摘要:
The present invention provides a method of manufacturing a porous thick film of an oxide that has extremely few cracks and can be satisfactorily used as an oxygen partial pressure detecting part of an oxygen sensor. The present invention relates to a method of manufacturing such a porous thick film as an oxygen partial pressure detecting part of a resistive oxygen sensor comprising taking a fine particle powder of an oxide containing cerium oxide as a raw material powder, preparing a paste containing the oxide, printing the paste onto a substrate by screen printing, calcining and sintering, the method comprising a step of carrying out heat treatment to effect particle growth from the average particle diameter of the raw material powder to a particle diameter less than the average particle diameter of the ultimately obtained thick film, a step of mixing the particle growth-effected powder with a solvent, a step of dispersing agglomerated particles in the solvent, a step of removing a precipitate, a step of evaporating off the solvent, and a step of mixing the resulting oxide with an organic binder to obtain the paste.
摘要:
A boron carbide based sintered body having a four-point flexural strength of at least 400 MPa and a fracture toughness of at least 2.8 MPa·m1/2, which has the following two preferred embodiments. (1) A boron carbide-titanium diboride sintered body obtained by sintering a mixed powder of a B4C powder, a TiO2 powder and a C powder while reacting them under a pressurized condition and comprising from 95 to 70 mol % of boron carbide and from 5 to 30 mol % of titanium diboride, wherein the boron carbide has a maximum particle diameter of at most 5 μm. (2) A boron carbide-chromium diboride sintered body containing from 10 to 25 mol % of CrB2 in B4C, wherein the sintered body has a relative density of at least 90%, boron carbide particles in the sintered body have a maximum particle diameter of at most 100 μm, and the abundance ratio (area ratio) of boron carbide particles of from 10 to 100 μm to boron carbide particles having a particle diameter of at most 5 μm, is from 0.02 to 0.6.
摘要:
A boron carbide based sintered body having a four-point flexural strength of at least 400 MPa and a fracture toughness of at least 2.8 MPa·m1/2, which has the following two preferred embodiments. (1) A boron carbide-titanium diboride sintered body obtained by sintering a mixed powder of a B4C powder, a TiO2 powder and a C powder while reacting them under a pressurized condition and comprising from 95 to 70 mol % of boron carbide and from 5 to 30 mol % of titanium diboride, wherein the boron carbide has a maximum particle diameter of at most 5 μm. (2) A boron carbide-chromium diboride sintered body containing from 10 to 25 mol % of CrB2 in B4C, wherein the sintered body has a relative density of at least 90%, boron carbide particles in the sintered body have a maximum particle diameter of at most 100 μm, and the abundance ratio (area ratio) of boron carbide particles of from 10 to 100 μm to boron carbide particles having a particle diameter of at most 5 μm, is from 0.02 to 0.6.
摘要:
A boron carbide based sintered body having a four-point flexural strength of at least 400 MPa and a fracture toughness of at least 2.8 MPa·m1/2, which has the following two preferred embodiments. (1) A boron carbide-titanium diboride sintered body obtained by sintering a mixed powder of a B4C powder, a TiO2 powder and a C powder while reacting them under a pressurized condition and comprising from 95 to 70 mol % of boron carbide and from 5 to 30 mol % of titanium diboride, wherein the boron carbide has a maximum particle diameter of at most 5 μm. (2) A boron carbide-chromium diboride sintered body containing from 10 to 25 mol % of CrB2 in B4C, wherein the sintered body has a relative density of at least 90%, boron carbide particles in the sintered body have a maximum particle diameter of at most 100 μm, and the abundance ratio (area ratio) of boron carbide particles of from 10 to 100 μm to boron carbide particles having a particle diameter of at most 5 μm, is from 0.02 to 0.6.
摘要:
A boron carbide based sintered body having a four-point flexural strength of at least 400 MPa and a fracture toughness of at least 2.8 MPa·m1/2, which has the following two preferred embodiments. (1) A boron carbide-titanium diboride sintered body obtained by sintering a mixed powder of a B4C powder, a TiO2 powder and a C powder while reacting them under a pressurized condition and comprising from 95 to 70 mol % of boron carbide and from 5 to 30 mol % of titanium diboride, wherein the boron carbide has a maximum particle diameter of at most 5 μm. (2) A boron carbide-chromium diboride sintered body containing from 10 to 25 mol % of CrB2 in B4C, wherein the sintered body has a relative density of at least 90%, boron carbide particles in the sintered body have a maximum particle diameter of at most 100 μm, and the abundance ratio (area ratio) of boron carbide particles of from 10 to 100 μm to boron carbide particles having a particle diameter of at most 5 μm, is from 0.02 to 0.6.
摘要:
A boron carbide based sintered body having a four-point flexural strength of at least 400 MPa and a fracture toughness of at least 2.8 MPa·m1/2, which has the following two preferred embodiments. (1) A boron carbide-titanium diboride sintered body obtained by sintering a mixed powder of a B4C powder, a TiO2 powder and a C powder while reacting them under a pressurized condition and comprising from 95 to 70 mol % of boron carbide and from 5 to 30 mol % of titanium diboride, wherein the boron carbide has a maximum particle diameter of at most 5 μm. (2) A boron carbide-chromium diboride sintered body containing from 10 to 25 mol % of CrB2 in B4C, wherein the sintered body has a relative density of at least 90%, boron carbide particles in the sintered body have a maximum particle diameter of at most 100 μm, and the abundance ratio (area ratio) of boron carbide particles of from 10 to 100 μm to boron carbide particles having a particle diameter of at most 5 μm, is from 0.02 to 0.6.
摘要:
A boron carbide based sintered body having a four-point flexural strength of at least 400 MPa and a fracture toughness of at least 2.8 MPa·m1/2, which has the following two preferred embodiments. (1) A boron carbide-titanium diboride sintered body obtained by sintering a mixed powder of a B4C powder, a TiO2 powder and a C powder while reacting them under a pressurized condition and comprising from 95 to 70 mol % of boron carbide and from 5 to 30 mol % of titanium diboride, wherein the boron carbide has a maximum particle diameter of at most 5 μm. (2) A boron carbide-chromium diboride sintered body containing from 10 to 25 mol % of CrB2 in B4C, wherein the sintered body has a relative density of at least 90%, boron carbide particles in the sintered body have a maximum particle diameter of at most 100 μm, and the abundance ratio (area ratio) of boron carbide particles of from 10 to 100 μm to boron carbide particles having a particle diameter of at most 5 μm, is from 0.02 to 0.6.
摘要:
The present invention relates to a chemical reaction system for efficiently excluding nitrogen oxides with low power consumption when excess oxygen is present in exhaust gas, to a method of use therefor, to an activation method therefor, and to a reaction method for oxidizing or reducing by the use of an oxidation-reduction reactor with high selectivity without the need to supply or exchange a reducing agent or oxidizing agent.
摘要:
A sintered ceramic article formed mainly of alumina, having a chemical composition of from 1 to 10% by weight of La.sub.2 O.sub.3, from 0.01 to 0.1% by weight of SiO.sub.2, and the balance of Al.sub.2 O.sub.3 and containing these components in the form of corundum (.alpha.-Al.sub.2 O.sub.3) and lanthanum .beta.-alumina (La.sub.2 O.sub.3.llAl.sub.2 O.sub.3) and a method for the production of a sintered ceramic article formed mainly of alumina, comprising the steps of shaping a mixture of Al.sub.2 O.sub.3, La.sub.2 O.sub.3, and SiO.sub.2, calcining the shaped mixture in the air at a temperature in the range of from 600.degree. C. to 1000.degree. C., and further firing the calcined shaped mixture to a temperature in the range of from 1400.degree. C. to 1800.degree. C.
摘要翻译:主要由氧化铝形成的烧结陶瓷制品,其化学组成为1至10重量%的La 2 O 3,0.01至0.1重量%的SiO 2,余量的Al 2 O 3并含有刚玉形式的这些组分(α -Al 2 O 3)和镧β-氧化铝(La 2 O 3·AlAl 2 O 3)和主要由氧化铝形成的烧结陶瓷制品的制造方法,包括以下步骤:将Al 2 O 3,La 2 O 3和SiO 2的混合物成型, 空气在600℃至1000℃的温度范围内进一步煅烧,并将焙烧成型的混合物进一步焙烧至1400℃至1800℃的温度。
摘要:
The present invention provides a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high specific surface area porous cordierite body that is stable at high temperatures, and also provides methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body. The present invention relates to a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high temperature-stable, high specific surface area porous cordierite body comprising a porous structure having a prescribed porosity and formed of a needle-shaped cordierite crystal phase, and further relates to methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body, and by using porous cordierite constituted of needle-shaped crystals as a catalyst-supporting honeycomb structure, the present invention is able to inhibit sintering-induced reduction in the specific surface area. Since a honeycomb can be directly produced as the cordierite sinter itself, an inexpensive product can be provided through the simplifying the prior-art step of coating the interior of the honeycomb.