摘要:
In the production of a dried acrylamide polymer by polymerizing, in an aqueous medium, acrylamide alone or a monomer mixture comprising 50 mole % or more of acrylamide and at least one monomer copolymerizable therewith with a radical initiator, and then drying the resulting hydrous acrylamide polymer, the allowing of at least one of the following compounds [I], [II] and [III] to be present in the drying step or a step prior thereto enables the dried acrylamide polymer having a high molecular weight and a good dissolvability in water to be obtained:[I] a non-polymerizable compound having in its molecule at least one group represented by the formula, ##STR1## wherein R.sub.1 is H or an alkyl group having up to 4 carbon atoms, [II] a compound represented by the formula, R.sub.2 --S--C.sub.n H.sub.2n X wherein n is an integer of 1 to 8, R.sub.2 is an alkyl group, an aryl group or --C.sub.n H.sub.2n X, in which X is --OH, --COOH (or its salt), --CN or --CONH.sub.2, and[III] a compound represented by the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are H, alkali metals or alkyl or aryl groups.
摘要翻译:在水性介质中单独使用丙烯酰胺或含有50摩尔%以上丙烯酰胺的单体混合物和至少一种可与其自由基引发剂共聚的单体的聚合反应生产干燥的丙烯酰胺聚合物,然后干燥得到的含水丙烯酰胺聚合物 ,允许至少一种以下化合物[I],[II]和[III]化合物存在于干燥步骤或之前的步骤中,使得干燥的丙烯酰胺聚合物具有高分子量和在水中的良好溶解性 [I]在其分子中具有至少一个由下式表示的基团的非聚合性化合物,其中R 1为H或具有至多4个碳原子的烷基,[II]表示的化合物 其中n为1〜8的整数,R 2为烷基,芳基或-C n H 2n,其中X为-OH,-COOH(或其盐),-CN或 - CONH 2和[III]由下式表示的化合物,其中R 3,R 4和R 3 5是H,碱金属或烷基或芳基。
摘要:
In the production of a dried acrylamide polymer by polymerizing, in an aqueous medium, acrylamide alone or a monomer mixture comprising 50 mole % or more of acrylamide and at least one monomer copolymerizable therewith with a radical initiator, and then drying the resulting hydrous acrylamide polymer, the allowing of 2-mercaptobenzimidazole to be present in the drying step or a step prior thereto enables the dried acrylamide polymer having a high molecular weight and a good dissolvability in water to be obtained.
摘要:
When an alkaline substance is added to and mixed with aggregates of the mutually adhering blobs of a hydrogel of an acrylamide polymer, (1) a mixing tank in which the portion to be contacted with the hydrogel of an acrylamide polymer is made of a chromium-plated material is used, and (2) to said hydrogel aggregates is added at least one compound represented by the general formulae: ##STR1## wherein R.sub.1 is a residue obtained by removing two OH groups from a saturated dihydric alcohol having 2 to 4 carbon atoms, and R.sub.2 is a residue obtained by removing three OH groups from a saturated trihydric alcohol having 3 to 6 carbon atoms, and having an average molecular weight of 500 to 5,000, whereby the hydrolysis of the acrylamide polymer can be achieved at a high efficiency while preventing the mutual adhesion of the hydrogel aggregates and also reducing the adhesion of the aggregates to the interior surface of the mixing tank to such an extent that there is substantially no problem of adhesion.
摘要翻译:当将碱性物质加入并与丙烯酰胺聚合物的水凝胶的相互粘合的团块的混合物混合时,(1)混合罐,其中与丙烯酰胺聚合物的水凝胶接触的部分由铬 - (2)对所述水凝胶聚集体加入至少一种由以下通式表示的化合物:HO [C 3 H 6 O] n H(I)其中R 1是残基 通过从具有2〜4个碳原子的饱和二元醇中除去2个OH基而获得的R 2是通过从具有3〜6个碳原子的饱和三元醇除去3个OH基而得到的残基,平均分子量为500〜 5,000,从而可以高效率地实现丙烯酰胺聚合物的水解,同时防止水凝胶聚集体的相互粘附并且还降低聚集体到混合罐的内表面的粘附程度,使得存在s 基本上没有粘附问题。
摘要:
Acrylamide polymers having remarkably high molecular weights can be obtained by polymerizing acrylamide or a monomer mixture comprising a preponderant quantity of acrylamide in an aqueous medium with the use of a specific redox initiator and a specific azo compound initiator. The polymerization initiator used in this porcess comprises a combination of a persulfate, formaldehyde sodium sufoxylate and 2,2'-azobis-2-amidinopropane.
摘要:
Polyacrylamide in the form of aquagel is partially hydrolyzed in such a manner that small pieces of the aquagel are mixed with an alkali agent in a specified quantity and maintained at a temperature of 50.degree. to 95.degree. C. until the hydrolysis reaches substantial completion. The quantity of the alkali agent is that corresponding to 1/1.1 to 1/3 of the hydrolysis percentage desired of the final partially hydrolyzed polyacrylamide. The partially hydrolyzed polyacrylamide thus produced is characterized by uniform hydrolysis evidenced by its improved solubility in water and a pH around 7 of its aqueous solution. The term "aquagel" is herein used interchangeably with a term "hydrogel".
摘要:
Apparatus for stirring hydrogel particles of a water-soluble polymer made as a tank defined by a drum within which is housed an inner drum. Water-soluble polymers are introduced through a top opening in the tank into an annular space defined by the inner wall surfaces of the tank and the outer wall surfaces of the inner drum. The water-soluble polymer contents in the annular space are stirred by vanes mounted on a corresponding vertically disposed driven arms. The vanes have leading surfaces advanced in different circular paths within the annular space. One of the vane stirring arms and vane thereon is disposed to travel along a circular path in the vicinity of the inner surfaces of the tank and the other stirring arm vane and corresponding vane are advanced along a circular path in the vicinity of the outer wall surfaces of the inner drum. The leading surfaces of the vanes are disposed at an angle relative to a corresponding radial plane passing the annular space within which the water-soluble polymer contents are stirred. The vanes urge the contents inwardly of the space away from the inner wall surfaces of the tank and outer wall surfaces of the inner drum respectively. The leading surfaces can be disposed to effectively urge the contents being stirred upwardly away from the bottom by an upward component of the force applied upon advancement of the vanes.
摘要:
Disclosed is a digital camera 2 including: a communication control unit 24 that receives album information A transmitted from a display control device and formed of a plurality of JPEG image files and a play list indicating a linkage among the files; a recording medium 25 that records the album information; an image display unit 222 that displays images of the plurality of recorded JPEG image files; and a CPU 261 that performs processing for displaying, on the image display unit, images of JPEG image files associated with one another by image linkage information of the play list among the plurality of JPEG image files based on an input of an image switching instruction from the operation input unit 231.
摘要:
A camera device comprises a movable type optical system, a driving unit which drives the optical system, and a control unit which makes the driving unit start driving of the optical system to a predetermined position by an initialization of the optical system, before other initializations than the initialization of the optical system, when the camera device is started up in a state in which an operation mode for photographing is set.
摘要:
Disclosed is a digital camera 2 including: a communication control unit 24 that receives album information A transmitted from a display control device and formed of a plurality of JPEG image files and a play list indicating a linkage among the files; a recording medium 25 that records the album information; an image display unit 222 that displays images of the plurality of recorded JPEG image files; and a CPU 261 that performs processing for displaying, on the image display unit, images of JPEG image files associated with one another by image linkage information of the play list among the plurality of JPEG image files based on an input of an image switching instruction from the operation input unit 231.
摘要:
A method includes specifying an image area which is contained in the subject-present image taken and in which nonflatness is less than or equal to a predetermined value, determining whether or not a range of the specified image area in the subject-present image in which the nonflatness is less than or equal to a predetermined value is greater than or equal to a predetermined range, generating an extraction background image used to extract a subject area in the subject-present image containing the subject, from the image area when the range of the image area in which the nonflatness is less than or equal to a predetermined value is determined to be greater than or equal to the predetermined range, and extracting the subject area from the subject-present image based on information on a difference between each pixel in the extraction background image and a corresponding pixel in the subject-present image.