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公开(公告)号：US20060155016A1
公开(公告)日：2006-07-13
申请号：US10508621
申请日：2003-03-21
IPC分类号： C08K5/34
CPC分类号： C08K5/34922 , C08F283/12 , C08F290/068 , C08L51/08 , C08L2666/02
摘要： The invention relates to a curable composition comprising (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, and an organic compound which comprises a polymerizable group, (B) a compound having a melamine group and no polymerizable unsaturated groups and (C) a compound having at least two polymerizable groups in the molecule other than the component (B); and to cured products and laminates with a with low reflectance and superior chemical resistance.
摘要翻译： 本发明涉及一种可固化组合物，其包含（A）通过键合选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物而制备的颗粒，以及 包含可聚合基团的有机化合物，（B）具有三聚氰胺基团并且不具有可聚合不饱和基团的化合物和（C）在分子中除了组分（B）之外具有至少两个可聚合基团的化合物; 并且具有低反射率和优异的耐化学性的固化产品和层压材料。
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公开(公告)号：US07084187B2
公开(公告)日：2006-08-01
申请号：US10488472
申请日：2002-09-26
IPC分类号： C08J3/28
CPC分类号： C09D4/00 , C08F230/08
摘要： To provide a radiation-sensitive curable liquid resin composition having excellent applicability and capable of producing a film excelling in hardness, scratch resistance, adhesion, transparency, and appearance of the surface of the film.A curable liquid resin composition comprising: (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium to a specific organic compound which comprises a polymerizable unsaturated group and a group shown by —X—C(═Y)—NH— (wherein X is NH, O, or S, and Y is O or S), and preferably a silanol group, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a specific alkylene glycol organic solvent, and preferably (D) a polymerization initiator.
摘要翻译： 本发明提供一种具有优异适用性且能够制备出优异的薄膜表面的硬度，耐擦伤性，粘附性，透明性和外观的薄膜的辐射敏感性固化性液体树脂组合物。 一种可固化液体树脂组合物，其包含：（A）通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物键合到特定的 包含可聚合不饱和基团和由-XC（-Y）-NH-（其中X是NH，O或S，Y是O或S）表示的基团的有机化合物，优选硅烷醇基，（B） 在分子中具有两个以上聚合性不饱和基团的化合物，（C）特定的亚烷基二醇有机溶剂，优选（D）聚合引发剂。
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3.发明申请Radiation-curable resin composition for forming optical part and optical part 有权用于形成光学部件和光学部件的辐射固化树脂组合物公开(公告)号：US20050032927A1
公开(公告)日：2005-02-10
申请号：US10840416
申请日：2004-05-07
IPC分类号： G02B1/04 , C08F2/46 , C08F220/18 , C08F220/36 , C08F290/06 , C08G18/67 , C08G18/81 , C08L75/04 , C08G2/00 , C08J3/28
CPC分类号： C08G18/8175 , C08F220/18 , C08F220/36 , C08G18/672 , G02B1/04 , C08L33/14 , C08G18/48
摘要： To provide a UV-curable resin composition useful for forming optical parts such as optical lenses. A radiation-curable resin composition for optical parts, comprising (A) 5-70 wt % of urethane (meth)acrylate, (B) 0.1-70 wt % of benzyl (meth)acrylate, and (C) 10-70 wt % of an ethylenically unsaturated group-containing compound other than the components (A) and (B).
摘要翻译： 提供用于形成诸如光学透镜的光学部件的UV固化树脂组合物。 一种光学部件用放射线固化型树脂组合物，其含有（A）5-70重量％的氨基甲酸酯（甲基）丙烯酸酯，（B）0.1-70重量％的（甲基）丙烯酸苄基酯和（C）10-70重量％ 的除了组分（A）和（B）之外的含烯属不饱和基团的化合物。
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公开(公告)号：US20070155882A1
公开(公告)日：2007-07-05
申请号：US10552510
申请日：2004-04-05
CPC分类号： C09D5/006 , C08F290/068 , C08K3/22 , C08K9/06 , C09D5/24 , C09D7/62 , C09D11/101
摘要： To provide a curable liquid composition excelling in storage stability and curability and capable of forming a coat (film) which excels in antistatic properties, hardness, scratch resistance, and transparency on the surface of various substrates, a cured film of the composition, and an antistatic laminate. A curable liquid composition comprising (A) particles including an oxide of at least one element selected from the group consisting of indium, antimony, zinc, and tin as a major component, (B) a compound having at least two polymerizable unsaturated groups in the molecule, (C) a solvent in which solubility of the component (B) is less than 10 wt %, and (D) a solvent in which solubility of the component (B) is 10 wt % or more, the components (A) and (B) being uniformly dispersed or dissolved in the composition.
摘要翻译： 为了提供优异的储存稳定性和固化性的可固化液体组合物，并且能够形成在各种基材的表面上的抗静电性，硬度，耐刮擦性和透明性优异的涂层（膜），该组合物的固化膜和 抗静电层压板 一种可固化液体组合物，其包含（A）包含选自由铟，锑，锌和锡组成的组中的至少一种元素的氧化物的主要成分的颗粒，（B）具有至少两个可聚合不饱和基团的化合物 分子，（C）成分（B）的溶解度小于10重量％的溶剂，（D）成分（B）的溶解度为10重量％以上的成分（A） 和（B）均匀地分散或溶解在组合物中。
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公开(公告)号：US07060737B2
公开(公告)日：2006-06-13
申请号：US10471256
申请日：2002-03-29
IPC分类号： C08F290/06 , B29B71/04 , B35B5/16
CPC分类号： C08K3/22 , B32B5/00 , C08F2/44 , C09D4/06 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/257 , Y10T428/259 , C08F290/147
摘要： The invention relates to a curable resin composition, cured products thereof, and laminated materials. The curable composition comprises: (A-1) acicular oxide particles, the oxide being an oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, (B) a compound having two or more polymerizable unsaturated groups, (C) a photopolymerization initiator is provided. After cure, the composition has excellent scratch resistance. In addition, it may have excellent antistatic characteristics and transparency. In a preferred embodiment the composition also comprises (A-2) particles other than the acicular particles (A-1), being oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium.
摘要翻译： 本发明涉及可固化树脂组合物，其固化产物和层压材料。 可固化组合物包含：（A-1）针状氧化物颗粒，氧化物为选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物 ，（B）具有两个以上聚合性不饱和基团的化合物，（C）光聚合引发剂。 固化后，该组合物具有优异的耐划伤性。 另外，它具有优异的抗静电特性和透明度。 在一个优选的实施方案中，组合物还包含除了针状颗粒（A-1）之外的（A-2）颗粒，其是选自硅，铝，锆，钛，锌，锗， 铟，锡，锑和铈。
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公开(公告)号：US20080281015A1
公开(公告)日：2008-11-13
申请号：US10581251
申请日：2004-11-29
IPC分类号： C08F283/02 , C08L33/00 , C08L69/00
CPC分类号： C08F283/00 , C08F283/01 , C08F283/02 , C08F290/061 , C08L51/08 , G02B1/04 , C08F220/10 , C08L2666/02
摘要： A photocurable composition comprising the following components (A) to (D): (A) at least one of the (meth)acrylates having the structures shown by the formulas (1) and (2), wherein R1 represents a hydrogen atom or a halogen atom excluding a fluorine atom, R2 is a hydrogen atom, a halogen atom excluding a fluorine atom, Ph-C(CH3)2—, Ph-, or an alkyl group having 1-20 carbon atoms, and R3 represents —CH2—, —S—, or —C(CH3)2—; (B) a (meth)acrylate having three or more functional groups, excluding the (meth)acrylates of the component (A); (C) a radical photoinitiator; and (D) a polycarbonate polyol having a hydroxyl value of 10-100; wherein 5-50 wt % of the total acrylic components in the composition are methacrylate compounds. A photocurable composition produces a cured product possessing a high refractive index, excelling in heat resistance, showing only a small amount of warping, and being particularly useful as an optical part such as a prism lens sheet.
摘要翻译： 包含以下组分（A）至（D）的光固化性组合物：（A）至少一种具有式（1）和（2）所示结构的（甲基）丙烯酸酯，其中R 1， SUP>表示氢原子或不包括氟原子的卤素原子，R 2是氢原子，不包括氟原子的卤素原子，Ph-C（CH 3 CH 3） ）2 - ，Ph-或具有1-20个碳原子的烷基，R 3表示-CH 2 - ， - S - 或-C（CH 3）2 - ; （B）除了（A）成分的（甲基）丙烯酸酯以外，具有3个以上的官能团的（甲基）丙烯酸酯。 （C）自由基光引发剂; 和（D）羟值为10-100的聚碳酸酯多元醇; 其中组合物中5-50重量％的丙烯酸组分总数是甲基丙烯酸酯化合物。 可光固化组合物产生具有高折射率，耐热性优异，仅显示少量翘曲的固化产物，并且作为诸如棱镜透镜片的光学部件特别有用。
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7.发明授权Radiation-curable resin composition for forming optical part and optical part 有权用于形成光学部件和光学部件的辐射固化树脂组合物公开(公告)号：US07173072B2
公开(公告)日：2007-02-06
申请号：US10840416
申请日：2004-05-07
IPC分类号： C08F2/46
CPC分类号： C08G18/8175 , C08F220/18 , C08F220/36 , C08G18/672 , G02B1/04 , C08L33/14 , C08G18/48
摘要： To provide a UV-curable resin composition useful for forming optical parts such as optical lenses. A radiation-curable resin composition for optical parts, comprising (A) 5–70 wt % of urethane (meth)acrylate, (B) 0.1–70 wt % of benzyl (meth)acrylate, and (C) 10–70 wt % of an ethylenically unsaturated group-containing compound other than the components (A) and (B).
摘要翻译： 提供用于形成诸如光学透镜的光学部件的UV固化树脂组合物。 一种光学部件用放射线固化型树脂组合物，其含有（A）5-70重量％的氨基甲酸酯（甲基）丙烯酸酯，（B）0.1-70重量％的（甲基）丙烯酸苄基酯和（C）10-70重量％ 的除了组分（A）和（B）之外的含烯属不饱和基团的化合物。
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公开(公告)号：US20050070623A1
公开(公告)日：2005-03-31
申请号：US10488472
申请日：2002-09-26
IPC分类号： C08F2/54 , C08F220/34 , C09D4/00 , C09D183/08 , C08G2/00
CPC分类号： C09D4/00 , C08F230/08
摘要： To provide a radiation-sensitive curable liquid resin composition having excellent applicability and capable of producing a film excelling in hardness, scratch resistance, adhesion, transparency, and appearance of the surface of the film. A curable liquid resin composition comprising: (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium to a specific organic compound which comprises a polymerizable unsaturated group and a group shown by —X—C(═Y)—NH— (wherein X is NH, O, or S, and Y is O or S), and preferably a silanol group, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a specific alkylene glycol organic solvent, and preferably (D) a polymerization initiator.
摘要翻译： 本发明提供一种具有优异适用性且能够制备出优异的薄膜表面的硬度，耐擦伤性，粘附性，透明性和外观的薄膜的辐射敏感性固化性液体树脂组合物。 一种可固化液体树脂组合物，其包含：（A）通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物键合到特定的 包含可聚合不饱和基团和由-XC（= Y）-NH-（其中X是NH，O或S，Y是O或S）表示的基团的有机化合物，优选硅烷醇基，（B） 在分子中具有两个以上聚合性不饱和基团的化合物，（C）特定的亚烷基二醇有机溶剂，优选（D）聚合引发剂。
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公开(公告)号：US06319603B1
公开(公告)日：2001-11-20
申请号：US09260507
申请日：1999-03-02
IPC分类号： G02B604
CPC分类号： G03F7/038 , C03C25/106 , C08F265/06 , C08G59/68 , C08L63/00 , C09D151/003 , G03F7/032 , Y10T428/2938 , C08L2666/04 , C08F222/1006 , C08F2220/1825 , C08F220/14 , C08F220/32
摘要： A liquid curable resin composition comprising (1) a (meth)acrylate polymer having a weight average molecular weight relative to polystyrene standard of at least about 5,000, (2) a ring-opening polymerizable monomer containing at least one epoxy group, and (3) a cationic photopolymerization initiator is disclosed. The composition produces cured products which exhibit superior heat resistance, excellent mechanical strength, and superb adhesive characteristics, and is suitable for use as a photo-curable adhesive, a photo-curable sealing material, a resin for optical three-dimensional molding, and a coating material for optical fibers, and optical fiber ribbon matrix.
摘要翻译： 一种液体可固化树脂组合物，其包含（1）相对于聚苯乙烯标准重均分子量为至少约5,000的（甲基）丙烯酸酯聚合物，（2）含有至少一个环氧基的开环聚合单体和（3 ）阳离子光聚合引发剂。 该组合物产生显示出优异的耐热性，优异的机械强度和极好的粘合特性的固化产物，并且适合用作光固化性粘合剂，光固化型密封材料，光学三维成型用树脂和 光纤涂层材料和光纤带状基体。
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公开(公告)号：US06180741B2
公开(公告)日：2001-01-30
申请号：US09413883
申请日：1999-10-07
申请人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
IPC分类号： C08G77458
CPC分类号： G02B1/046 , C08G18/61 , C08G18/672 , C08L83/08 , C09D4/06 , C08G18/6674 , C08L83/00 , C08F290/148 , C08F290/147
摘要： A liquid curable resin composition exhibiting superior storing stability and suitable for use as a material for optical fiber ribbon matrix, a bundling material, and a material for up-jacketing fibers. The composition contains a first polydimethylsiloxane compound which contains (i) at least two urethane bonds, (ii) an unreactive organic group attached to at least one end of the first polydimethyl-siloxane, and (iii) a (meth)acrylol group attached to at least one end of the first polydimethylsiloxane, and a second polydimethylsiloxane compound which contains (i) at least two urethane bonds and (ii) an unreactive organic group attached to at least one end of the second polydimethylsiloxane, and optionally a third polysiloxane compound which does not contain urethane bonds.
摘要翻译： 一种液体固化树脂组合物，其显示出优良的储存稳定性，适合用作光纤带状基体材料，捆扎材料和上覆纤维材料。 该组合物包含第一聚二甲基硅氧烷化合物，其包含（i）至少两个氨基甲酸酯键，（ii）连接至第一聚二甲基硅氧烷的至少一个末端的非反应性有机基团，和（iii）（甲基）丙烯酰基 第一聚二甲基硅氧烷的至少一个末端和第二聚二甲基硅氧烷化合物，其包含（i）至少两个氨基甲酸酯键和（ii）连接到第二聚二甲基硅氧烷的至少一个末端的非反应性有机基团，以及任选的第三聚硅氧烷化合物， 不含氨基甲酸酯键。
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