, and fine particles of the following reaction product (A) and fine particles of the following addition polymer (B), dispersed in the aqueous medium, or an aqueous medium, and fine particles comprising the reaction product (A) and the addition polymer (B), dispersed in the aqueous medium: Reaction product (A): a reaction product of compounds (a1), (a2) and (a3); Compound (a1): a compound having a polyfluoroalkyl group and a group having an active hydrogen atom reactive with an isocyanate group; Compound (a2): a compound having no polyfluoroalkyl group and a group having an active hydrogen atom reactive with an isocyanate group; Compound (a3): a polyisocyanate compound; Addition polymer (B): a copolymer comprising polymer units of a polyfluoroalkyl group-containing (meth)acrylate and polymer units of methyl methacrylate.

    摘要翻译： 包含水性介质的水分散型防污组合物和下列反应产物（A）的细颗粒和分散在水性介质中的下述加成聚合物（B）的微粒或水性介质，以及包含 分散在水性介质中的反应产物（A）和加成聚合物（B）：反应产物（A）：化合物（a1），（a2）和（a3）的反应产物;化合物（a1） 具有与异氰酸酯基反应的活性氢原子的基团;化合物（a2）：不具有多氟烷基的化合物和具有与异氰酸酯基反应的活性氢原子的基团;化合物（a3）：多异氰酸酯化合物 ;加成聚合物（B）：包含含聚氟烷基的（甲基）丙烯酸酯的聚合物单元和甲基丙烯酸甲酯的聚合物单元的共聚物。

    Water and oil repellent composition
    8.
    发明授权
    Water and oil repellent composition 有权
    防水防油组成

    公开(公告)号：US08609795B2

    公开(公告)日：2013-12-17

    申请号：US11940577

    申请日：2007-11-15

    申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

    发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

    IPC分类号： C08F118/00

    CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

    摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

    摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。 作为必要成分的防水斥油剂组合物，其含有含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：含有Rf基的单体，其形成 不含熔点或熔点至多55℃的光聚合物，归因于衍生自Rf基团的微晶，玻璃化转变点至少为20℃。单体（b）：不具有Rf基团的单体 并具有可交联的官能团。

    Water- and- oil repellent composition and process for producing the same
    9.
    发明授权
    Water- and- oil repellent composition and process for producing the same 失效
    拒水拒油剂组合物及其制备方法

    公开(公告)号：US06610775B1

    公开(公告)日：2003-08-26

    申请号：US09869330

    申请日：2001-09-25

    申请人： Kazuya Oharu ,  Yuriko Kaida ,  Toyomichi Shimada ,  Takashige Maekawa

    发明人： Kazuya Oharu ,  Yuriko Kaida ,  Toyomichi Shimada ,  Takashige Maekawa

    IPC分类号： C08L7500

    CPC分类号： D06M15/263 ,  C08F220/22 ,  C08F220/26 ,  C08F290/02 ,  C09K3/18 ,  D06M13/165 ,  D06M13/17 ,  D06M15/27 ,  D06M15/277 ,  D06M15/53 ,  D06M2101/34 ,  D06M2200/11 ,  D06M2200/12

    摘要： A water dispersion type water and oil repellent composition capable of imparting highly long-lasting water and oil repellency to fibers of various materials. It comprises a polymer which essentially contains polymerized units of a (meth)acrylate having a polyfluoroalkyl group and polymerized units of a polymerizable monomer which essentially contains a polymerizable unsaturated group and a hydroxyl group and in which the polymerizable unsaturated group and the hydroxyl group are connected to each other through 7 or more covalent bonds, a surfactant which contains a nonionic surfactant in an amount of from 60 to 100 wt %, an aqueous medium, and a cross-linkable compound.

    摘要翻译： 一种水分散型斥水斥油剂组合物，其能够对各种材料的纤维赋予高度持久的拒水拒油性。 它包括聚合物，其基本上包含具有多氟烷基的（甲基）丙烯酸酯的聚合单元和基本上包含可聚合不饱和基团和羟基并且其中可聚合不饱和基团和羟基连接的可聚合单体的聚合单元 通过7个以上共价键彼此相互接触，含有60-100重量％的非离子表面活性剂，水性介质和可交联化合物的表面活性剂。

    Water repellent composition
    10.
    发明授权
    Water repellent composition 有权

    公开(公告)号：US06590035B2

    公开(公告)日：2003-07-08

    申请号：US09984401

    申请日：2001-10-30

    申请人： Toyomichi Shimada ,  Kyoichi Kaneko ,  Takashige Maekawa

    发明人： Toyomichi Shimada ,  Kyoichi Kaneko ,  Takashige Maekawa

    IPC分类号： C08L2712

    CPC分类号： D06M15/29 ,  C08L33/06 ,  C08L33/16 ,  D06M15/263 ,  D06M15/277 ,  D06M15/285 ,  D06M2200/12 ,  C08L2666/04

    摘要： A water repellent composition is provided containing the polymers (A) and (B), wherein polymers (A) and (B) are not present in the same particles, wherein polymer (A) is an addition polymer having at least 60 mass % of polymerized units of a (meth)acrylate (a) having a polyfluoroalkyl group, and 0-40 mass % of a methacrylate (b) having a long chain alkyl group and not a polyfluoroalkyl group, and, if necessary, polymerized units of a polymerizable monomer (x) other than monomers (a) and (b), polymer (B) is an addition polymer having 0-60 mass % of monomer (a), and at least 30 mass % of polymerized units of a polymerizable monomer (c), other than monomers (a) and (b), and, if necessary, polymerized units of a monomer (y) other than monomers (a) and (c), along with an article treated therewith and the method of treating an article with the water repellent composition.