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1.发明授权公开(公告)号：US07709415B2
公开(公告)日：2010-05-04
申请号：US10509087
申请日：2003-04-22
申请人： Nozomu Sugo , Hideharu Iwasaki , Takanori Kitamura , Tatsuo Morotomi , Tsuyoshi Kowaka , Teruhiro Okada , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
发明人： Nozomu Sugo , Hideharu Iwasaki , Takanori Kitamura , Tatsuo Morotomi , Tsuyoshi Kowaka , Teruhiro Okada , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
IPC分类号： C01B31/08
CPC分类号： H01G9/155 , C01B32/342 , H01M4/0471 , H01M4/583 , Y02E60/13
摘要： Activated carbon useful as polarizable electrode material for an electric double-layer capacitor can be obtained by mixing a carbonaceous material and an alkali metal hydroxide while maintaining a solid state, granulating the obtained mixture while maintaining its solid state, dehydrating the obtained granulated substance while maintaining its solid state, and subjecting the granulated dehydration product obtained in the dehydration step to an activation treatment. The preferred pressure of the granulation treatment in the granulation step is 0.01 to 300 Torr, and the preferred temperature of the granulation treatment is 90 to 140° C. The preferred pressure of the dehydration treatment in the dehydration step is 0.01 to 10 Torr, and the preferred temperature of the dehydration treatment is 200 to 400° C.
摘要翻译： 用作双电层电容器的可极化电极材料的活性炭可以通过在保持固体状态下混合碳质材料和碱金属氢氧化物同时保持固体状态使所得到的混合物成粒，同时保持所得粒状物质，同时保持 其固体状态，并将脱水步骤中获得的造粒脱水产物进行活化处理。 制粒工序中的造粒处理的优选压力为0.01〜300乇，造粒处理温度优选为90〜140℃。脱水工序中脱水处理的优选压力为0.01〜10乇， 脱水处理的优选温度为200〜400℃。
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2.发明申请公开(公告)号：US20050181941A1
公开(公告)日：2005-08-18
申请号：US10509087
申请日：2003-04-22
申请人： Nozomu Sugo , Hideharu Iwasaki , Takanori Kitamura , Tatsuo Morotomi , Tsuyoshi Kowaka , Teruhiro Okada , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
发明人： Nozomu Sugo , Hideharu Iwasaki , Takanori Kitamura , Tatsuo Morotomi , Tsuyoshi Kowaka , Teruhiro Okada , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
IPC分类号： C01B31/12 , H01G9/00 , H01G11/20 , H01G11/22 , H01G11/24 , H01G11/26 , H01G11/34 , H01G11/38 , H01G11/40 , H01G11/42 , H01G11/44 , H01G11/86
CPC分类号： H01G9/155 , C01B32/342 , H01M4/0471 , H01M4/583 , Y02E60/13
摘要： Activated carbon useful as polarizable electrode material for an electric double-layer capacitor can be obtained by mixing a carbonaceous material and an alkali metal hydroxide while maintaining a solid state, granulating the obtained mixture while maintaining its solid state, dehydrating the obtained granulated substance while maintaining its solid state, and subjecting the granulated dehydration product obtained in the dehydration step to an activation treatment. The preferred pressure of the granulation treatment in the granulation step is 0.01 to 300 Torr, and the preferred temperature of the granulation treatment is 90 to 140° C. The preferred pressure of the dehydration treatment in the dehydration step is 0.01 to 10 Torr, and the preferred temperature of the dehydration treatment is 200 to 400° C.
摘要翻译： 用作双电层电容器的可极化电极材料的活性炭可以通过在保持固体状态下混合碳质材料和碱金属氢氧化物同时保持固体状态使所得到的混合物成粒，同时保持所得粒状物质，同时保持 其固体状态，并将脱水步骤中获得的造粒脱水产物进行活化处理。 制粒工序中的造粒处理的优选压力为0.01〜300乇，造粒处理温度优选为90〜140℃。脱水工序中脱水处理的优选压力为0.01〜10乇， 脱水处理的优选温度为200〜400℃。
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3.发明申请公开(公告)号：US20050266990A1
公开(公告)日：2005-12-01
申请号：US10519399
申请日：2003-07-03
申请人： Hideharu Iwasaki , Nozomu Sugo , Mitsunori Hitomi , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
发明人： Hideharu Iwasaki , Nozomu Sugo , Mitsunori Hitomi , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
IPC分类号： B82Y30/00 , B82Y99/00 , C01B31/12 , H01G11/20 , H01G11/22 , H01G11/24 , H01G11/26 , H01G11/32 , H01G11/34 , H01G11/36 , H01G11/38 , H01G11/40 , H01G11/42 , H01G11/44 , H01G11/86 , H01M4/583 , C01B31/08
CPC分类号： H01G11/34 , C01B32/342 , Y02E60/13
摘要： In activated carbon obtained by subjecting a carbonaceous material to an activation treatment, the overall content of alkali metals is set at 100 ppm or less, or the overall content of heavy metals is set at 20 ppm or less and the overall content of alkali metals is set at 200 ppm or less. In cases where such activated carbon is used as a raw material in electronic devices, the formation of dendrites by the reductive deposition of alkali metals or heavy metals tends not to occur, so that problems such as short-circuiting or the like tend not to arise, and a good rate of self-discharge retention is shown.
摘要翻译： 在将碳质材料进行活化处理而得到的活性炭中，碱金属的总含量为100ppm以下，重金属的总含量为20ppm以下，碱金属的总量为 设定在200ppm以下。 在这种活性炭用作电子器件中的原料的情况下，不会发生通过还原沉积碱金属或重金属形成枝晶，因此不会出现短路等问题 ，并显示出良好的自放电保持率。
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4.发明授权公开(公告)号：US07759289B2
公开(公告)日：2010-07-20
申请号：US10519399
申请日：2003-07-03
申请人： Hideharu Iwasaki , Nozomu Sugo , Mitsunori Hitomi , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
发明人： Hideharu Iwasaki , Nozomu Sugo , Mitsunori Hitomi , Shushi Nishimura , Takeshi Fujino , Shigeki Oyama , Yuji Kawabuchi
IPC分类号： C01B31/08
CPC分类号： H01G11/34 , C01B32/342 , Y02E60/13
摘要： In activated carbon obtained by subjecting a carbonaceous material to an activation treatment, the overall content of alkali metals is set at 100 ppm or less, or the overall content of heavy metals is set at 20 ppm or less and the overall content of alkali metals is set at 200 ppm or less. In cases where such activated carbon is used as a raw material in electronic devices, the formation of dendrites by the reductive deposition of alkali metals or heavy metals tends not to occur, so that problems such as short-circuiting or the like tend not to arise, and a good rate of self-discharge retention is shown.
摘要翻译： 在将碳质材料进行活化处理而得到的活性炭中，碱金属的总含量为100ppm以下，重金属的总含量为20ppm以下，碱金属的总量为 设定在200ppm以下。 在这种活性炭用作电子器件中的原料的情况下，不会发生通过还原沉积碱金属或重金属形成枝晶，因此不会出现诸如短路等的问题 ，并显示出良好的自放电保持率。
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5.发明授权公开(公告)号：US07214646B1
公开(公告)日：2007-05-08
申请号：US10048470
申请日：2000-08-09
申请人： Takeshi Fujino , Shigeki Oyama , Naohiko Oki , Minoru Noguchi , Kenji Sato , Shushi Nishimura , Takashi Maeda , Yuji Kawabuchi , Takahiro Haga
发明人： Takeshi Fujino , Shigeki Oyama , Naohiko Oki , Minoru Noguchi , Kenji Sato , Shushi Nishimura , Takashi Maeda , Yuji Kawabuchi , Takahiro Haga
IPC分类号： C01B31/08
摘要： To produce activated carbon for an electrode of an electric double-layer capacitor, the following steps are carried out sequentially: a step of subjecting a massive mesophase pitch to a pulverizing treatment to provide a pulverized powder; a step of subjecting the pulverized powder to an infusibilizing treatment under conditions of a temperature in a range of 300° C. (inclusive) to 450° C. (inclusive) in the atmospheric air current, a step of subjecting the pulverized powder to a carbonizing treatment under conditions of a temperature in a range of 600° C. (inclusive) to 900° C. (inclusive) in an inert gas current to provide a carbonized powder, a step of subjecting the carbonized powder to an alkali activating treatment under conditions of a temperature in a range of 500° C. (inclusive) to 1,000° C. (inclusive) in an inert gas atmosphere, followed by the post treatments, thereby producing alkali-activated carbon, and a step of subjecting the alkali-activated carbon to a pulverizing treatment. If an electrode is produced using the activated carbon, the electrode density can be increased.
摘要翻译： 为了制造双电层电容器的电极用活性炭，依次进行以下步骤：将大量的中间相沥青进行粉碎处理以提供粉碎粉末的步骤; 在大气气流中，在温度范围为300℃〜450℃的条件下对粉碎粉进行渗透处理的工序，将粉碎粉末 在惰性气流中在600℃（含）〜900℃（以下）的温度条件下进行碳化处理，得到碳化粉末，将碳化粉末进行碱活化处理的工序 在惰性气体气氛中，在500℃（含）-100℃（含）范围内的温度条件进行后处理，从而制造碱活性炭， 活性炭进行粉碎处理。 如果使用活性炭制造电极，则可以提高电极密度。
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6.发明申请Process for producing activated carbon for electrode of electric double-layer capacitor 审中-公开双电层电容器电极活性炭生产工艺公开(公告)号：US20070183958A1
公开(公告)日：2007-08-09
申请号：US11727974
申请日：2007-03-29
申请人： Takeshi Fujino , Shigeki Oyama , Naohiko Oki , Minoru Noguchi , Kenji Sato , Shushi Nishimura , Takashi Maeda , Yuji Kawabuchi , Takahiro Haga
发明人： Takeshi Fujino , Shigeki Oyama , Naohiko Oki , Minoru Noguchi , Kenji Sato , Shushi Nishimura , Takashi Maeda , Yuji Kawabuchi , Takahiro Haga
IPC分类号： C01B31/02
摘要： To produce activated carbon for an electrode of an electric double-layer capacitor, the following steps are carried out sequentially: a step of subjecting a massive mesophase pitch to a pulverizing treatment to provide a pulverized powder; a step of subjecting the pulverized powder to an infusibilizing treatment under conditions of a temperature in a range of 300° C. (inclusive) to 450° C. (inclusive) in the atmospheric air current, a step of subjecting the pulverized powder to a carbonizing treatment under conditions of a temperature in a range of 600° C. (inclusive) to 900° C. (inclusive) in an inert gas current to provide a carbonized powder, a step of subjecting the carbonized powder to an alkali activating treatment under conditions of a temperature in a range of 500° C. (inclusive) to 1,000° C. (inclusive) in an inert gas atmosphere, followed by the post treatments, thereby producing alkali-activated carbon, and a step of subjecting the alkali-activated carbon to a pulverizing treatment. If an electrode is produced using the activated carbon, the electrode density can be increased.
摘要翻译： 为了制造双电层电容器的电极用活性炭，依次进行以下步骤：将大量的中间相沥青进行粉碎处理以提供粉碎粉末的步骤; 在大气气流中，在温度范围为300℃〜450℃的条件下对粉碎粉进行渗透处理的工序，将粉碎粉末 在惰性气流中在600℃（含）〜900℃（以下）的温度条件下进行碳化处理，得到碳化粉末，将碳化粉末进行碱活化处理的工序 在惰性气体气氛中，在500℃（含）-100℃（含）范围内的温度条件进行后处理，从而制造碱活性炭， 活性炭进行粉碎处理。 如果使用活性炭制造电极，则可以提高电极密度。
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公开(公告)号：US06589904B1
公开(公告)日：2003-07-08
申请号：US09712953
申请日：2000-11-16
IPC分类号： H01M488
摘要： The present invention provides an activated carbon produced by a process, which includes: activating a carbonaceous material, to obtain an activated carbonaceous material; and contacting the activated carbonaceous material with an acid. Another embodiment of the present invention provides an electrode for an electric double-layer capacitor, which includes the above-described activated carbon. Another embodiment of the present invention provides a filter, which includes the above-described activated carbon. Another embodiment of the present invention provides a shaped article, which includes the above-described activated carbon. Another embodiment of the present invention provides a method for producing activated carbon, which includes activating a carbonaceous material, to obtain an activated carbonaceous material; and contacting the activated carbonaceous material with an acid, to obtain the activated carbon. The acid-processed activated carbon has a strong affinity for water, and is particularly suitable for water purification. Electrodes produced by shaping the acid-processed activated carbon have the advantage of large electrostatic capacity per the unit volume, and are particularly suitable for capacitors.
摘要翻译： 本发明提供一种通过工艺制造的活性炭，其包括：活化碳质材料，得到活性碳质材料; 并且用活性炭材料与酸接触。本发明的另一个实施方案提供了一种包括上述活性炭的双电层电容器用电极。 本发明的另一个实施方案提供一种过滤器，其包括上述活性炭。 本发明的另一个实施方案提供了一种成型制品，其包括上述活性炭。 本发明的另一个实施方案提供了一种生产活性炭的方法，其包括活化碳质材料，以获得活性碳质材料; 并使活性碳质材料与酸接触，得到活性炭。 酸处理的活性炭对水具有很强的亲和力，特别适用于水净化。 通过成型酸处理的活性炭制成的电极具有每单位体积大的静电容量的优点，并且特别适用于电容器。
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公开(公告)号：US06207255B1
公开(公告)日：2001-03-27
申请号：US08834020
申请日：1997-04-11
IPC分类号： B32B326
CPC分类号： B01J20/28033 , B01D39/083 , B01D39/086 , B01D39/2062 , B01D53/02 , B01D2239/0241 , B01D2239/0407 , B01D2239/0435 , B01D2239/0618 , B01D2239/065 , B01D2239/0668 , B01D2239/0681 , B01D2239/1233 , B01D2239/1241 , B01D2253/102 , B01D2253/25 , B01D2253/304 , B01D2253/34 , B01D2257/90 , B01D2259/4566 , B01J20/28023 , B01J20/28026 , B01J20/2803 , Y10T428/24636 , Y10T442/174 , Y10T442/20 , Y10T442/2139 , Y10T442/2738 , Y10T442/2861 , Y10T442/3049 , Y10T442/3179 , Y10T442/3195 , Y10T442/322
摘要： Preferably configured in ridge and recess irregularity, the inventive article provides adsorption of malodor components in air and also dust collecting function. It comprises woven sheet having coarse three dimensional structure whose areas of sheet surface as well as internal fiber structure allowable to contact to incoming outer air are formed with a binder layer made of latex or emulsion or non-solvent adhesive and such binder layer is adhered with activated carbon particles partially exposed. The process of adhereing activated carbon particles is conveniently performed by a fluidizing bed. The inventive sheet form fabric incorporates the particles with a high void ratio and uniformity and thereby exhibits high adsorptive rate and capacity, and exceedingly low pressure loss with such result that it is applicable regardless of high or air wind rate. Preferable use is a filter element of air-conditioner for cars.
摘要翻译： 优选地以脊部和凹部不规则的形式配置，本发明的制品提供恶臭成分在空气中的吸附以及除尘功能。 它包括具有粗糙三维结构的编织片，其片材表面面积以及允许接触进入的外部空气的内部纤维结构形成有由胶乳或乳液或非溶剂粘合剂制成的粘合剂层，并且这种粘合剂层与 活性炭颗粒部分暴露。 粘附活性炭颗粒的方法方便地通过流化床进行。 本发明的片状织物具有高空隙率和均匀性的颗粒，从而表现出高的吸附速率和容量，以及非常低的压力损失，因此无论高风量还是空气风速都适用。 优选的是用于汽车的空调的过滤元件。
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9.发明授权公开(公告)号：US07410510B2
公开(公告)日：2008-08-12
申请号：US10571061
申请日：2004-09-10
申请人： Takeshi Fujino , Shushi Nishimura
发明人： Takeshi Fujino , Shushi Nishimura
IPC分类号： H01G9/00
CPC分类号： H01G11/34 , Y02E60/13 , Y10T29/417
摘要： A process for producing an activated carbon for an electrode of an electric double-layer capacitor, includes a step of subjecting a carbonized material to an alkali activating treatment, wherein the carbonized material has an average true specific gravity of 1.450 to 1.650 and a variation of the true specific gravities of 0.025 or less.
摘要翻译： 一种双电层电容器用电极活性炭的制造方法，其特征在于，包括对碳化物进行碱活化处理的步骤，其中，碳化物的平均真比重为1.450〜1.650， 真实比重为0.025以下。
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10.发明申请公开(公告)号：US20070026624A1
公开(公告)日：2007-02-01
申请号：US10571061
申请日：2004-09-10
申请人： Takeshi Fujino , Shushi Nishimura
发明人： Takeshi Fujino , Shushi Nishimura
IPC分类号： H01L21/20
CPC分类号： H01G11/34 , Y02E60/13 , Y10T29/417
摘要： A process for producing an activated carbon for an electrode of an electric double-layer capacitor, includes a step of subjecting a carbonized material to an alkali activating treatment, wherein the carbonized material has an average true specific gravity of 1.450 to 1.650 and a variation of the true specific gravities of 0.025 or less.
摘要翻译： 一种双电层电容器用电极活性炭的制造方法，其特征在于，包括对碳化物进行碱活化处理的步骤，其中，碳化物的平均真比重为1.450〜1.650， 真实比重为0.025以下。
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