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公开(公告)号:US20170346091A1
公开(公告)日:2017-11-30
申请号:US15597179
申请日:2017-05-17
Inventor: AKIRA KANO , JUNICHI SAKAMOTO , NOBUHIKO HOJO
IPC: H01M4/485 , C30B29/32 , H01G11/46 , H01G11/50 , H01G11/68 , H01M4/131 , C01G23/00 , H01M4/66 , H01M4/62 , H01M10/0525 , H01M4/02 , H01M4/04 , H01M4/1391
Abstract: An electrochemical device includes a negative electrode containing a negative electrode active material, a positive electrode, and an electrolyte. The negative electrode active material has a crystal structure with an Fm3m space group and contains a compound represented by composition formula (1) below, LixTiyOz Formula (1), where 0.4≦x/y
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公开(公告)号:US20160351955A1
公开(公告)日:2016-12-01
申请号:US15157486
申请日:2016-05-18
Inventor: TAKAYUKI NAKATSUTSUMI , MAYUMI MAENISHI , NOBUHIKO HOJO
IPC: H01M10/0564 , H01M4/133 , H01M4/131 , H01M10/0525
CPC classification number: H01M10/0525 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M2300/0034 , H01M2300/0037
Abstract: An electrolyte solution contains a non-aqueous solvent and an alkali metal salt dissolved in the non-aqueous solvent. The non-aqueous solvent contains a linear carboxylate represented by the following formula: where R1 and R2 independently represent an aromatic group, an unsaturated aliphatic group, or a saturated aliphatic group. A battery includes the electrolyte solution, a positive electrode containing a positive electrode active material that has a property of occluding and releasing an alkali metal ion, and a negative electrode containing an alkali metal or a negative electrode active material that has a property of occluding and releasing the alkali metal ion.
Abstract translation: 其中R1和R2独立地表示芳族基团,不饱和脂族基团或饱和脂族基团。 电池包括电解质溶液,含有具有闭塞和释放碱金属离子的性质的正极活性物质的正极和含有碱金属或负极活性物质的负极,所述碱金属或负极活性物质具有阻塞和/ 释放碱金属离子。
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公开(公告)号:US20150155601A1
公开(公告)日:2015-06-04
申请号:US14553089
申请日:2014-11-25
Inventor: TAKAYUKI NAKATSUTSUMI , NOBUHIKO HOJO , HIROTETSU SUZUKI , YU OTSUKA
IPC: H01M10/0569 , H01M4/48 , H01M4/583 , H01M10/0568
CPC classification number: H01M10/0569 , H01M4/483 , H01M4/587 , H01M10/054 , H01M10/0568 , H01M2300/0034 , H01M2300/0037
Abstract: A sodium secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolytic solution including a non-aqueous solvent. The non-aqueous solvent includes a fluoro group-containing chain carboxylic acid ester represented by General Formula (1): wherein R1 is an aromatic group, an unsaturated aliphatic group or a saturated aliphatic group; R2, R3 and R4 are each a hydrogen atom, an aromatic group, an unsaturated aliphatic group or a saturated aliphatic group; and at least one of R1, R2, R3 and R4 includes one or more fluoro groups.
Abstract translation: 钠二次电池包括正极,负极和包含非水溶剂的非水电解液。 非水性溶剂包括由通式(1)表示的含氟基的链状羧酸酯:其中,R 1为芳香族基团,不饱和脂肪族基团或饱和脂肪族基团; R2,R3和R4各自为氢原子,芳基,不饱和脂族基或饱和脂族基; 并且R 1,R 2,R 3和R 4中的至少一个包括一个或多个氟基团。
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公开(公告)号:US20180337399A1
公开(公告)日:2018-11-22
申请号:US15974490
申请日:2018-05-08
Inventor: NOBUHIKO HOJO , TAKAYUKI NAKATSUTSUMI , TETSUYUKI OKANO , MAYUMI MAENISHI , MASAHIRO TAKAHATA
IPC: H01M4/36 , H01M4/38 , H01M4/587 , H01M10/0525 , H01M10/0569
CPC classification number: H01M4/587 , H01M4/134 , H01M10/0525 , H01M10/0569 , H01M2300/0034
Abstract: A negative electrode active material for a nonaqueous secondary battery includes graphite containing boron. The graphite has an average discharge potential of 0.16 V or more and 0.2 V or less, based on Li. A nonaqueous secondary battery includes: a positive electrode including a positive electrode active material capable of occluding and releasing an alkali metal ion; a negative electrode including a negative electrode active material above; and a nonaqueous electrolyte solution.
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公开(公告)号:US20180337398A1
公开(公告)日:2018-11-22
申请号:US15974312
申请日:2018-05-08
Inventor: MAYUMI MAENISHI , TAKAYUKI NAKATSUTSUMI , TETSUYUKI OKANO , NOBUHIKO HOJO
IPC: H01M4/36 , H01M4/38 , H01M4/587 , H01M10/0525 , H01M10/0569
Abstract: A negative electrode active material for a nonaqueous secondary battery includes graphite containing boron. The graphite has a crystallite size Lc of 100 nm or more in the c-axis direction, In a Raman spectrum obtained by Raman spectroscopy of a surface of the graphite, a ratio R is 0.4 or more, the ratio R being a ratio of a maximum peak value Id of Raman intensity of a D band appearing in a Raman shift range of 1300 cm−1 or more and 1400 cm−1 or less to a maximum peak value Ig of Raman intensity of a G band appearing in a Raman shift range of 1500 cm−1 or more and 1650 cm−1 or less.
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公开(公告)号:US20160351960A1
公开(公告)日:2016-12-01
申请号:US15158594
申请日:2016-05-19
Inventor: TAKAYUKI NAKATSUTSUMI , MAYUMI MAENISHI , NOBUHIKO HOJO
IPC: H01M10/0565 , H01M4/131 , H01M4/134 , H01M10/0525
CPC classification number: H01M10/0525 , H01M4/485 , H01M10/0413 , H01M10/0436 , H01M10/0567 , H01M10/0569 , H01M2300/0025 , H01M2300/0037
Abstract: An electrolyte solution contains a non-aqueous solvent and an alkali metal salt dissolved in the non-aqueous solvent. The non-aqueous solvent contains cyclopropanecarbonitrile. A battery includes an electrolyte solution which contains a non-aqueous solvent containing cyclopropanecarbonitrile and an alkali metal salt dissolved in the non-aqueous solvent, a positive electrode containing a positive electrode active material that has a property of occluding and releasing an alkali metal ion, and a negative electrode containing an alkali metal or a negative electrode active material that has a property of occluding and releasing the alkali metal ion.
Abstract translation: 电解质溶液含有溶解在非水溶剂中的非水溶剂和碱金属盐。 非水溶剂含有环丙腈。 电池包括含有溶解在非水溶剂中的环丙烷腈和碱金属盐的非水溶剂的电解质溶液,含有具有吸留和释放碱金属离子性质的正极活性物质的正极, 以及含有碱金属或负极活性物质的负极,其具有吸留和释放碱金属离子的性质。
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公开(公告)号:US20180337425A1
公开(公告)日:2018-11-22
申请号:US15959294
申请日:2018-04-23
Inventor: TAKAYUKI NAKATSUTSUMI , AKIRA KANO , JUNKO MATSUSHITA , NOBUHIKO HOJO
CPC classification number: H01M10/0525 , C01B32/205 , C01B32/21 , H01M2/204 , H01M4/133 , H01M4/134 , H01M4/366 , H01M4/381 , H01M4/583 , H01M4/5835 , H01M4/587 , H01M4/62 , H01M4/662 , H01M2004/027 , H01M2004/028
Abstract: A negative-electrode active material comprises a graphite including at least boron and fluorine. The fluorine is disposed at least on a surface of the graphite. A ratio R satisfies 0.5≤R≤1, where R=SBB/SB, and SB denotes a total peak area of a boron 1s spectrum of the graphite obtained by X-ray photoelectron spectroscopy, and SBB denotes a peak area of all spectra each having a peak in a binding energy range of not less than 184.0 eV and not more than 188.5 eV in the boron 1s spectrum.
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公开(公告)号:US20180337424A1
公开(公告)日:2018-11-22
申请号:US15959292
申请日:2018-04-23
Inventor: TAKAYUKI NAKATSUTSUMI , NOBUHIKO HOJO , AKIRA KANO , JUNKO MATSUSHITA
Abstract: A negative-electrode active material comprises: a graphite including boron; and a covering layer that covers a surface of the graphite. The covering layer comprises carbon. A ratio R satisfies 0≤R≤0.001, where R=SB/(SB+SC), and SB denotes a total peak area of a boron 1 s spectrum of the negative-electrode active material obtained by X-ray photoelectron spectroscopy, and SC denotes a total peak area of a carbon 1 s spectrum of the negative-electrode active material obtained by X-ray photoelectron spectroscopy.
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公开(公告)号:US20180069267A1
公开(公告)日:2018-03-08
申请号:US15813218
申请日:2017-11-15
Inventor: HIROTETSU SUZUKI , RYUICHI NATSUI , NOBUHIKO HOJO
IPC: H01M10/0569 , H01M4/505 , H01M10/052 , H01M10/0568
Abstract: Provided is a battery including: a positive electrode containing a positive electrode active material; a negative electrode; and an electrolyte solution containing a nonaqueous solvent. The positive electrode active material contains a compound represented by composition formula (1) below and having a crystal structure belonging to space group FM3-M: LixMeyOαFβ. (1) Here, Me is one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and C. x, y, α, and β satisfy the following conditions: 1.7≦x≦2.2, 0.8≦y≦1.3, 1≦α≦2.5, and 0.5≦β≦2, respectively. The nonaqueous solvent includes at least one solvent selected from hydrofluoroethers, phosphazenes, phosphates, and perfluoropolyethers.
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10.
公开(公告)号:US20180337430A1
公开(公告)日:2018-11-22
申请号:US15937808
申请日:2018-03-27
Inventor: HIROTETSU SUZUKI , NOBUHIKO HOJO
IPC: H01M10/0569 , H01M10/0568 , H01M10/0525 , H01M2/16
Abstract: A nonaqueous electrolyte includes a nonaqueous solvent and an alkali metal salt dissolved in the nonaqueous solvent. The nonaqueous solvent contains a perfluoropolyether and a nitrile compound represented by a formula Rf—CN, where Rf represents a hydrocarbon group which has a carbon number of 2 to 4 and in which at least one hydrogen atom is substituted with fluorine.
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