公开(公告)号：US20140349844A1

公开(公告)日：2014-11-27

申请号：US14456858

申请日：2014-08-11

Applicant: PETROCHINA COMPANY LIMITED

Inventor： Shunqin Liang ,  Ying Qian ,  Longgang Lv ,  Limin Sun ,  Yundi Zheng ,  Tinghai Wang ,  Jie Wu ,  Fengxia Cao

IPC: B01J23/888 ,  B01J23/86 ,  B01J23/887

CPC classification number: B01J23/888 ,  B01J21/04 ,  B01J21/12 ,  B01J23/78 ,  B01J23/83 ,  B01J23/85 ,  B01J23/866 ,  B01J23/8871 ,  B01J23/8872 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0207 ,  B01J37/024 ,  C10G2400/02

Abstract: A selective nickel-based hydrogenation catalyst and the preparation thereof, characterized in that: provided that the catalyst is weighed 100%, it comprises nickel oxide 14-20% as active component, lanthanum oxide and/or cerium oxide 2-8%, and VIB element oxide 1-8% as aids, 2-8% silica, 1-8% alkaline earth metal oxides, and alumina as the balance. The catalyst specific surface area is 60-150 m2/g, and the pore volume is 0.4-0.6 ml/g. The catalyst has good hydrogenation performance, especially impurity and colloid resistance and hydrogenation stability. The catalyst can be applied to the diolefin selective hydrogenation of medium or low-distillate oil, especially of the full-distillates pyrolysis gasoline.

Abstract translation: 一种选择性镍基氢化催化剂及其制备方法，其特征在于：如果催化剂称重为100％，则其包含氧化镍14-20％作为活性组分，氧化镧和/或氧化铈2-8％，以及 VIB元素氧化物1-8％作为助剂，2-8％二氧化硅，1-8％碱土金属氧化物和氧化铝作为余量。 催化剂比表面积为60-150m2 / g，孔体积为0.4-0.6ml / g。 该催化剂具有良好的氢化性能，特别是杂质和胶体阻力以及氢化稳定性。 催化剂可用于中等或低馏分油，特别是全馏分裂解汽油的二烯烃选择性氢化。

公开(公告)号：US20180290949A1

公开(公告)日：2018-10-11

申请号：US16010005

申请日：2018-06-15

Applicant: PetroChina Company Limited

Inventor： Chunxia Che ,  Yulong Liang ,  Ying Qian ,  Wei Han ,  Feng Zhang ,  Galian Gou ,  Xilin Jing ,  Xiaoxin Chang ,  Qiang Gui ,  Lifen Gu ,  Wei Xie ,  Zhongdong Zhang ,  Dehua Huang ,  Duping Tan ,  Yuan Gao ,  Lin Cheng

IPC: C07C5/09 ,  B01J23/50 ,  B01J23/89 ,  B01J23/62 ,  B01J23/52

Abstract: The present invention relates to a palladium-based supported hydrogenation catalyst and a preparation method and application thereof. The catalyst is prepared by the following method: impregnating an Al2O3-containing carrier with an organic solution containing a bipyridine derivative having hydroxy group, optionally drying followed by impregnating with a mixed solution containing the main active component palladium ions and the auxiliary active component Mn+ ions, where M is one selected from Ag, Au, Ni, Pb and Cu; and then optionally drying, and calcining to obtain the catalyst. The preparation method provided by the present invention allows Pd atoms and M atoms to be highly uniformly dispersed on the carrier, which overcomes the adverse impact of the surface tension of the impregnation solution and the solvation effect on the dispersibility of active components. The palladium-based supported hydrogenation catalyst provided by the present invention has excellent hydrogenation activity, ethylene selectivity and anti-coking performance, and can be used in a selective hydrogenation process of C2 fraction.

公开(公告)号：US09597668B2

公开(公告)日：2017-03-21

申请号：US14456858

申请日：2014-08-11

Applicant: PETROCHINA COMPANY LIMITED

Inventor： Shunqin Liang ,  Ying Qian ,  Longgang Lv ,  Limin Sun ,  Yundi Zheng ,  Tinghai Wang ,  Jie Wu ,  Fengxia Cao

IPC: B01J23/888 ,  B01J21/12 ,  B01J23/83 ,  B01J23/85 ,  B01J23/86 ,  B01J23/887 ,  B01J35/10 ,  B01J37/02 ,  B01J21/04 ,  B01J23/78 ,  B01J37/00

CPC classification number: B01J23/888 ,  B01J21/04 ,  B01J21/12 ,  B01J23/78 ,  B01J23/83 ,  B01J23/85 ,  B01J23/866 ,  B01J23/8871 ,  B01J23/8872 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0207 ,  B01J37/024 ,  C10G2400/02

Abstract: A selective nickel-based hydrogenation catalyst and the preparation thereof, characterized in that: provided that the catalyst is weighed 100%, it comprises nickel oxide 14-20% as active component, lanthanum oxide and/or cerium oxide 2-8%, and VIB element oxide 1-8% as aids, 2-8% silica, 1-8% alkaline earth metal oxides, and alumina as the balance. The catalyst specific surface area is 60-150 m2/g, and the pore volume is 0.4-0.6 ml/g. The catalyst has good hydrogenation performance, especially impurity and colloid resistance and hydrogenation stability. The catalyst can be applied to the diolefin selective hydrogenation of medium or low-distillate oil, especially of the full-distillates pyrolysis gasoline.

公开(公告)号：US10800717B2

公开(公告)日：2020-10-13

申请号：US16010005

申请日：2018-06-15

Applicant: PetroChina Company Limited

Inventor： Chunxia Che ,  Yulong Liang ,  Ying Qian ,  Wei Han ,  Feng Zhang ,  Galian Gou ,  Xilin Jing ,  Xiaoxin Chang ,  Qiang Gui ,  Lifen Gu ,  Wei Xie ,  Zhongdong Zhang ,  Dehua Huang ,  Duping Tan ,  Yuan Gao ,  Lin Cheng

IPC: C07C5/09 ,  B01J23/50 ,  B01J23/52 ,  B01J23/62 ,  B01J23/89 ,  B01J35/10 ,  B01J35/00 ,  B01J37/02 ,  B01J35/02 ,  B01J37/18

Abstract: The present invention relates to a palladium-based supported hydrogenation catalyst and a preparation method and application thereof. The catalyst is prepared by the following method: impregnating an Al2O3-containing carrier with an organic solution containing a bipyridine derivative having hydroxy group, optionally drying followed by impregnating with a mixed solution containing the main active component palladium ions and the auxiliary active component Mn+ ions, where M is one selected from Ag, Au, Ni, Pb and Cu; and then optionally drying, and calcining to obtain the catalyst. The preparation method provided by the present invention allows Pd atoms and M atoms to be highly uniformly dispersed on the carrier, which overcomes the adverse impact of the surface tension of the impregnation solution and the solvation effect on the dispersibility of active components. The palladium-based supported hydrogenation catalyst provided by the present invention has excellent hydrogenation activity, ethylene selectivity and anti-coking performance, and can be used in a selective hydrogenation process of C2 fraction.