公开(公告)号：US06524402B1

公开(公告)日：2003-02-25

申请号：US08494220

申请日：1995-06-23

申请人： Paul Broutin ,  Pascal Nisio ,  François Ropital

发明人： Paul Broutin ,  Pascal Nisio ,  François Ropital

IPC分类号： C23C800

CPC分类号： C23C28/044 ,  B01J19/02 ,  B01J2219/00135 ,  B01J2219/00164 ,  B01J2219/0236 ,  C10G9/203 ,  C23C16/02 ,  C23C28/048

摘要： A passivation method for the metallic surface of a nickel and iron-based superalloy which is used as the constituent material of reactor or furnace walls is described, in which the superalloy is coated on at least one of its surfaces which comes into contact with a corrosive atmosphere containing either hydrocarbons at high temperature or containing oxidizing gases at high temperature, with at least two successive layers resulting from successive chemical vapour deposition of its one or more constituent elements, the external phase, resulting from chemical vapour deposition of at least one silicon compound and the layer(s) deposited between the superalloy surface, and the external layer resulting from chemical vapour deposition of at least one of a metal or metalloid.

摘要翻译： 描述了用作反应器或炉壁的构成材料的镍和铁基超级合金的金属表面的钝化方法，其中将超合金涂覆在与腐蚀性接触的至少一个表面上 在高温下含有烃或在高温下含有氧化性气体的气氛，具有由其一种或多种构成元素的连续化学气相沉积产生的至少两个连续的层，由至少一种硅化合物的化学气相沉积产生的外相 以及沉积在超级合金表面之间的层和由金属或准金属中的至少一种的化学气相沉积产生的外部层。

公开(公告)号：US06348145B1

公开(公告)日：2002-02-19

申请号：US09109867

申请日：1998-07-06

申请人： François Ropital ,  Paul Broutin ,  Marcel François ,  Alain Bertoli

发明人： François Ropital ,  Paul Broutin ,  Marcel François ,  Alain Bertoli

IPC分类号： C10G1700

CPC分类号： C23C28/023 ,  C10G9/203 ,  C23C10/42 ,  C23C28/028

摘要： Coated steel articles are described which exhibit anti-coking properties, and a process for producing such articles by depositing an anti-coking coating on a matrix constituted by a steel, in general a refractory steel. These articles comprise: a refractory steel substrate comprising at least 0.2% by weight of carbon; a carbon-rich diffusion barrier; and an outer layer containing 90% to 99% by weight of chromium, coated by a cementation method. More particularly, the coated steel articles constitute tubes for reactors or stills used in various refining or petrochemical processes.

摘要翻译： 描述了具有抗焦化性能的涂覆钢制品，以及通过在由钢构成的基体（通常为耐火钢）上沉积抗焦化涂层来制造这种制品的方法。 这些制品包括：包含至少0.2重量％的碳的耐火钢基材;富碳扩散阻挡层; 和含有90重量％至99重量％铬的外层，通过胶结法涂覆。 更具体地，涂覆的钢制品构成用于各种精炼或石化工艺中的反应器或静止物的管。

公开(公告)号：US08349281B2

公开(公告)日：2013-01-08

申请号：US10584047

申请日：2004-12-10

申请人： Hervé Toulhoat ,  François Ropital ,  Sébastien Duval

发明人： Hervé Toulhoat ,  François Ropital ,  Sébastien Duval

IPC分类号： C22B3/00 ,  C01F1/00 ,  B01D53/14 ,  C25B3/00

CPC分类号： B01D53/62 ,  C25B3/04 ,  Y02C10/04 ,  Y02C10/14 ,  Y02P20/152

摘要： A process for sequestrating carbon emitted into the atmosphere in the form of CO2 comprises: a) a step for concentrating CO2 in the liquid phase; b) a step for electro-reduction in an aprotic medium to a compound in which the carbon changes to oxidation number +3 in the form of oxalic acid or formic acid; c) if appropriate, a step for re-extracting oxalic or formic acid in the aqueous phase; and d) a step for mineralization by reaction with a compound of an element M, resulting in a stable compound in which the atomic ratio C/M is about 2/1.

摘要翻译： 以CO 2形式排放到大气中的碳的过程包括：a）将CO 2浓缩在液相中的步骤; b）将非质子介质中的电还原为其中碳变成氧化值+3的草酸或甲酸形式的化合物的步骤; c）如果合适，在水相中重新萃取草酸或甲酸的步骤; 和d）通过与元素M的化合物反应而矿化的步骤，得到其中原子比C / M为约2/1的稳定化合物。

公开(公告)号：US06291079B1

公开(公告)日：2001-09-18

申请号：US09254486

申请日：1999-05-10

申请人： José Mallen Herrero ,  François Ropital

发明人： José Mallen Herrero ,  François Ropital

IPC分类号： C21D806

CPC分类号： B21C37/045 ,  C21D8/06 ,  C21D8/065 ,  C22C38/22 ,  Y10T428/12 ,  Y10T428/12431 ,  Y10T428/12972

摘要： The invention concerns a method for manufacturing steel wire comprising the following steps: manufacturing a reinforcing wire of sizeable length by rolling or hot wire drawing from steel containing the following elements: 0.18% to 0.45 % C, 0.4% to 1.8% Mn, 1% to 4% Cr, 0.1% to 0.6% Si, 0% to 1.5% Mo, 0% to 1.5% Ni, at most 0.01% S and 0.02% P, the reinforcing wire having, after being rolled or hot drawn, a temperature at least higher than the AC3 temperature, preferably by 50 to 200° C. and in particular by 100 to 150° C.; winding the wire in reels before air cooling the raw manufacturing wire to obtain a HRC hardness not less than 40 and preferably higher than 45. In a variant, the method consists in quenching and tempering so that the wire has a hardness between 20 HRC and 35 HRC. The invention also concerns a reinforcing wire and a flexible tube for carrying effluents.

摘要翻译： 本发明涉及一种制造钢丝的方法，包括以下步骤：通过轧制或热拉丝从含有以下元素的钢制造尺寸相当大的钢丝：0.18％至0.45％C，0.4％至1.8％Mn，1％ 至4％Cr，0.1％至0.6％Si，0％至1.5％Mo，0％至1.5％Ni，至多0.01％S和0.02％P，加强丝在轧制或热拉伸后具有温度 至少高于AC3温度，优选为50〜200℃，特别优选为100〜150℃。 在空气冷却原始生产线之前将线缠绕在卷轴上，以获得不低于40且优选高于45的HRC硬度。在一个变型中，该方法包括淬火和回火，使得线的硬度在20HRC和35之间 HRC。 本发明还涉及用于承载流出物的增强线和柔性管。

公开(公告)号：US06824672B2

公开(公告)日：2004-11-30

申请号：US10045092

申请日：2002-01-15

申请人： Philippe Lecour ,  Xavier Longaygue ,  François Ropital ,  Laurent Antoni

发明人： Philippe Lecour ,  Xavier Longaygue ,  François Ropital ,  Laurent Antoni

IPC分类号： C10G7500

CPC分类号： C22C38/50 ,  C22C38/001 ,  C22C38/42 ,  C22C38/44 ,  C22C38/58 ,  Y10S585/92 ,  Y10S585/95

摘要： An austenitic stainless steel with a composition comprising: at most 0.15% of C; 2% to 10% of Mn; at most 2% of Ni; at most 4% of Cu; 0.1% to 0.4% of N; 10% to 20% of Cr; at most 1% of Si; at most 3% of Mo; and at most 0.7% of Ti; is used to manufacture equipment, for example furnaces, reactors or ducts, or elements of this equipment, or to coat the internal walls of this equipment, said equipment being used to implement petrochemical processes conducted at temperatures of 350° C. to 1100° C. and in which coke can be formed.

摘要翻译： 一种奥氏体不锈钢，其组成为：至多0.15％的C; 2％至10％的Mn;至多2％的Ni;至多4％的Cu; 0.1％至0.4％的N; 10％至20 Cr％，Si：1％以下，Mo：3％以下。 并且最多的0.7％的Ti用于制造设备，例如炉子，反应器或管道或本设备的元件，或用于涂覆该设备的内壁，所述设备用于实施在350℃的温度下进行的石化工艺 ℃至1100℃，其中可以形成焦炭。

公开(公告)号：US07867464B2

公开(公告)日：2011-01-11

申请号：US12480257

申请日：2009-06-08

申请人： Pascal Raybaud ,  François Ropital

发明人： Pascal Raybaud ,  François Ropital

IPC分类号： C01B33/32 ,  H01M4/88

CPC分类号： C01B3/001 ,  C01B3/0031 ,  Y02E60/327

摘要： A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSi MXMSiHn  where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1 1≦XNa≦3 1≦XK≦2  n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or formed hydrides. or to the formula MSiXSi MSiXSiH2XSi+1  where M is selected from among Li, Na, or K and in which the atomic ratio XSi=Si/M takes on a value of 1 to 4.

摘要翻译： 一种用于氢的可逆储存的方法，包括使碱金属和硅的合金与导致形成氢化物或相应的氢化物的气态氢接触，包括使用对应于下式的至少一个平衡系统：MXMSi MXMSiHn其中M选自Li，Na或K，其中原子比XM取以下值：XLi = 1 1＆nlE; XNa＆nlE; 3 1＆nlE; XK＆nlE; 2 n是与化学计量相对应的氢原子数 氢化物或形成的氢化物。 或其中M选自Li，Na或K并且其中原子比XSi = Si / M的值为1至4的式MSiXSi MSiXSiH 2 XSi + 1。

公开(公告)号：US07608239B2

公开(公告)日：2009-10-27

申请号：US11347578

申请日：2006-02-06

申请人： Pascal Raybaud ,  François Ropital

发明人： Pascal Raybaud ,  François Ropital

IPC分类号： C01B3/04

CPC分类号： C01B3/001 ,  C01B3/0026 ,  C01B3/0031 ,  C01B6/04 ,  C01B21/0602 ,  C01B21/0612 ,  C01B21/0923 ,  F17C11/005 ,  Y02E60/321 ,  Y02E60/327 ,  Y02E60/364

摘要： A process for the reversible storage of hydrogen, comprising bringing into contact a material that consists of magnesium elements and nitrogen elements with gaseous hydrogen leading to the formation of an amide or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: Mg3N2Mg(NH2)2+2MgHn where n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed. The material can also comprise, in a minor proportion, at least one transition metal of groups 3 to 12 of the periodic table that is selected from among Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn and Pd.

摘要翻译： 一种用于氢的可逆储存的方法，包括使由镁元素和氮元素组成的材料与导致形成酰胺或相应的氢化物的气态氢接触的材料包括使用对应于下式的平衡系统：Mg 3 N 2 “img id =”CUSTOM-CHARACTER-00001“he =”2.46mm“wi =”2.46mm“file =”US07608239-20091027-P00001.TIF“alt =”custom character“img-content =”character“img-format =“tif”/> Mg（NH 2）2 + 2MgHn其中n是与形成的氢化物或氢化物的化学计量相对应的氢原子数。 所述材料还可以以少量的比例包含选自Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn中的至少一种元素周期表第3至12族的过渡金属和 钯

公开(公告)号：US07547432B2

公开(公告)日：2009-06-16

申请号：US11347577

申请日：2006-02-06

申请人： Pascal Raybaud ,  François Ropital

发明人： Pascal Raybaud ,  François Ropital

IPC分类号： C01B6/04 ,  F17C11/00

CPC分类号： C01B3/0031 ,  C01B6/24 ,  F17C11/005 ,  Y02E60/321 ,  Y02E60/327 ,  Y10S420/90

摘要： A process for the reversible storage of hydrogen, comprising bringing into contact an alloy of magnesium and palladium with the gaseous hydrogen leading to the formation of hydride or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: MgxPdMgxPdHn in which atomic ratio x takes on a value of 3 to 6, and n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed or to the formula: MgxPdMg2PdH4+Mgx-2Hn in which the atomic ratio x takes on a value of 7 to 9, and n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed.

摘要翻译： 包括使镁和钯的合金与导致氢化物或相应的氢化物形成的气态氢接触的方法，包括使用对应于下列公式的平衡系统： -formulae description =“In-line Formulas”end =“lead”？> MgxPd MgxPdHn <？in-line-formula description =”在线公式“end =”tail“？>其中原子 比例x取3至6的数值，n是与所形成的氢化物或氢化物的化学计量相对应的氢原子数或式：<？in-line-formula description =“In-line Formula”end =“lead”？> MgxPd Mg2PdH4 + Mgx-2Hn <？in -line-formula description =“In-line Formulas”end =“tail”？>，其中原子比x取值为7至9，n是与氢化物的化学计量相对应的氢原子数， 形成氢化物。

公开(公告)号：US06235238B1

公开(公告)日：2001-05-22

申请号：US09282219

申请日：1999-03-31

申请人： Philippe Lecour ,  Xavier Longaygue ,  François Ropital

发明人： Philippe Lecour ,  Xavier Longaygue ,  François Ropital

IPC分类号： C22C3822

CPC分类号： F27D1/0006 ,  C07C5/333 ,  C10G35/04 ,  C22C38/12 ,  C22C38/22 ,  C22C38/34 ,  C23C4/073 ,  C23C30/00 ,  C07C11/09

摘要： In order to produce elements for furnaces, reactors or conduits on the walls of which coke can appear, steels are used with a composition which is adapted to resist coking comprising, by weight, at most 0.25% of C, 1.5% to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.030% of S and at to most 0.03% of P, the complement to 100% being essentially iron. Novel steel compositions for use in these applications are those which comprise, by weight, at most 0.25% of C, more than 2.5% and up to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.03% of S and at most 0.03% of P, the complement to 100% being essentially iron.

摘要翻译： 为了生产可以出现焦炭的炉子，反应器或导管的元件，可以使用具有适于抵抗焦化的组合物的钢，所述组合物按重量计最多包含0.25％的C，1.5％至5％ Si，4〜10％的Cr，0.5〜2％的Mo，0.3〜1％的Mn，最多为0.030％的S和至多0.03％的P，补充为100％的本质上为铁。 用于这些应用的新型钢组合物是包含至多0.25％C，超过2.5％和至多5％Si，4％至10％Cr，0.5％至2％Mo ，0.3％至1％的Mn，至多0.03％的S和至多0.03％的P，100％的互补物基本上是铁。