摘要:
A process for preparing free-radically polymerizable carboxylic esters by reacting ethyllenically unsaturated carboxylic acids, carboxylic anhydrides or carbonyl halides (referred to collectively as carboxylic acid component) with a hydroxyl compound composed of at least 60% by weight of C2 to C4 alkoxy groups (and referred to for short as polyalkoxy compound), which comprises said reacting taking place in the presence of a polymerization inhibitor and of a reducing agent.
摘要:
The present invention relates to novel comb polymers which bear poly-C2-C4-alkylene ether side chains A and functional groups B which at a pH of >12 are present in the form of anionic groups on a carbon backbone and also the salts of such comb polymers. The invention also relates to the use of these comb polymers as additives in preparations comprising a mineral binder. The polyalkylene ether side chains A have the following formula: *—U—(C(O))k—X-(Alk-O)n—Y—Z A.
摘要翻译:本发明涉及具有聚-C2-C4-亚烷基醚侧链A和官能团B的新型梳状聚合物,其pH> 12是以碳骨架上的阴离子基团的形式存在,以及其中的盐 梳状聚合物。 本发明还涉及这些梳状聚合物作为添加剂在包含矿物粘合剂的制剂中的用途。 聚亚烷基醚侧链A具有下式:* -U-(C(O))k -X-(Alk-O)n -Y-Z A
摘要:
The present invention relates to the use of comb polymers which have a carbon backbone which bears polyether groups of the formula A *—U—(C(O))k—X-(Alk-O)n—W A wherein * indicates the binding site to the carbon backbone of the comb polymer, U stands for a chemical bond or an alkylene group with 1 to 8 C atoms, X means oxygen or a NR group, k is 0 or 1, n stands for a whole number, the mean value whereof, based on the comb polymer, lies in the range from 5 to 300, Alk stands for C2-C4 alkylene, where Alk within the group (Alk-O)n can be the same or different, W means a hydrogen, a C1-C6 alkyl residue or an aryl residue or means the group Y—Z, Y stands for a linear or branched alkylene group with 2 to 8 C atoms, which may bear a phenyl ring, Z stands for a 5- to 10-membered nitrogen heterocycle bound via nitrogen, which can have as ring members, as well as the nitrogen atom and as well as carbon atoms, 1, 2 or 3 additional hetero atoms, selected from oxygen, nitrogen and sulfur, wherein the nitrogen ring members can contain a group R′, and wherein 1 or 2 carbon ring members can be present as carbonyl groups, R stands for hydrogen, C1-C4 alkyl or benzyl, and R′ stands for hydrogen, C1-C4 alkyl or benzyl; and functional groups B, which are present in the form of anionic groups at pH>12, and salts thereof as grinding aids in cement-containing preparations.
摘要:
The present invention relates to the use of comb polymers which have a carbon backbone which bears polyether groups of the formula A *—U—(C(O))k—X-(Alk-O)n—W A wherein * indicates the binding site to the carbon backbone of the comb polymer, U stands for a chemical bond or an alkylene group with 1 to 8 C atoms, X means oxygen or a NR group, k is 0 or 1, n stands for a whole number, the mean value whereof, based on the comb polymer, lies in the range from 5 to 300, Alk stands for C2-C4 alkylene, where Alk within the group (Alk-O)n can be the same or different, W means a hydrogen, a C1-C6 alkyl residue or an aryl residue or means the group Y-Z, Y stands for a linear or branched alkylene group with 2 to 8 C atoms, which may bear a phenyl ring, Z stands for a 5- to 10-membered nitrogen heterocycle bound via nitrogen, which can have as ring members, as well as the nitrogen atom and as well as carbon atoms, 1, 2 or 3 additional hetero atoms, selected from oxygen, nitrogen and sulfur, wherein the nitrogen ring members can contain a group R′, and wherein 1 or 2 carbon ring members can be present as carbonyl groups, R stands for hydrogen, C1-C4 alkyl or benzyl, and R′ stands for hydrogen, C1-C4 alkyl or benzyl; and functional groups B, which are present in the form of anionic groups at pH>12, and salts thereof as grinding aids in cement-containing preparations.
摘要:
The present invention relates to novel comb polymers which bear poly-C2-C4-alkylene ether side chains A and functional groups B which at a pH of >12 are present in the form of anionic groups on a carbon backbone and also the salts of such comb polymers. The invention also relates to the use of these comb polymers as additives in preparations comprising a mineral binder. The polyalkylene ether side chains A have the following formula: *—U—(C(O))k—X-(Alk-O)n—Y-Z A where * indicates the point of bonding to the carbon backbone of the comb polymer, U is a chemical bond or an alkylene group having from 1 to 8 carbon atoms, X is oxygen or an NR group, k is 0 or 1, n is an integer whose average value, based on the comb polymer, is in the range from 5 to 300, Alk is C2-C4-alkylene, with the Alk radicals within the group (Alk-O)n being able to be identical or different, Y is a linear or branched alkylene group which has from 2 to 8 carbon atoms and may bear a phenyl ring, Z is a 5- to 10-membered nitrogen heterocycle which is bound via nitrogen and can have, in addition to the nitrogen atom and carbon atoms, 1, 2 or 3 additional heteroatoms selected from among oxygen, nitrogen and sulfur as ring members, with the nitrogen ring members being able to bear a group R′ and 1 or 2 carbon ring members being able to be present as carbonyl groups, R is hydrogen, C1-C4-alkyl or benzyl and R′ is hydrogen, C1-C4-alkyl or benzyl.
摘要:
A process for preparing poly-C2-C4-alkylene glycol mono(meth)acrylic acid esters by reacting (meth)acrylic anhydride with a poly-C2-C4-alkylene glycol carrying at least one OH group in the presence of abase having a solubility in the poly-C2-C4-alkylene glycol of not more than 10 g/l at 90° C.
摘要:
A polymer is obtained by removing the medium from a polymer dispersion or polymer solution containing at least one polymeric phase and at least one stabilizer suitable to protect against the damaging effect of light, heat and/or oxidation.
摘要:
An aqueous polymer dispersion, wherein the dispersion contains from 0.0001 to 1 mol of a hydrolyzable silicon group and from 0.0001 to 1 mol of a urea or thiourea group, based, in each case, on 100 g of the polymer present in the dispersion.
摘要:
The present invention provides a process for preparing polymer powders by evaporating the volatile constituents from aqueous dispersions of film-forming polymers P in the presence of drying assistants T selected from the salts of oligomeric arylsulfonic acid-formaldehyde condensates wherein prior to the evaporation of the volatile constituents the aqueous polymer dispersion comprises at least 1.5% by weight, preferably at least 1.7% by weight, based on the polymer in the dispersion, of at least one anionic surface-active compound AO having at least one C6-C32 alkyl group; the polymer powders obtainable by the process; and their use in binding mineral building materials.
摘要:
The present invention relates to the use of homopolymers or copolymers of (meth)acrylic acid or copolymers of C3-C40-monoolefins with ethylenically unsaturated C4-C6-dicarboxylic anhydrides as additives in ceramic masses, in particular in brick earth and clay for producing building ceramics such as bricks and roofing tiles, and also ceramic masses comprising these additives.