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    Polymer dispersions as an additive in building materials
    5.
    发明授权
    Polymer dispersions as an additive in building materials 有权
    聚合物分散体作为建筑材料中的添加剂

    公开(公告)号：US06809148B1

    公开(公告)日：2004-10-26

    申请号：US10383609

    申请日：2003-03-10

    申请人： Markus Koppers ,  Joachim Pakusch ,  Hermann Anders ,  Marco Schmidt ,  Hans-Jürgen Denu

    发明人： Markus Koppers ,  Joachim Pakusch ,  Hermann Anders ,  Marco Schmidt ,  Hans-Jürgen Denu

    IPC分类号： C08F22010

    CPC分类号： C04B24/2641 ,  C04B24/2647 ,  C04B24/2676 ,  C04B24/2688 ,  C04B28/02 ,  C04B2103/0057 ,  C04B2111/00586 ,  C04B2111/0075 ,  C08F212/04 ,  C08F236/10 ,  C08F290/062

    摘要： Polymer dispersions comprise at least one copolymer which contains, as polymerized monomers, a) from 25 to 70% by weight of at least one conjugated aliphatic diene, b) from 25 to 70% by weight of at least one vinylaromatic monomer, c) from 2.5 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid or c′) from 0.1 to 10% by weight of at least one alkylpolyethylene glycol (meth)acrylate of the formula (I) where R1 is hydrogen or methyl, R2 is C1-C4-alkyl and n is an integer from 1 to 100, or c″) from 2 to 15% by weight of a mixture of the monoester c) and the alkylpolyethylene glycol (meth)acrylate c′), d) from 0 to 1.0% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) from 0 to 5.0% by weight of ethylenically unsaturated nitriles and f) from 0 to 1.0% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids. The polymer dispersions described are suitable, inter alia, as additives in building materials based on hydraulic binders.

    摘要翻译： 聚合物分散体包含至少一种共聚物，其包含作为聚合单体的a）25至70重量％的至少一种共轭脂族二烯，b）25至70重量％的至少一种乙烯基芳族单体，c） 2.5至15重量％的至少一种C2-C10-链烷二醇与丙烯酸或甲基丙烯酸orc'的单酯）0.1至10重量％的至少一种式（I）的烷基聚乙二醇（甲基）丙烯酸酯， 其中R 1是氢或甲基，R 2是C 1 -C 4 - 烷基，n是1至100的整数，orc“）2至15重量％的单酯c）和 烷基聚乙二醇（甲基）丙烯酸酯c'），d）0至1.0重量％的具有至少一个酸基的烯键式不饱和单体或其盐，e）0-5.0重量％的烯属不饱和腈和 ）0至1.0重量％的α，β-烯键式不饱和单羧酸和二羧酸的酰胺。所述聚合物分散体是合适的，i 特别是作为基于水泥粘合剂的建筑材料中的添加剂。

    Preparation of polymer powders
    8.
    发明授权
    Preparation of polymer powders 失效
    聚合物粉末的制备

    公开(公告)号：US06291573B1

    公开(公告)日：2001-09-18

    申请号：US09210765

    申请日：1998-12-14

    申请人： Joachim Pakusch ,  Bernd Reck ,  Peter Claassen ,  Hans-Jürgen Denu ,  Eckehardt Wistuba ,  Claudia Heibel

    发明人： Joachim Pakusch ,  Bernd Reck ,  Peter Claassen ,  Hans-Jürgen Denu ,  Eckehardt Wistuba ,  Claudia Heibel

    IPC分类号： C08L2904

    CPC分类号： C08J3/16 ,  C04B24/2676 ,  C04B24/2688 ,  C04B26/04 ,  C04B2103/0057 ,  C08J2325/08

    摘要： The present invention relates to a process for preparing polymer powders from aqueous polymer dispersions in which the dispersed polymer P comprises in copolymerized form: i) at least one vinylaromatic monomer (a), ii) 1,3-butadiene as monomer (b), and iii) one or more monomers (c) different than the monomers (a) and (b), which comprises drying the aqueous polymer dispersion in the presence of polyvinyl alcohol as drying agent. The present invention also relates to the polymer powders obtainable by this process and to the use of these polymer powders as binders in paints, varnishes and coating compositions generally, in adhesives, and for modifying mineral construction materials. The present invention also relates to mineral construction materials in the form of dry formulations comprising the polymer powders of the invention.

    摘要翻译： 本发明涉及一种由聚合物水分散体制备聚合物粉末的方法，其中分散的聚合物P以共聚形式包含：i）至少一种乙烯基芳族单体（a），ii）1,3-丁二烯作为单体（b）， 和ii）与单体（a）和（b）不同的一种或多种单体（c），其包括在聚乙烯醇存在下干燥聚合物水分散体作为干燥剂。 本发明还涉及通过该方法获得的聚合物粉末以及这些聚合物粉末作为粘合剂在粘合剂中的用途，通常用于粘合剂和用于改性矿物建筑材料中的粘合剂。 本发明还涉及包含本发明的聚合物粉末的干制剂形式的矿物构造材料。

    Use of Comb Polymers as a Grinding Agent for Preparations Containing Cement
    9.
    发明申请
    Use of Comb Polymers as a Grinding Agent for Preparations Containing Cement 有权
    使用梳子聚合物作为含水泥制剂的研磨剂

    公开(公告)号：US20080293850A1

    公开(公告)日：2008-11-27

    申请号：US12095799

    申请日：2006-11-23

    申请人： Joachim Pakusch ,  Stefan Becker ,  Thomas Gotz ,  Rainer Dyllick-Brenzinger ,  Rolf Gulden

    发明人： Joachim Pakusch ,  Stefan Becker ,  Thomas Gotz ,  Rainer Dyllick-Brenzinger ,  Rolf Gulden

    IPC分类号： C04B7/02 ,  C08L33/02

    CPC分类号： C04B24/2605 ,  C04B24/2647 ,  C04B24/267 ,  C04B28/02 ,  C04B2103/006 ,  C04B2103/52 ,  Y02P40/20

    摘要： The present invention relates to the use of comb polymers which have a carbon backbone which bears polyether groups of the formula A *—U—(C(O))k—X-(Alk-O)n—W  A wherein * indicates the binding site to the carbon backbone of the comb polymer, U stands for a chemical bond or an alkylene group with 1 to 8 C atoms, X means oxygen or a NR group, k is 0 or 1, n stands for a whole number, the mean value whereof, based on the comb polymer, lies in the range from 5 to 300, Alk stands for C2-C4 alkylene, where Alk within the group (Alk-O)n can be the same or different, W means a hydrogen, a C1-C6 alkyl residue or an aryl residue or means the group Y-Z, Y stands for a linear or branched alkylene group with 2 to 8 C atoms, which may bear a phenyl ring, Z stands for a 5- to 10-membered nitrogen heterocycle bound via nitrogen, which can have as ring members, as well as the nitrogen atom and as well as carbon atoms, 1, 2 or 3 additional hetero atoms, selected from oxygen, nitrogen and sulfur, wherein the nitrogen ring members can contain a group R′, and wherein 1 or 2 carbon ring members can be present as carbonyl groups, R stands for hydrogen, C1-C4 alkyl or benzyl, and R′ stands for hydrogen, C1-C4 alkyl or benzyl; and functional groups B, which are present in the form of anionic groups at pH>12, and salts thereof as grinding aids in cement-containing preparations.

    摘要翻译： 本发明涉及具有碳骨架的梳状聚合物的用途，所述主骨架具有式A的聚醚基团。在线式描述=“在线公式”末端=“铅”→* - U-（ C（O））kX-（Alk-O）nW A <βin-line-formula description =“In-line Formulas”end =“tail”？>其中*表示梳形聚合物的碳骨架的结合位点 ，U表示1〜8个C原子的化学键或亚烷基，X表示氧或NR基，k表示0或1，n表示整数，其基于梳形聚合物的平均值， AlK代表C2-C4亚烷基，其中Alk（O-O）n中的Al可以相同或不同，W表示氢，C1-C6烷基或芳基残基 或者表示基团YZ，Y表示具有2至8个C原子的直链或支链亚烷基，其可以带有苯环，Z表示通过氮键合的5至10元氮杂环，其可以具有环 成员，以及硝基 原子以及碳原子，1,2或3个选自氧，氮和硫的另外的杂原子，其中氮环成员可以含有基团R'，并且其中1或2个碳环成员可以以 羰基，R代表氢，C 1 -C 4烷基或苄基，R'代表氢，C 1 -C 4烷基或苄基; 和以pH> 12的阴离子基团形式存在的官能团B及其盐作为含水泥制剂中的助磨剂。